Acyl group migration and cleavage in selectively protected β-D-galactopyranosides as studied by NMR spectroscopy and kinetic calculations

Journal of the American Chemical Society

Volumn 130, Issue 27, 2008, Pages 8769-8772

  Roslund, Mattias U ^a   Aitio, Olli ^c   Wärna, Johan ^b   Maaheimo, Hannu ^d   Murzin, Dmitry Yu ^b   Leino, Reko ^a  

^a ÅBO AKADEMI UNIVERSITY   (Finland)

^b LABORATORY OF INDUSTRIAL CHEMISTRY AND REACTION ENGINEERING   (Finland)

^c UNIVERSITY OF HELSINKI   (Finland)

^d VTT TECHNICAL RESEARCH CENTRE OF FINLAND   (Finland)

Author keywords

[No Author keywords available]

Indexed keywords

ESTERIFICATION; ESTERS; NUCLEAR MAGNETIC RESONANCE; ORGANIC COMPOUNDS; SYSTEM STABILITY;

ACYL GROUPS; AMERICAN CHEMICAL SOCIETY (ACS); COUNTERCLOCKWISE (CCW); ESTER GROUPS; KINETIC CALCULATIONS; KINETIC MODELLING; MIGRATION RATES; NMR SPECTROS COPY; PROTECTING GROUPS (PG); RELATIVE STABILITIES;

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

ACETIC ACID DERIVATIVE; BETA GALACTOPYRANOSIDE; ESTER; PYRANOSIDE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL BINDING; CHEMICAL REACTION KINETICS; MOLECULAR STABILITY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION ANALYSIS;

GALACTOSE; GLUCOSIDES; HYDROGEN-ION CONCENTRATION; KINETICS; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR CONFORMATION;

EID: 46949083185     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja801177s     Document Type: Article

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