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Volumn , Issue 17, 2008, Pages 2031-2033

Gold-platinum bimetallic clusters for aerobic oxidation of alcohols under ambient conditions

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL; GOLD; GOLD PLATINUM; PLATINUM; POLYSTYRENE DERIVATIVE;

EID: 46749156876     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b800657a     Document Type: Article
Times cited : (95)

References (30)
  • 14
    • 46749153987 scopus 로고    scopus 로고
    • See references in ref. 6
    • See references in ref. 6
  • 27
    • 46749101524 scopus 로고    scopus 로고
    • See Supplementary Information In case of oxidation of alcohols catalyzed by Au:PVP under basic conditions, much larger KIE was observed. See:
    • See Supplementary Information
  • 28
    • 21644475112 scopus 로고    scopus 로고
    • In course of oxidation reactions, both hydrogens are transferred as protons mediated by a solvent, but to maintain neutrality two electrons are transferred through metal clusters. This type of mechanism was proposed for aerobic oxidations catalyzed by metalloenzymes which also work at body temperature open to atmosphere under neutral conditions in aqueous solutions. See:
    • H. Tsunoyama H. Sakurai Y. Negishi T. Tsukuda J. Am. Chem. Soc. 2005 127 9374
    • (2005) J. Am. Chem. Soc. , vol.127 , pp. 9374
    • Tsunoyama, H.1    Sakurai, H.2    Negishi, Y.3    Tsukuda, T.4
  • 30
    • 46749145488 scopus 로고    scopus 로고
    • This gold-platinum bimetallic catalyst shows high turnover frequency at elevated temperature (TOF = 37 500/h for the oxidation of sec-phenetyl alcohol at 160°C)
    • This gold-platinum bimetallic catalyst shows high turnover frequency at elevated temperature (TOF = 37 500/h for the oxidation of sec-phenetyl alcohol at 160°C)


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.