Reaction of the dicobalt alkyne compound Co 2(CO) 6(μ-dmad) with the diphosphine ligand 4,5-bis(diphenylphosphino)- 4-cyclopenten-1,3-dione (bpcd). Spectroscopic properties, X-ray diffraction data, and thermal reactivity of the chelating isomer of Co 2(CO) 4(bpcd)(μ-dmad)

Journal of Chemical Crystallography

Volumn 34, Issue 8, 2004, Pages 513-521

  Xia, Chun Gu ^a   Bott, Simon G ^b   Richmond, Michael G ^c  

^a LANZHOU INSTITUTE OF CHEMICAL PHYSICS   (China)

^b University of Houston   (United States)

^c UNIVERSITY OF NORTH TEXAS   (United States)

Author keywords

alkyne ligand attack; bidentate phosphine ligand; Dicobalt alkyne compounds; hydrocarbyl compound

Indexed keywords

4,5 BIS(DIPHENYLPHOSPHINO) 4 CYCLOPENTEN 1,3 DIONE; AMPHOLYTE; COBALT DERIVATIVE; PHOSPHINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHELATION; CHEMICAL REACTION; CRYSTALLIZATION; CYCLIC POTENTIOMETRY; DATA ANALYSIS; OXIDATION REDUCTION REACTION; PHYSICAL CHEMISTRY; QUANTUM YIELD; SPECTROSCOPY; THERMOSTABILITY; X RAY DIFFRACTION;

EID: 4644362737     PISSN: 10741542     EISSN: None     Source Type: Journal    
DOI: 10.1023/B:JOCC.0000042019.54785.9a     Document Type: Article

References (47)

1. (a) Chia, L.S.; Cullen, W.R.; Franklin, M.; Manning, A.R. Inorg. Chem. 1975, 14, 2521.
2. (b) Bianchini, C.; Dapporto, P.; Meli, A. J. Organomet. Chem. 1979, 174, 205.
3. (a) Bird, P.H.; Fraser, A.R.; Hall, D.N. Inorg. Chem. 1977, 16, 1923.
4. (b) Crow, J.P.; Cullen, W.R. Inorg. Chem. 1971, 10, 2165.
5. (c) Sappa, E.; Predieri, G.; Marko, L. Inorg. Chim. Acta 1995, 228, 147.
6. (a) Cunninghame, R.G.; Hanton, L.R.; Jensen, S.D.; Robinson, B.H.; Simpson, J. Organometallics 1987, 6, 1470.
7. (b) Jensen, S.D.; Robinson, B.H.; Simpson, J. Organometallics 1987, 6, 1479.
8. (c) McAdam, C.J.; Duffy, N.W.; Robinson, B.H.; Simpson, J. Organonietallics 1996, 15, 3935.
9. (d) McAdam, C.J.; Duffy, N.W.; Robinson, B.H.; Simpson, J. J. Organomet. Chem. 1997, 527, 197.
10. (e) Hore, L.-A.; McAdam, C.J.; Kerr, J.L.; Duffy, N.W.; Robinson, B.H.; Simpson, J. Organometallics 2000, 19, 5039.
11. Yang, K.; Bott, S.G.; Richmond, M.G. Organometallics 1994, 13, 3788.
12. (a) Yang, K.; Bott, S.G.; Richmond, M.G. Organometallics, 1994, 13, 3767; 1995, 14, 4977.
13. (a) Yang, K.; Bott, S.G.; Richmond, M.G. Organometallics, 1994, 13, 3767; 1995, 14, 4977.
14. (b) Yang, K.; Bott, S.G.; Richmond, M.G. J. Organomet. Chem. 1995, 516, 65.
15. (a) Fenske, D.; Becher, H.J. Chem. Ber. 1974, 107, 117.
16. (b) Fenske, D. Chem. Ber. 1979, 112, 363.
17. (c) Fenske, D.; Becher, H.J. Chem. Ber. 1975, 108, 2115.
18. Bott, S.G.; Yang, K.; Richmond, M.G. J. Chem. Crystallogr. 2000, 30, 627.
19. (a) Greenfield, H.; Stemberg, H.W.; Friedel, R.A.; Wotiz, J.H.; Markby, R.; Wender, I. J. Am. Chem. Soc. 1956, 78, 120.
20. (b) Cetini, G.; Gambino, O.; Rosetti, R.; Sappa, E. J. Organomet. Chem. 1967, 8, 149.
21. Shriver, D.F. The Manipulation of Air-Sensitive Compounds; McGraw-Hill: New York, 1969.
22. Bard, A.J.; Faulkner, L.R. Electrochemical Methods; Wiley: New York, 1980.
23. (a) Koelle, U. J. Organomet. Chem. 1977, 133, 53.
24. (b) Albers, M.O.; Coville, N. Coord. Chem. Rev. 1984, 53, 227.
25. (a) Rao, C.N.R. Chemical Applications of Infrared Spectroscopy; Academic Press: New York, 1963.
26. (b) Dolphin, D.; Wick, A. Tabulation of Infrared Spectral Data; Wiley-Interscience: New York, 1977.
27. (a) Shen, H.; Williams, T.J.; Bott, S.G.; Richmond, M.G. J. Organomet. Chem. 1995, 505, 1.
28. (b) Shen, H.; Bott, S.G.; Richmond, M,G. Organometallics 1995, 14, 4625.
29. (c) Bott, S.G.; Yang, K.; Wang, J.C.; Richmond, M.G. Inorg. Chem. 2000, 39, 6051.
30. (d) Bott, S.G.; Shen, H.; Senter, R.A.; Richmond, M.G. Organometallics 2003, 22, 1953.
31. (a) Garrou, P.E. Chem. Rev. 1981, 81, 229.
32. (b) Richmond, M. G.; Kochi, J.K. Organometallics 1987, 6, 254.
33. Thorn, D.L.; Hoffmann, R. Inorg. Chem. 1978, 17, 126.
34. (a) Mingos, D.M.P.; May, A.S. In The Chemistry of Metal Cluster Compounds; Shriver, D.F.; Kaesz, H.D.; Adams, R.D., Eds.; VCH Publishers: New York, 1990; Chapter 2.
35. (b) Mingos, D.M.P.; Wales, D.J. Introduction to Cluster Chemistry; Prentice Hall: Englewood Cliffs, NJ, 1990.
36. Hanson, B.E.; Mancini, J.S. Organometallics 1983, 2, 126.
37. (a) Cotton, P.A.; Jamerson, J.D.; Stults, B.R. J. Am. Chem. Soc. 1976, 98, 1774.
38. (b) Gregson, D.; Howard, J.A.K. Acta Crystallogr. 1983, C39, 1024.
39. (c) Bonner, J.-J.; Mathieu, R. Inorg. Chem. 1978, 17, 1973.
40. (c) Fronczek, F.R.; Erickson, M.S. J. Chem. Crystallogr. 1995, 25, 737.
41. Orpen, A.G.; Brammer, L.; Allen, F.H.; Kennard, O.; Watson, D.G.; Taylor, R. J. Chem. Soc. Dalton Trans. 1989, S1.
42. Duffy, N.W.; McAdam. C.J.; Robinson, B.H.; Simpson. J. J. Organoment. Chem. 1998, 565, 19.
43. (a) Kissinger, P.T.; Heineman, W. R. Laboratory Techniques in Electroanalytical Chemistry; Marcel Dekker: New York, 1984.
44. (b) Gosser, D.K., Jr. Cyclic Voltammetry; VCH Publishers: New York, 1993.
45. (a) Peake, B.M.; Rieger, P.H.; Robinson, B.H.; Simpson, J. J. Am. Chem. Soc. 1980, 102, 156.
46. (b) Casagrande, L.V.; Chen, T.; Rieger, P.H.; Robinson, B.H.; Simpson, J.; Visco, S.J. Inorg. Chem. 1984, 23, 2019.
47. Arewgoda, C.M.; Rieger, P.H.; Robinson, B.H.; Simpson, J.; Visco, S.J. J. Am. Chem. Soc. 1982, 104, 5633.