X-ray diffraction structure of Co2(CO)4(μ-PhC≡CH)[(Z)-Ph2PCH=CHPPh2]: Proof for diphosphine ligand chelation

Journal of Chemical Crystallography

Volumn 30, Issue 10, 2000, Pages 627-632

  Bott, Simon G ^a   Yang, Kaiyuan ^b   Richmond, Michael G ^b  

^a University of Houston   (United States)

^b UNIVERSITY OF NORTH TEXAS   (United States)

Author keywords

Dicobalt compound; Diphosphine ligand; X ray diffraction

Indexed keywords

EID: 0034287137     PISSN: 10741542     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1011940014273     Document Type: Article

References (20)

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19. M - P), where P ⋯ P is the internuclear phosphine distance (3.049 Å) and M - P is the average Co - P distance (2.188 Å). See: Dierkes, P.; van Leeuwen, P. W. N. M. J. Chem. Soc. Dalton Trans. 1999, 1519.
20. 2] results from the coordination of a stronger σ-donating diphosphine ligand.