A new class of CVD precursors to metal borides: Cr(B3H 8)2 and related octahydrotriborate complexes

Journal of the American Chemical Society

Volumn 126, Issue 39, 2004, Pages 12230-12231

  Goedde, Dean M ^a   Girolami, Gregory S ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIS(OCTAHYDROTRIBORATE)BERYLLIUM; BORINIC ACID DERIVATIVE; BORON DERIVATIVE; CHROMIC ACID; CHROMIUM CHLORIDE; HYDROGEN; LEWIS BASE; OCTAHYDROTRIBORATE; OLIGOMER; PENTANE; POLYMER; TETRAHYDROFURAN; TOLUENE; TRANSITION ELEMENT; TRIMETHYLPHOSPHINE; UNCLASSIFIED DRUG; ZINC COMPLEX;

ARTICLE; CHEMICAL INTERACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; DECOMPOSITION; DRY DEPOSITION; ELECTRON SPIN RESONANCE; HYDROLYSIS; INFRARED SPECTROMETRY; OXIDATION; ROOM TEMPERATURE; SOLID STATE; SPECTROMETRY; X RAY DIFFRACTION;

EID: 4644306526     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja046906c     Document Type: Article

References (52)

1. Sung, J. W.; Goedde, D. M.; Girolami, G. S.; Abelson, J. R. J. Appl. Phys. 2002, 91, 3904-3911.
2. Jensen, J. A.; Gozum, J. E.; Pollina, D. M.; Girolami, G. S. J. Am. Chem. Soc. 1988, 110, 1643-1644.
3. Wayda, A. L.; Schneemeyer, L. F.; Opila, R. L. Appl. Phys. Lett. 1988, 53, 361-363.
4. Tolle, J.; Roucka, R.; Tsong, I. S. T.; Ritter, C.; Crozier, P. A.; Chizmeshya, A. V. G.; Kouvetakis, J. Appl. Phys. Lett. 2003, 82, 2398-2400.
5. Marynick, D. S.; Lipscomb, W. N. Inorg. Chem. 1972, 11, 820-823.
6. Dain, C. J.; Downs, A. J.; Goode, M. J.; Evans, D. G.; Nicholls, K. T.; Rankin, D. W. H.; Robertson. H. E. J. Chem. Soc., Dalton Trans. 1991, 967-977.
7. Hoekstra, H. R.; Katz, J. J. J. Am. Chem. Soc. 1949, 71, 2488-2492.
8. (a) Banks, R. H.; Edelstein, N. M.; Rietz, R. R.; Templeton, D. H.; Zalkin, A. J. Am. Chem. Soc. 1978, 100, 1957-1958.
9. (b) Banks, R. H.; Edelstein, N. M. In Lanthanide and Actinide Chemistry and Spectroscopy; Edelstein, N. M., Ed.; ACS Symposium Series 131; American Chemical Society: Washington, DC, 1980; pp 331-348.
10. (a) Bernstein, E. R.; Hamilton, W. C.; Keiderling, T. A.; La Placa, S. J.; Lippard, S. J.; Mayerle, J. J. Inorg. Chem. 1972, 11, 3009-3016.
11. (b) Charpin, P.; Nierlich, M.; Vigner, D.; Lance, M.; Baudry, D. Acta Crystallogr. C 1987, 43, 1465-1467.
12. Aldridge, S.; Blake, A. J.; Downs, A. J.; Gould, R. O.; Parsons, S.; Pulham, C. R. J. Chem. Soc., Dalton. Trans. 1997, 1007-1012.
13. (a) Bird, P. H.; Churchill, M. R. J. Chem. Soc., Chem. Commun. 1967, 403.
14. (b) Haaland, A.; Shorokhov, D. J.; Tutukin, A. V.; Volden, H. V.; Swang, O.; McGrady, G. S.; Kaltsoyannis, N.; Downs, A. J.; Tang, C. Y.; Turner, J. F. C. Inorg. Chem. 2002, 41, 6646-6655.
15. (a) Broach, R. W.; Chuang, I.-S.; Marks, T. J.; Williams, J. M. Inorg. Chem. 1983, 22, 1081-1084.
16. (b) Borisenko, K. B.; Downs, A. J.; Robertson, H. E.; Rankin, D. W. H.; Tang, C. Y. Dalton Trans. 2004, 967-970.
17. Banks, R. H.; Edelstein, N. M.; Spencer, B.; Templeton, D. H.; Zalkin, A. J. Am. Chem. Soc. 1980, 102, 620-623.
18. Marks, T. J.; Kolb, J. R. Chem. Rev. 1977, 77, 263-293.
19. (a) Lippard, S. J.; Ucko, D. A. Inorg. Chem. 1968, 7, 1051-1056.
20. (b) Klanberg, F.; Muetterties, E. L.; Guggenberger, L. J. Inorg. Chem. 1968, 7, 2272-2278.
21. (c) Lippard, S. J.; Melmed, K. M. Inorg. Chem. 1969, 8, 2755-2762.
22. (d) Muetterties, E. L.; Peet, W. G.; Wegner, P. A.; Alegranti, C. W. Inorg. Chem. 1970, 9, 2447-2451.
23. (e) Bushweller, C. H.; Beall, H.; Dewkett, W. J. Inorg. Chem. 1976, 15, 1739-1740.
24. (f) Hildebrandt, S. J.; Gaines, D. F.; Calabrese, J. C. Inorg. Chem. 1978, 17, 790-794.
25. (g) Chen, M. W.; Gaines, D. F.; Hoard, L. G. Inorg. Chem. 1980, 19, 2989-2993.
26. (h) Bould, J.; Greenwood, N. N.; Kennedy, J. D. J. Organomet. Chem. 1983, 249, 11-21.
27. (i) Greenwood, N. N.; Kennedy, J. D.; Thomton-Pett, M.; Woollins, J. D. J. Chem. Soc., Dalton Trans. 1985, 2397-2406.
28. (j) Brown, M.; Fontaine, X. L. R.; Greenwood, N. N.; MacKinnon, P.; Kennedy, J. D.; Thomton-Pett, M. J. Chem. Soc., Dalton Trans. 1987, 2181-2187.
29. (k) Grebenik, P. D.; Leach, J. B.; Pounds, J. M.; Green, M. L. H.; Mountford, P. J. Organomet. Chem. 1990, 382, Cl-C5.
30. (l) Hill, T. G.; Godfroid, R. A.; White, J. P., III; Shore, S. G. Inorg. Chem. 1991, 30, 2952-2954.
31. (m) Alcock, N. W.; Burns, I. D.; Claire, K. S.; Hill, A. F. Inorg. Chem. 1992, 31, 4606-4610.
32. (n) Bullick, H. J.; Grebenik, P. D.; Green, M. L. H.; Hughes, A. K.; Leach, J. B.; McGowan, P. C. J. Chem. Soc., Dalton Trans. 1995, 67-75.
33. (o) Burns, I. D.; Hill, A. F.; Williams, D. J. Inorg. Chem. 1996, 35, 2685-2687.
34. (p) Beckett, M. A.; Jones, P. W. Synth. React. Inorg. Met.-Org. Chem. 1997, 27, 41-50.
35. (q) Serrar, C.; Es-Sofi, A.; Boutalib, A.; Ouassas, A.; Jarid, A. Inorg. Chem. 2000, 39, 2224-2226.
36. (r) Ghosh, S.; Beatty, A. M.; Fehlner, T. P. Collect. Czech. Chem. Commun. 2002, 67, 808-812.
37. (s) Beckett, M. A.; Brassington, D. S.; Coles, S. J.; Gelbrich, T.; Hursthouse, M. B. Polyhedron 2003, 22, 1627-1632
38. Gaines, D. F.; Hildebrandt, S. J. Inorg. Chem. 1978, 17, 794-806.
39. Guggenberger, L. J. Inorg. Chem. 1970, 9, 367-373.
40. Hough, W. V.; Edwards, L. J.; McElroy, A. D. J. Am. Chem. Soc. 1958, 80, 1828-1829.
41. Jensen, J. A.; Girolami, G. S. Inorg. Chem. 1989, 28, 2107-2113.
42. Calabrese, J. C.; Gaines, D. F.; Hildebrandt, S. J.; Morris, J. H. J. Am. Chem. Soc. 1976, 98, 5489-5492.
43. Gaines, D. F.; Walsh, J. L.; Morris, J. H.; Hillenbrand, D. F. Inorg. Chem. 1978, 17, 1516-1522.
44. Mitterer, C. J. Solid State Chem. 1997, 133, 279-291.
45. Williams, W. S. J. Miner. Met. Mater. Soc. 1997, 49, 38-42.
46. Abelson, J. R.; Girolami, G. S. manuscript in preparation.
47. Salupo, T. A.; Shore, S. G. Abstracts of Papers, 210th National Meeting of the American Chemical Society, Chicago, IL, August 20-24, 1995; American Chemical Society: Washington, DC, 1995; INOR-421.
48. Heteroleptic metallaboranes containing ancillary ligands can serve as precursors to metal borides, albeit with the usual problem of carbon contamination. See also: (a) White, J. P.; Deng, H. B.; Shore, S. G. Inorg. Chem. 1991, 30, 2337-2342.
49. (b) Thimmappa, B. H. S.; Fehlner, T. P.; Long, G. J.; Pringle, O. A. Chem. Mater. 1991, 3, 1148-1152.
50. (c) Jun, C. S.; Fehlner, T. P.; Long, G. J. Chem. Mater. 1992, 4, 440-446.
51. (d) Reich, S.; Messelhauser, J.; Suhr, H.; Erker, G.; Fritze, C. Adv. Mater. 1994, 6, 674-676.
52. (e) Hanko, K.; Vass, G.; Szepes, L. J. Organomet. Chem. 1995, 492, 235-239.