Synthesis and characterisation of a series of Group 7 metal 2,2,2,2-dicarbonylbis(triorganophosphine)-arachno-2-metallatetraboranes, [M(CO)2L2(B3H8)] (M = Re, Mn); crystal and molecular structures of [Re(CO)2(dppf)(B3H8)] and [Mn(CO)2(dppe)(B3H8)]

Polyhedron

Volumn 22, Issue 12, 2003, Pages 1627-1632

  Beckett, Michael A ^a   Brassington, David S ^a   Coles, Simon J ^b   Gelbrich, Thomas ^b   Hursthouse, Michael B ^b  

^a BANGOR UNIVERSITY   (United Kingdom)

^b UNIVERSITY OF SOUTHAMPTON   (United Kingdom)

Author keywords

Boron; Carbonyl complexes; Manganese; Octahydrotriborate(2 ); Organophosphine ligands; Rhenium; X ray structures

Indexed keywords

MANGANESE COMPOUNDS; RHENIUM; RHENIUM COMPOUNDS; SINGLE CRYSTALS; SYNTHESIS (CHEMICAL);

CARBONYL COMPLEXES; CRYSTAL AND MOLECULAR STRUCTURE; IR-SPECTROSCOPY; OCTAHYDROTRIBORATE(2-); ORGANOPHOSPHINE LIGAND; PHOTOLYTIC CONDITIONS; SINGLE-CRYSTAL X-RAY DIFFRACTION STUDIES; SYNTHESIS AND CHARACTERIZATIONS; SYNTHESISED; X-RAY STRUCTURE;

CHELATION;

2,2,2,2 DICARBONYLBIS(TRIORGANOPHOSPHINE) 2 METALLATETRABORANE; BORANE DERIVATIVE; ORGANOPHOSPHATE INSECTICIDE; RHENIUM; UNCLASSIFIED DRUG;

ARTICLE; CRYSTAL STRUCTURE; DECARBOXYLATION; DERIVATIZATION; INFRARED SPECTROSCOPY; MOLECULAR INTERACTION; NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; STRUCTURE ANALYSIS; SYNTHESIS; X RAY DIFFRACTION;

EID: 0037667827     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0277-5387(03)00289-4     Document Type: Article

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