How do analogous α-chloroenamides and α-iodoenamides give different product distributions in 5-Endo radical cyclizations?

Journal of the American Chemical Society

Volumn 130, Issue 26, 2008, Pages 8437-8445

  Curran, Dennis P ^a   Guthrie, David B ^a   Geib, Steven J ^a  

^a UNIVERSITY OF PITTSBURGH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMIDES; NONMETALS; OLEFINS; SILANES; SILICON; TIN; TITANIUM COMPOUNDS;

ALKENYL; CHAIN REACTIONS; CYCLIZATIONS; CYCLIZED PRODUCTS; DIFFERENT EFFECTS; PRODUCT DISTRIBUTIONS; PRODUCT RATIOS; RADICAL CYCLIZATIONS; RADICAL PRECURSORS; REACTION CONDITIONS; REDUCED PRODUCTS; ROTAMER; SIDE REACTIONS;

CYCLIZATION;

ALKENE DERIVATIVE; ALKENYL GROUP; ALPHA CHLOROENAMIDE DERIVATIVE; ALPHA IODOENAMIDE DERIVATIVE; AMIDE; CHLORIDE; GAMMA LACTAM DERIVATIVE; IODIDE; IODINE DERIVATIVE; METHYL GROUP; N BENZYL 2 HALO N CYCLOHEX 1 ENYLACETAMIDE DERIVATE; RADICAL; REAGENT; SILICON DERIVATIVE; TIN;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLIZATION; DEIODINATION; PRECURSOR; REACTION ANALYSIS; REDUCTION;

EID: 46049112698     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja8012962     Document Type: Article

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