The rate enhancement for prolyl cis-to-trans isomerization of cyclic CPFC peptide is caused by an increase in the vibrational entropy of the transition state

Journal of Physical Chemistry B

Volumn 112, Issue 11, 2008, Pages 3287-3289

  Lee, Joo Yun ^a   Kang, Young Kee ^a  

^a Chungbuk National University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

AMINES; ELECTRON TRANSITIONS; ISOMERS;

CIS-TO-TRANS ISOMERIZATION; CIS-TRANS ISOMERIZATION; CONFORMATIONAL PREFERENCES; RATE ENHANCEMENT; TRANSITION STATE (TS); VIBRATIONAL ENTROPY;

ISOMERIZATION;

AC CYS PRO PHE CYS NH2; AC-CYS-PRO-PHE-CYS-NH2; CYCLOPEPTIDE; OLIGOPEPTIDE; PROLINE;

AMINO ACID SEQUENCE; ARTICLE; CHEMISTRY; COMPUTER SIMULATION; CONFORMATION; ISOMERISM; KINETICS; MOLECULAR GENETICS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTEIN BINDING; QUANTUM THEORY; THERMODYNAMICS;

AMINO ACID SEQUENCE; COMPUTER SIMULATION; ISOMERISM; KINETICS; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR CONFORMATION; MOLECULAR SEQUENCE DATA; OLIGOPEPTIDES; PEPTIDES, CYCLIC; PROLINE; PROTEIN BINDING; QUANTUM THEORY; THERMODYNAMICS;

EID: 45949098190     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp711715j     Document Type: Article

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