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45749103264
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Free-OH groups are benzoylated in the enol products
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Free-OH groups are benzoylated in the enol products.
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21
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33845348952
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2-catalyzed methylalumination occurs with ca. 95:5 regioselectivity. However, no products derived from oxidation of the minor regioisomer were detected in the crude reaction mixtures. See Lipshutz, B. H.; Butler, T.; Lower, A. J. Am. Chem. Soc. 2006, 128, 15396.
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2-catalyzed methylalumination occurs with ca. 95:5 regioselectivity. However, no products derived from oxidation of the minor regioisomer were detected in the crude reaction mixtures. See Lipshutz, B. H.; Butler, T.; Lower, A. J. Am. Chem. Soc. 2006, 128, 15396.
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22
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23
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0141628814
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AD of vinyl sulfones: Evans, P.; Leffray, M. Tetrahedron 2003, 59, 7973.
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(b) AD of vinyl sulfones: Evans, P.; Leffray, M. Tetrahedron 2003, 59, 7973.
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24
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0000882040
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AD of enol ethers : Hashiyama, T.; Morikawa, K.; Sharpless, K. B. J. Org. Chem. 1992, 57, 5067.
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(c) AD of enol ethers : Hashiyama, T.; Morikawa, K.; Sharpless, K. B. J. Org. Chem. 1992, 57, 5067.
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-
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25
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0000711829
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Benzoyl substituents are known to interact favorably with AD ligands: (a) Corey, E. J.; Guzman-Perez, A.; Noe, M. C. J. Am. Chem. Soc. 1995, 117, 10805.
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Benzoyl substituents are known to interact favorably with AD ligands: (a) Corey, E. J.; Guzman-Perez, A.; Noe, M. C. J. Am. Chem. Soc. 1995, 117, 10805.
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27
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33749234144
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and references therein
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Schuster, C.; Knollmueller, M.; Gaertner, P. Tetrahedron: Asymmetry 2006, 17, 2430, and references therein.
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Schuster, C.1
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Yamada, S.1
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32
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45749121912
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See Supporting Information for complete experimental details
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See Supporting Information for complete experimental details.
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