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0039966334
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45449096300
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For details of cone angle estimates, see the Supporting Information
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For details of cone angle estimates, see the Supporting Information.
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27
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0002343287
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31
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45449114391
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Experimental procedure and characterization of 1: [Fe{η5- C5H4P(OPh)2}2, 0.201 g, 0.325 mmol) was dissolved in ether (10 mL, and CsF (0.22 g, 1.46 mmol) and CF 3SiMe3 (0.24 g, 1.69 mmol) were added. After it was stirred at room temperature for 14 h, the mixture was filtered and the solvent removed from the clear filtrate, giving the crude product as a dark orange oil. The product was recrystallized twice from hexane to give orange crystals of 1 (0.112 g, 66, Mp: 49.8°C. 31P NMR (C6D6, δ-3.8 (sept, 2JPF, 73 Hz, 19F NMR (C6D6, δ-53.9 (d, 2JPF, 73 Hz, 1H NMR (C6D6, δ 3.99 (m, 4H, 4.12 (m, 4H, 13C NMR (CD2Cl2, δ 60.1 (m, 73.5 (s, 74.2 (d, 3JCP, 18 Hz, 126.5 qdq, 1
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2: C, 32.21; H, 1.54. Found: C, 32.62; H, 1.49.
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-
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32
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45449083242
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Crystal data for 1: C14H8F12FeP 2, monoclinic, C2/c, a, 17.536(1) Å, b, 9.850(1) Å, c= 12.428(1) Å, β, 125.650(1)°, V, 1744.4(2) Å3, Z, 4, Dc, 1.988 g cm-3, T= 150.0(1) K, Rint, 0.0169, 7417 reflections measured, 2542 unique reflections, 2261 reflections used, R1, 0.0281, wR2, 0.080
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int = 0.0169, 7417 reflections measured, 2542 unique reflections, 2261 reflections used, R1 = 0.0281, wR2 = 0.080.
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33
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33746989769
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0001299185
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Graziani, R.6
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35
-
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45449107791
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int = 0.0280, 19 082 reflections measured, 5882 unique reflections, 5148 reflections used, R1 = 0.0255, wR2 = 0.0592.
-
int = 0.0280, 19 082 reflections measured, 5882 unique reflections, 5148 reflections used, R1 = 0.0255, wR2 = 0.0592.
-
-
-
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36
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33947093595
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Ferguson, G.; Roberts, P. J.; Alyea, E. C.; Khan, M. Inorg. Chem. 1978, 17, 2965-2967.
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37
-
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45449102463
-
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int = 0.0555, 45 498 reflections measured, 15 451 unique reflections, 12 051 reflections used, R1 = 0.0423, wR2 = 0.1181.
-
int = 0.0555, 45 498 reflections measured, 15 451 unique reflections, 12 051 reflections used, R1 = 0.0423, wR2 = 0.1181.
-
-
-
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39
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0001650221
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