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Volumn 27, Issue 11, 2008, Pages 2402-2404

Synthesis, structure, and coordination properties of 1,1′- bis(bis(trifluoromethyl)phosphino)ferrocene, dfmpf

Author keywords

[No Author keywords available]

Indexed keywords

IRON; IRON COMPOUNDS; STRUCTURAL PROPERTIES;

EID: 45449094629     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om701244b     Document Type: Article
Times cited : (23)

References (40)
  • 11
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    • (a) Burg, A. B. Inorg. Chem. 1978, 17, 593-599.
    • (1978) Inorg. Chem , vol.17 , pp. 593-599
    • Burg, A.B.1
  • 16
    • 45449097854 scopus 로고
    • Ph.D. Dissertation, University of Southern California
    • (f) Grant, L. R., Jr. Ph.D. Dissertation, University of Southern California, 1961.
    • (1961)
    • Grant Jr., L.R.1
  • 22
    • 4444264289 scopus 로고    scopus 로고
    • and references cited therein
    • (b) Kalberer, E. W.; Roddick, D. M. Organometallics 2004, 23, 4209-4214, and references cited therein.
    • (2004) Organometallics , vol.23 , pp. 4209-4214
    • Kalberer, E.W.1    Roddick, D.M.2
  • 24
    • 0039966334 scopus 로고
    • Estimated from structural data; see
    • Estimated from structural data; see: Ernst, M. F.; Roddick, D. M. Organometallics 1990, 9, 1586-1594.
    • (1990) Organometallics , vol.9 , pp. 1586-1594
    • Ernst, M.F.1    Roddick, D.M.2
  • 25
    • 45449096300 scopus 로고    scopus 로고
    • For details of cone angle estimates, see the Supporting Information
    • For details of cone angle estimates, see the Supporting Information.
  • 27
    • 0002343287 scopus 로고
    • Togni, A, Hayashi, T, Eds, VCH: New York
    • (b) Gan, K.-S.; Hor, T. S. A. In Ferrocenes; Togni, A.; Hayashi, T., Eds.; VCH: New York, 1995; pp 1-104.
    • (1995) Ferrocenes , pp. 1-104
    • Gan, K.-S.1    Hor, T.S.A.2
  • 31
    • 45449114391 scopus 로고    scopus 로고
    • Experimental procedure and characterization of 1: [Fe{η5- C5H4P(OPh)2}2, 0.201 g, 0.325 mmol) was dissolved in ether (10 mL, and CsF (0.22 g, 1.46 mmol) and CF 3SiMe3 (0.24 g, 1.69 mmol) were added. After it was stirred at room temperature for 14 h, the mixture was filtered and the solvent removed from the clear filtrate, giving the crude product as a dark orange oil. The product was recrystallized twice from hexane to give orange crystals of 1 (0.112 g, 66, Mp: 49.8°C. 31P NMR (C6D6, δ-3.8 (sept, 2JPF, 73 Hz, 19F NMR (C6D6, δ-53.9 (d, 2JPF, 73 Hz, 1H NMR (C6D6, δ 3.99 (m, 4H, 4.12 (m, 4H, 13C NMR (CD2Cl2, δ 60.1 (m, 73.5 (s, 74.2 (d, 3JCP, 18 Hz, 126.5 qdq, 1
    • 2: C, 32.21; H, 1.54. Found: C, 32.62; H, 1.49.
  • 32
    • 45449083242 scopus 로고    scopus 로고
    • Crystal data for 1: C14H8F12FeP 2, monoclinic, C2/c, a, 17.536(1) Å, b, 9.850(1) Å, c= 12.428(1) Å, β, 125.650(1)°, V, 1744.4(2) Å3, Z, 4, Dc, 1.988 g cm-3, T= 150.0(1) K, Rint, 0.0169, 7417 reflections measured, 2542 unique reflections, 2261 reflections used, R1, 0.0281, wR2, 0.080
    • int = 0.0169, 7417 reflections measured, 2542 unique reflections, 2261 reflections used, R1 = 0.0281, wR2 = 0.080.
  • 35
    • 45449107791 scopus 로고    scopus 로고
    • int = 0.0280, 19 082 reflections measured, 5882 unique reflections, 5148 reflections used, R1 = 0.0255, wR2 = 0.0592.
    • int = 0.0280, 19 082 reflections measured, 5882 unique reflections, 5148 reflections used, R1 = 0.0255, wR2 = 0.0592.
  • 37
    • 45449102463 scopus 로고    scopus 로고
    • int = 0.0555, 45 498 reflections measured, 15 451 unique reflections, 12 051 reflections used, R1 = 0.0423, wR2 = 0.1181.
    • int = 0.0555, 45 498 reflections measured, 15 451 unique reflections, 12 051 reflections used, R1 = 0.0423, wR2 = 0.1181.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.