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Volumn 43, Issue 34, 2004, Pages 4497-4500

Synthesis and structure of a dimetallated buckybowl: Coordination of one {Cp*Ru}+ unit to each side of corannulene

Author keywords

Aromaticity; Corannulenes; Ruthenium; Structure elucidation

Indexed keywords

ORGANIC SOLVENTS; SILVER; STRUCTURE (COMPOSITION); SYNTHESIS (CHEMICAL); X RAY ANALYSIS;

EID: 4544385390     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200454225     Document Type: Article
Times cited : (60)

References (30)
  • 6
    • 0042029708 scopus 로고    scopus 로고
    • a) M. A. Petrukhina, K. W. Andreini, J. Mack, L. T. Scott, Angew. Chem. 2003, 115, 3497; Angew. Chem. Int. Ed. 2003, 42, 3375;
    • (2003) Angew. Chem. Int. Ed. , vol.42 , pp. 3375
  • 20
    • 4544295771 scopus 로고    scopus 로고
    • Kα radiation (γ = 0.71073 Å) at T= 193(2) K. Data were corrected for absorption effects by empirical methods using SADABS software (min/max. transmission 0.67). The structure was solved by direct methods and refined using the SHELXTL (version 5.1) software package in full-matrix anisotropic approximation for all non-hydrogen atoms. Hydrogen atoms were placed at idealized positions and refined using the "riding model". The refinement converged to R1 = 0.0760, wR2 = 0.2048 for I > 2σ(I), and R1 = 0.1076, wR2 = 0.2357 for all data, and a goodness-of-fit of 1.048. All significant electron density residuals were found approximately 1 Å from Ru atoms. CCDC-236736 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk).
  • 21
    • 0000878272 scopus 로고
    • J. C. Hanson, C. E. Nordman, Acta Crystallogr. Sect. B 1976, 32, 1147. The C-C bond distances are average values of chemically equivalent bonds from two crystallographically independent molecules and two independent sets of data.
    • (1976) Acta Crystallogr. Sect. B , vol.32 , pp. 1147
    • Hanson, J.C.1    Nordman, C.E.2
  • 24


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.