TMSCl-mediated catalytic carbocupration of alkynoates: An unprecedented and remarkable effect of catalyst loading on highly selective stereochemical induction via a TMS-allenoate intermediate

European Journal of Organic Chemistry

Volumn , Issue 15, 2004, Pages 3201-3204

  Jennings, Michael P ^a   Sawant, Kailas B ^a  

^a UNIVERSITY OF ALABAMA   (United States)

Author keywords

Carbocupration; Cuprates; Grignard reaction; Propiolates; TMS allenoate

Indexed keywords

ALKYNE DERIVATIVE; ALLENE DERIVATIVE; COPPER DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION KINETICS; GRIGNARD REACTION; ISOMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; TEMPERATURE DEPENDENCE;

EID: 4544326720     PISSN: 1434193X     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejoc.200400314     Document Type: Article

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