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85030193289
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note
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6OH→16 see Experimental (entry 7-Oxooctanal, 16).
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28
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85030191661
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note
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2CO at 120°C (80 atm) and subsequent reduction of the keto group.
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85030194887
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note
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3 it was possible to enhance the yield of 28 from 60 to 75%, which brought about an 1.25-fold increase of the overall yield of racemic quadrilure (24).
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13C NMR spectra of (2E,4E) and (2Z,4E) isomers of hydroprene [cf. Maasalu, A.; Teng, S.; Valimae, T.; Laats, K. Eesti NSV Tead. Akad. Toim. (Keem.) 1983, 32, 170; Chem. Abstr. 1983, 100, 6865].
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