Stereocontrolled formation of vinylsilanes via homolytic substitution at silicon

Synthesis

Volumn , Issue 13, 2004, Pages 2226-2235

  Blum, Andreas ^a   Hess, Wilfried ^a   Studer, Armido ^a,b  

^a PHILIPPS UNIVERSITY MARBURG   (Germany)

^b UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

Radical chemistry; Silicon; Stereoselective synthesis; Tin; Vinyl silanes

Indexed keywords

SILANES; SILICON; SYNTHESIS (CHEMICAL);

VINYL RADICALS; VINYL SILANES;

STEREOCHEMISTRY;

2 (2,2 DIPHENYL 4,5,6,6A TETRAHYDRO 2H CYCLOPENTA[D][1,2]OXASILOL 3 YL)PROPAN 2 OL; 2 METHYL 5 [METHYL(DIPHENYL)SILYL]OCT 4 ENE 2,7 DIOL; 2,2 DIPHENYL 3 TRIMETHYLSILYL 4,5,6,6A TETRAHYDRO 2H CYCLOPENTA[D][1,2]OXAZILOLE; 2,2 DIPHENYL 3 TRIMETHYLSILYLMETHYL 4,5,6,6A TETRAHYDRO 2H CYCLOPENTA[D][1,2]OXASILOLE; 2,2,3 TRIPHENYL 4,5,6,6A TETRAHYDRO 2H CYCLOPENTA[D][1,2]OXASILOLE; 3 [[TERT BUTYL(DIMETHYL)SILYL]OXY]BUTYRALDEHYDE; 4 [METHYL(DIPENYL)SILYL]PENT 4 EN 2 OL; 4 IODO 6,6 DIMETHYLHEPT 4 EN 2 OL; 4 IODOPENT 4 EN 2 OL; 5 [METHYL(DIPHENYL)SILYL]HEX 4 EN 2 OL; 5 CYCLOHEXYL 4 [METHYL(DIPHENYL)SILYL]PENT 4 EN 2 OL; 5 CYCLOHEXYL 4 IODOPENT 4 EN 2 OL; 6 HYDROXY 4 IODOHEPT 3 ONIC ACID ETHYL ESTER; 6,6 DIMETHYL 4 [METHYL(DIPHENYL)SILYL]HEPT 4 EN 2 OL; 6,6 DIMETHYLHEPT 4 EN 2 OL; SILICON; UNCLASSIFIED DRUG; VINYL DERIVATIVE; VINYLSILANE DERIVATIVE;

ARTICLE; CYCLIZATION; REACTION ANALYSIS; STEREOCHEMISTRY; SUBSTITUTION REACTION; SYNTHESIS;

EID: 4544319698     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2004-829186     Document Type: Article

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