Phenyl 2-pyridyl ketone and its oxime in manganese carboxylate chemistry: Synthesis, characterisation, X-ray studies and magnetic properties of mononuclear, trinuclear and octanuclear complexes

European Journal of Inorganic Chemistry

Volumn , Issue 14, 2004, Pages 2885-2901

  Milios, Constantinos J ^a   Stamatatos, Theocharis C ^a   Kyritsis, Panayotis ^b   Terzis, Aris ^c   Raptopoulou, Catherine P ^c   Vicente, Ramon ^d   Escuer, Albert ^d   Perlepes, Spyros P ^a  

^a UNIVERSITY OF PATRAS   (Greece)

^b UNIVERSITY OF ATHENS   (Greece)

^c INSTITUTE OF MATERIALS SCIENCE   (Greece)

^d UNIVERSITY OF BARCELONA   (Spain)

Author keywords

Carboxylate ligands; Magnetic properties; Manganese; N,O ligands; X ray crystallography

Indexed keywords

CARBOXYLATION; CHELATION; IONS; KETONES; LIGANDS; MAGNETIC PROPERTIES; MANGANESE; MOLECULES; PH; SYNTHESIS (CHEMICAL);

CARBOXYLATE LIGANDS; CIS-TRANS; HIGHER YIELD; MONODENTATES; MONONUCLEAR COMPLEXES; N,O LIGAND; O LIGANDS; PYRIDYL; TRINUCLEAR; X-RAY STUDIES;

X RAY CRYSTALLOGRAPHY;

BENZOIC ACID; CARBON; CARBOXYLIC ACID; CHELATING AGENT; FERROMAGNETIC MATERIAL; HYDROGEN; HYDROXIDE; KETONE; MANGANESE; METAL ION; OXIME; OXYGEN; PHENYL GROUP; WATER;

ARTICLE; CHELATION; COMPLEX FORMATION; COORDINATION; INFRARED SPECTROSCOPY; ION TRANSPORT; LIGATION; MAGNETISM; MOLECULE; OXIDATION; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS; TEMPERATURE; X RAY CRYSTALLOGRAPHY;

EID: 4544230848     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200400035     Document Type: Article

References (78)

1. [1a] T. G. Carrell, A. M. Tyryshkin, G. C. Dismukes, J. Biol. Inorg. Chem. 2002, 7, 2-22.
2. [1b] V. K. Yachandra, K. Sauer, M. P. Klein, Chem. Rev. 1996, 96, 2927-2950.
3. A. Zouni, H.- T. Witt, J. Kern, P. Fromme, N. Krauss, W. Sanger, P. Orth, Nature 2001, 409, 739-743.
4. [3a] S. Wang, M. S. Wemple, J. Yoo, K. Poking, J. C. Huffman, K. S. Hagen, D. N. Hendrickson, G. Christou, Inorg. Chem. 2000, 39, 1501-1513, and references cited therein.
5. [3b] T. Afrati, C. Dendrinou-Samara, C. P. Raptopoulou, A. Terzis, V. Tangoulis, D. Kessissoglou, Angew. Chem. Int. Ed. 2002, 41, 2148-2150, and references cited therein.
6. [4a] D. Gatteschi, R. Sessoli, Angew. Chem. Int. Ed. 2003, 42, 268-297.
7. [4b] G. Christou, D. Gatteschi, D. N. Hendrickson, R. Sessoli, MRS Bull. 2000, 25, 66-71.
8. [5a] R. Sessoli, D. Gatteschi, A. Caneschi, M. A. Novak, Nature 1993, 365, 141-143.
9. [5b] R. Sessoli, H.-L. Tsai, A. R. Schake, S. Wang, J. B. Vincent, K. Folting, D. Gatteschi, G. Christou, D. N. Hendrickson, J. Am. Chem. Soc. 1993, 775, 1804-1816.
10. [6a] C. Boskovic, W. Wernsdorfer, K. Folting, J. C. Huffman, D. N. Hendrickson, G. Christou, Inorg. Chem. 2002, 41, 5107-5118, and references cited therein.
11. [6b] E. K. Brechin, M. Soler, J. Davidson, D. N. Hendrickson, S. Parsons, G. Christou, Chem. Commun. 2002, 2252-2253.
12. [6c] E. K. Brechin, C. Boskovic, W. Wernsdorfer, J. Yoo, A. Yamaguchi, E. C. Sanudo, T. R. Concolino, A. L. Rheingold, H. Ishimoto, D. N. Hendrickson, G. Christou, J. Am. Chem. Soc. 2002, 124, 9710-9711.
13. [6d] C. J. Milios, C. P. Raptopoulou, A. Terzis, F. Lloret, R. Vicente, S. P. Perlepes, A. Escuer, Angew. Chem. Int. Ed. 2004, 43, 210-212.
14. C. Boskovic, E. K. Brechin, W E. Streib, K. Folting, J. C. Bollinger, D. N. Hendrickson, G. Christou, J. Am. Chem. Soc. 2002, 124, 3725-3736.
15. G. S. Papaefstathiou, S. P. Perlepes, Comments Inorg. Chem. 2002, 23, 249-274.
16. [9a] V. Tangoulis, C. P. Raptopoulou, A. Terzis, S. Paschalidou, S. P. Perlepes, E. G. Bakalbassis, Inorg. Chem. 1997, 36, 3996-4006.
17. [9b] V. Tangoulis, C. P. Raptopoulou, S. Paschalidou, E. G. Bakalbassis, S. P. Perlepes, A. Terzis, Angew. Chem. Int. Ed. Engl. 1997, 36, 1083-1085.
18. [9c] A. Tsohos, S. Dionyssopoulou, C. P. Raptopoulou, A. Terzis, E. G. Bakalbassis, S. P. Perlepes, Angew. Chem. Int. Ed. 1999, 38, 983-985.
19. [9d] G. S. Papaefstathiou, S. P. Perlepes, A. Escuer, R. Vicente, M. Font-Bardia, X. Solans, Angew. Chem. Int. Ed. 2001, 40, 884-886.
20. [9e] G. S. Papaefstathiou, A. Escuer, R. Vicente, M. Font-Bardia, X. Solans, S. P. Perlepes, Chem. Commun. 2001, 2414-2415.
21. [9f] G. S. Papaefstathiou, A. Escuer, C. P. Raptopoulou, A. Terzis, S. P. Perlepes, R. Vicente, Eur. J. Inorg. Chem. 2001, 1567-1574.
22. [9g] N. Lalioti, C. P. Raptopoulou, A. Terzis, A. E. Aliev, I. P. Gerothanassis, E. Manessi-Zoupa, S. P. Perlepes, Angew. Chem. Int. Ed. 2001, 40, 3211-3214.
23. [9h] G. S. Papaefstathiou, A. Escuer, M. Font-Bardia, S. P. Perlepes, X. Solans, R. Vicente, Polyhedron 2002, 21, 2027-2032.
24. [9i] A. K. Boudalis, F. Dahan, A. Bousseksou, J.-P. Tuchagues, S. P. Perlepes, Dalton Trans. 2003, 3411-3418.
25. [9j] A. K. Boudalis, B. Donnadieu, V. Nastopoulos, J. M. Clemente-Juan, A. Mari, Y. Sanakis, J.-P. Tuchagues, S. P. Perlepes, Angew. Chem. Int. Ed. 2004, 43, 2266-2270.
26. C. J. Milios, E. Kefalloniti, C. P. Raptopoulou, A. Terzis, R. Vicente, N. Lalioti, A. Escuer, S. P. Perlepes, Chem. Commun. 2003, 819-820.
27. C. J. Milios, C. P. Raptopoulou, A. Terzis, R. Vicente, A. Escuer, S. P. Perlepes, Inorg. Chem. Commun. 2003, 6, 1056-1060.
28. [12a] Y. Yu. Kukushkin, A. J. L. Pombeiro, Coord. Chem. Rev. 1999, 181, 147-175.
29. [12b] P. Chaudhuri, Coord. Chem. Rev. 2003, 243, 143-190.
30. C. J. Milios, E. Kefalloniti, C. P. Raptopoulou, A. Terzis, A. Escuer, R. Vicente, S. P. Perlepes, Polyhedron 2004, 23, 83-95, and references cited therein.
31. J. B. Vincent, K. Folting, J. C. Huffman, G. Christou, Inorg. Chem. 1986, 25, 996-999.
32. M. W. Wemple, H.-L. Tsai, S. Wang, J. P. Claude, W. E. Streib, J. C. Huffman, D. N. Hendrickson, G. Christou, Inorg. Chem. 1996, 55, 6437-6449.
33. N. C. Harden, M. A. Bolcar, W. Wernsdorfer, K. A. Abboud, W. E. Streib, G. Christou, Inorg. Chem. 2003, 42, 7067-7076.
34. [17a] M. A. Halcrow, W. E. Streib, K. Folting, G. Christou, Acta Crystallogr., Sect. C 1995, 57, 1263-1267.
35. [17b] A. G. Blackman, J. C. Huffman, E. B. Lobkovsky, G. Chrislou, Polyhedron 1992, 77, 251-255.
36. [17c] A. R. Schake, J. B. Vincent, Q. Li, P. D. W. Boyd, K. Folting, J. C. Huffman, D. N. Hendrickson, G. Christou, Inorg. Chem. 1989, 28, 1915-1923.
37. [18a] H.-L. Tsai, S. Wang, K. Folting, W. E. Streib, D. N. Hendrickson, G. Christou, J. Am. Chem. Soc. 1995, 777, 2503-2514.
38. [18b] R. C. Squire, S. M. J. Aubin, K. Folting, W. E. Streib, G. Christou, D. N. Hendrickson, Inorg. Chem. 1995, 34, 6463-6471.
39. J. B. Vincent, H.-R. Chang, K. Folting, J. C. Huffman, G. Christou, D. N. Hendrickson, J. Am. Chem. Soc. 1987, 709, 5703-5711.
40. H. H. Thorpe, Inorg. Chem. 1992, 31, 1585-1588.
41. H. J. Eppley, S. M. J. Aubin, W. E. Streib, J. C. Bollinger, D. N. Hendrickson, G. Christou, Inorg. Chem. 1997, 36, 109-115.
42. J. B. Vincent, C. Christmas, H.-R. Chang, Q. Li, P. D. W. Boyd, J. C. Huffman, D. N. Hendrickson, G. Christou, J. Am. Chem. Soc. 1989, 777, 2086-2097.
43. B. Albela, M. S. El Fallah, J. Ribas, K. Folting, G. Christou, D. N. Hendrickson, Inorg. Chem. 2001, 40, 1037-1044.
44. For example, see: [24a] R. W. Saalfrank, N. Low, B. Demleitner, D. Stalke, M. Teichert, Chem. Eur. J. 1998, 4, 1305-1311.
45. [24b] R. W. Saalfrank, N. Löw, S. Trummer, G. M. Sheldrick, M. Teichert, D. Stalke, Eur. J. Inorg. Chem. 1998, 559-563.
46. C. Boskovic, J. C. Huffman, G. Christou, Chem. Commun. 2002, 2502-2503.
47. E. K. Brechin, G. Christou, M. Soler, M. Helliwell, S. J. Teat, Dalton Trans. 2003, 513-514.
48. [27a] E. Libby K. Folting, C. J. Huffman, J. C. Huffman, G. Christou, Inorg. Chem. 1993, 32, 2549-2556.
49. [27b] E. K. Brechin, M. Soler, G. Christou, M. Helliwell, S. J. Teal, W. Wernsdorfer, Chem. Commun. 2003, 1276-1277.
50. [27c] S. Wang, H.-L. Tsai, K. Folting, J. D. Martin, D. N. Hendrickson, G. Christou, J. Chem. Soc., Chem. Commun. 1994, 671-673.
51. [27d] V. A. Grillo, M. J. Knapp, J. C. Bollinger, D. N. Hendrickson, G. Christou, Angew. Chem. Int. Ed. Engl. 1996, 35, 1818-1820.
52. A. J. Tasiopoulos, K. A. Abboud, G. Chrislou, Chem. Commun. 2003, 580-581.
53. R. E. P. Winpenny, Adv. Inorg. Chem. 2001, 52, 1-111.
54. K. S. Hagen, T. D. Weslmoreland, M. J. Scott, W. H. Armstrong, J. Am. Chem. Soc. 1989, 777, 1907-1909.
55. [31a] M. Soler E. Rumberger, K. Folting, D. N. Hendrickson, G. Christou, Polyhedron 2001, 20, 1365-1369.
56. [31b] L. F. Jones, E. K. Brechin, D. Collison, A. Harrison, S. J. Teat, W. Wernsdorfer, Chem. Commun. 2002, 2794-2795.
57. [32a] V. Tangoulis, D. A. Malamalari, K. Soulli, V. Slergiou, C. P. Raptopoulou, A. Terzis, Th. A. Kabanos, D. P. Kessissoglou, Inorg. Chem. 1996, 35, 4974-4983.
58. [32b] S. Menage, S. E. Vitols, P. Bergerat, E. Codjovi, O. Kahn, J.-J. Girerd, M. Guillot, X. Solans, T. Calvet, Inorg. Chem. 1991, 30, 2666-2671.
59. [32c] R. L. Rardin, P. Poganiuch, A. Bino, D. P. Goldberg, W B. Tolman, S. Li, S. J. Lippard, J. Am. Chem. Soc. 1992, 114, 5240-5249.
60. [32d] J. B. Vincent, G. Christou, Adv. Inorg. Chem. Radiochem. 1989, 33, 197-257.
61. R. A. Reynolds III, W. R. Dunham, D. Coucouvanis, Inorg. Chem. 1998, 37, 1232-1241.
62. [32f] K. Tsuneyoshi, H. Kobayashi, H. Miyamae, Acta Crystallogr., Sect. C 1993, 49, 233-236.
63. For an excellent review on trinuclear Mn complexes, see: D. P. Kessissoglou, Coord. Chem. Rev. 1999, 185-186, 837-858.
64. For a review on the "carboxylale shift" mechanism, see: R. L. Rardin, W. B. Tolman, S. J. Lippard, New J. Chem. 1991, 75, 417-430.
65. B. Albela, M. Corbella, J. Ribas, I. Castro, J. Sletten, H. Stockli-Evans, Inorg. Chem. 1998, 37, 788-798.
66. Z. Sun, P. K. Gantzel, D. N. Hendrickson, Polyhedron 1998, 17, 1511-1516.
67. I. Chadjistamatis, A. Terzis, C. P. Raptopoulou, S. P. Perlepes, Inorg. Chem. Commun. 2003, 6, 1365-1371.
68. M. Tiliakos, P. Cordopatis, A. Terzis, C. P. Raptopoulou, S. P. Perlepes, E. Manessi-Zoupa, Polyhedron 2001, 20, 2203-2214.
69. [39a] G. B. Deacon, R. J. Phillips, Coord. Chem. Rev. 1980, 33, 227-250.
70. [39b] H. Sakiyama, K. Tokuyama, Y. Matsumura, H. Okawa, J. Chem. Soc., Dalton Trans. 1993, 2329-2334.
71. R. D. Cannon, R. P. White, Prog. Inorg. Chem. 1988, 36, 195-298.
72. K. Kambe, J. Phys. Soc. Jpn. 1950, 48, 15.
73. [42a] E. Libby, J. K. McCusker, E. A. Schmitt, K. Folting, D. N. Hendrickson, G. Christou, Inorg. Chem. 1991, 50, 3486-3495.
74. [42b] S. Wang, K. Folting, W. E. Streib, E. A. Schmitt, J. K. McCusker, D. N. Hendrickson, G. Christou, Angew. Chem. Int. Ed. Engl. 1991, 30, 305-306.
75. [42c] G. Aromi, S. Bhaduri, P. Artus, J. C. Huffman, D. N. Hendrickson, G. Christou, Polyhedron 2002, 21, 1779-1786.
76. [42d] C. Canada-Vilalta, J. C. Huffman, G. Christou, Polyhedron 2001, 20, 1785-1793.
77. [43a] G. M. Sheldrick, SHELXS-86, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1986.
78. [43b] G. M. Sheldrick, SHELXL-93, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1993.