Tetranuclear and Octanuclear Manganese Carboxylate Clusters: Preparation and Reactivity of (NBu4n)[Mn4O2 (O2CPh)9(H2O) and Synthesis of (NBu 4n)2[Mn8O4(O2 CPh)12(Et2mal)2(H2O)2]

Inorganic Chemistry

Volumn 35, Issue 22, 1996, Pages 6437-6449

  Wemple, Michael W ^a   Tsai, Hui Lien ^b   Wang, Sheyi ^a   Claude, Juan Pablo ^a   Streib, William E ^a   Huffman, John C ^a   Hendrickson, David N ^b   Christou, George ^a  

^a INDIANA UNIVERSITY   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001408139     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9603013     Document Type: Article

References (59)

1. (a) Indiana University. (b) University of California at San Diego.
2. Lis, T. Acta Crystallogr. 1980, B36, 2042.
3. Christmas, C.; Vincent, J. B.; Chang, H.-R.; Huffman, J. C.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1988, 110, 823.
4. Luneau, D.; Savarinult, J.-M.; Tuchagues, J.-P. Inorg. Chem. 1988, 27, 3912.
5. Bhula, R.; Weatherburn, D. C. Angew. Chem., Int. Ed. Engl. 1991, 30, 688.
6. Low, D. W.; Eichhorn, D. M.; Draganescu, A.; Armstrong, W. H. Inorg. Chem. 1991, 30, 878.
7. Wang, S.; Huffman, J. C.; Folting, K.; Streib, W. E.; Lobkovsky, E. B.; Christou, G. Angew. Chem., Int. Ed. Engl. 1991, 30, 1672.
8. Gorun, S. M.; Stibrany, R. T. U.S. Patent 5,041,575, 1991.
9. Wang, S.; Tsai, H.-L.; Streib, W. E.; Christou, G.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1992, 677.
10. Perlepes, S. P.; Huffman, J. C.; Christou, G. J. Chem. Soc., Chem. Commun. 1992, 1657.
11. Libby, E.; Folting, K.; Huffman, C.J.; Huffman, J. C.; Christou, G. Inorg. Chem. 1993, 32, 2549.
12. Wang, S.; Tsai, H.-L.; Folting, K.; Martin, J. D.; Hendrickson, D. N.; Christou, G. J. Chem. Soc., Chem. Commun. 1994, 671.
13. Squire, R. C.; Aubin, S. M. J.; Folting, K.; Streib, W. E.; Christou, G.; Hendrickson, D. N. Inorg. Chem. 1995, 34, 6463.
14. (a) Debus, R. J. Biochim. Biophys. Acta 1992, 1102, 269.
15. (b) Manganese Redox Enzymes; Pecoraro, V. L., Ed.; VCH Publishers: New York, 1992.
16. Vincent, J. B.; Christmas, C.; Chang, H.-R.; Li, Q.; Boyd, P. D. W.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1989, 111, 2086.
17. Libby, E.; McCusker, J. K.; Schmitt, E. A.; Folting, K.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1991, 30, 3486.
18. Bouwman, E.; Bolcar, M. A.; Libby, E.; Huffman, J. C.; Folting, K.; Christou, G. Inorg. Chem. 1992, 31, 5185.
19. Hendrickson, D. N.; Christou, G.; Schmitt, E. A.; Libby E.; Bashkin, J. S.; Wang, S.; Tsai, H.-L.; Vincent, J. B.; Boyd, P. D. W.; Huffman, J. C.; Folting, K.; Li, Q.; Streib, W. E. J. Am. Chem. Soc. 1992, 114, 2455.
20. Wang, S.; Tsai, H.-L.; Hagen, K. S.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1994, 116, 8376.
21. Wemple, M. W.; Adams, D. M.; Folting, K.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1995, 117, 7275.
22. Wemple, M. W.; Adams, D. M.; Hagen, K. S.; Folting, K.; Hendrickson, D. N.; Christou, G. J. Chem. Soc., Chem. Commun. 1995, 1591.
23. Caneschi, A.; Gatteschi, D.; Rey, P.; Sessoli, R. Inorg. Chem. 1991, 30, 3936.
24. Caneschi, A.; Gatteschi, D.; Sessoli, R.; Barra, A. L.; Brunel, L. C.; Guillot, M. J. Am. Chem. Soc. 1991, 113, 5873.
25. Sessoli, R.; Tsai, H.-L.; Schake, A. R.; Wang, S.; Vincent, J. B.; Folting, K.; Gatteschi, D.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1993, 115, 1804.
26. Sessoli, R.; Gatteschi, D.; Caneschi, A.; Novak, M. A. Nature 1993, 305, 141.
27. Vincent, J. B.; Tsai, H.-L.; Blackman, A. G.; Wang, S.; Boyd, P. D. W.; Folting, K.; Huffman, J. C.; Lobkovsky, E. B.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1993, 115, 12353.
28. Eppley, H. J.; Tsai, H.-L.; de Vries, N.; Folting, K.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1995, 117, 301.
29. Tsai, H.-L.; Wang, S.; Folting, K.; Streib, W. E.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1995, 117, 2503.
30. Goldberg, D. P.; Caneschi, A.; Delfs, C. D.; Sessoli, R.; Lippard, S. J. J. Am. Chem. Soc. 1995, 117, 5789.
31. Schmitt, E. A.; Noodleman, L.; Baerends, E. J.; Hendrickson, D. N. J. Am. Chem. Soc. 1992, 114, 6109.
32. McCusker, J. K.; Tang, H. G.; Wang, S.; Christou, G.; Hendrickson, D. N. Inorg. Chem. 1992, 31, 1874.
33. (a) McCusker, J. K.; Schmitt, S. A.; Hendrickson, D. N. In Magnetic-Molecular Materials: Gatteschi, D., Kahn, O., Miller, J. S., Palacio, F., Eds.; Kluwer: Boston, 1991; pp 297-319.
34. (b) Hendrickson, D. N. Spin Frustration in Polynuclear Complexes. In Research Frontiers in Magnetochemistry; O'Connor, C. J., Ed.; World Scientific: Singapore, 1993.
35. Wang, S.; Folting, K.; Streib, W. E.; Schmitt, E. A.; McCusker, J. K.; Hendrickson, D. N.; Christou, G. Angew. Chem., Int. Ed. Engl. 1991, 30, 305.
36. (a) Kulawiec, R. J.; Crabtree, R. H.; Brudvig, G. W.; Schulte, G. K. Inorg. Chem. 1988, 27, 1309.
37. (b) Thorp, H. H.; Sarneski, J. E.; Kulawiec, R. J.; Brudvig, G. W.; Crabtree, R. H.; Papaefthymiou, G. C. Inorg. Chem. 1991, 30, 1153.
38. (a) Mikuriya, M.; Yamato, Y.; Tokii, T. Chem. Lett. 1991, 1429.
39. (b) Mikuriya, M.; Yamato, Y.; Tokii, T. Bull. Chem. Soc. Jpn. 1992, 65, 2624.
40. (a) Chandra, S. K.; Chakravorty, A. Inorg. Chem. 1991, 30, 3795.
41. (b) Chandra, S. K.; Chakravorty, P.; Chakravorty, A. J. Chem. Soc., Dalton Trans. 1993, 863.
42. Gedye, C.; Harding, C.; McKee, V.; Nelson, J.; Patterson, J. J. Chem. Soc., Chem. Commun. 1992, 392.
43. Jiang, Z.-H.; Ma, S.-L.; Liao, D.-Z.; Yan, S.-P.; Wang, G.-L.; Yao, X.-K.; Wang, R.-J. J. Chem. Soc., Chem. Commun. 1993, 745.
44. Wemple, M. W.; Tsai, H.-L.; Streib, W. E.; Hendrickson, D. N.; Christou, G. J. Chem. Soc., Chem. Commun. 1994, 1031.
45. Vincent, J. B.; Chang, H.-R.; Folting, K.; Huffman, J. C.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1987, 109, 5703.
46. Wang, S.; Tsai, H.-L.; Wemple, M. W.; Hagen, K. S.; Hendrickson, D. N.; Christou, G. Manuscript in preparation.
47. Chisholm, M. H.; Folting, K.; Huffman, J. C.; Kirkpatrick, C. C. Inorg. Chem. 1984, 23, 1021.
48. Theory and Applications of Molecular Paramagnetism; Boudreaux, E. A.; Mulay, L. N., Eds.; J. Wiley & Sons: New York, 1976.
49. Olmstead, W. N.; Bardwell, F. G. J. Org.. Chem. 1980, 45, 3295.
50. Halcrow, M. A.; Streib, W. E.; Folting, K.; Christou, G. Acta Crystallogr., Sect. C 1995, C51, 1263.
51. Representative manganese complexes: (a) Lis, T.; Matuszewski, J.; Jeźowska-Trzebiatowska, B. Acta Crystallogr., Sect. B 1977, 33, 1943. (b) Lis, T.; Matuszewski, J. Acta Crystallogr., Sect. B 1979, 35, 2212. (c) Lis, T.; Matuszewski, J. J. Chem. Soc., Dalton Trans. 1980, 996. Saadeh, S. M.; Trojan, K. L.; Kampf, J. W.; Hatfield, W. E.; Pecoraro, V. L. Inorg. Chem. 1993, 32, 3034. (e) Haselhorst, G.; Wieghardt, K. J. Inorg. Biochem. 1995, 59, 624.
52. Representative manganese complexes: (a) Lis, T.; Matuszewski, J.; Jeźowska-Trzebiatowska, B. Acta Crystallogr., Sect. B 1977, 33, 1943. (b) Lis, T.; Matuszewski, J. Acta Crystallogr., Sect. B 1979, 35, 2212. (c) Lis, T.; Matuszewski, J. J. Chem. Soc., Dalton Trans. 1980, 996. Saadeh, S. M.; Trojan, K. L.; Kampf, J. W.; Hatfield, W. E.; Pecoraro, V. L. Inorg. Chem. 1993, 32, 3034. (e) Haselhorst, G.; Wieghardt, K. J. Inorg. Biochem. 1995, 59, 624.
53. Representative manganese complexes: (a) Lis, T.; Matuszewski, J.; Jeźowska-Trzebiatowska, B. Acta Crystallogr., Sect. B 1977, 33, 1943. (b) Lis, T.; Matuszewski, J. Acta Crystallogr., Sect. B 1979, 35, 2212. (c) Lis, T.; Matuszewski, J. J. Chem. Soc., Dalton Trans. 1980, 996. Saadeh, S. M.; Trojan, K. L.; Kampf, J. W.; Hatfield, W. E.; Pecoraro, V. L. Inorg. Chem. 1993, 32, 3034. (e) Haselhorst, G.; Wieghardt, K. J. Inorg. Biochem. 1995, 59, 624.
54. Representative manganese complexes: (a) Lis, T.; Matuszewski, J.; Jeźowska-Trzebiatowska, B. Acta Crystallogr., Sect. B 1977, 33, 1943. (b) Lis, T.; Matuszewski, J. Acta Crystallogr., Sect. B 1979, 35, 2212. (c) Lis, T.; Matuszewski, J. J. Chem. Soc., Dalton Trans. 1980, 996. Saadeh, S. M.; Trojan, K. L.; Kampf, J. W.; Hatfield, W. E.; Pecoraro, V. L. Inorg. Chem. 1993, 32, 3034. (e) Haselhorst, G.; Wieghardt, K. J. Inorg. Biochem. 1995, 59, 624.
55. Representative manganese complexes: (a) Lis, T.; Matuszewski, J.; Jeźowska-Trzebiatowska, B. Acta Crystallogr., Sect. B 1977, 33, 1943. (b) Lis, T.; Matuszewski, J. Acta Crystallogr., Sect. B 1979, 35, 2212. (c) Lis, T.; Matuszewski, J. J. Chem. Soc., Dalton Trans. 1980, 996. Saadeh, S. M.; Trojan, K. L.; Kampf, J. W.; Hatfield, W. E.; Pecoraro, V. L. Inorg. Chem. 1993, 32, 3034. (e) Haselhorst, G.; Wieghardt, K. J. Inorg. Biochem. 1995, 59, 624.
56. Hansson, E. Acta Chem. Scand. 1973, 27, 2827.
57. Tsai, H.-L.; Wang, S.; Christou, G.; Hendrickson, D. N. Unpublished results.
58. Kambe, K. J. Phys. Soc. Jpn. 1950, 5, 48.
59. NMR of Paramagnetic Molecules; LaMar, G. N.; Horrocks, W. D., Jr., Holm, R. H., Eds., Academic Press: New York, 1973.