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V. Kapko, D. Matyushov, and C.A. Angell are currently demonstrating the generation of a phase diagram with features close to those of Figure 6, obtained for a system in which a Lennard-Jones sphere is systematically distorted to create a rod-like atom. A wide region about the eutectic is a computer glass-former, with interesting liquid-state properties.
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V. Kapko, D. Matyushov, and C.A. Angell are currently demonstrating the generation of a phase diagram with features close to those of Figure 6, obtained for a system in which a Lennard-Jones sphere is systematically distorted to create a rod-like atom. A wide region about the eutectic is a computer glass-former, with interesting liquid-state properties.
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A Widom line is defined by Stanley and coworkers [see L.-M. Xu, P. Kumar, S.V. Buldyrev, H.E. Stanley, Proc. Natl. Acad. Sci. USA 102, 16588 (2005)] to be the extension of a line of first-order liquid-liquid transition temperatures beyond the critical point which terminates the coexistence line.
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A Widom line is defined by Stanley and coworkers [see L.-M. Xu, P. Kumar, S.V. Buldyrev, H.E. Stanley, Proc. Natl. Acad. Sci. USA 102, 16588 (2005)] to be the extension of a line of first-order liquid-liquid transition temperatures beyond the critical point which terminates the coexistence line.
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85036914761
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Users of this form should be aware that it greatly overemphasizes the early couple of orders of magnitude of frequency decrease; hence, unless this is taken into account, it gives a portrayal of liquid behavior that is not a good guide to what is happening near Tg. The analysis of the heat capacity using the form Sex, Cp log(T/Tm) does the opposite
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m) does the opposite.
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