Thermodynamic fragility and kinetic fragility in supercooling liquids: A missing link in molecular liquids

Journal of Chemical Physics

Volumn 111, Issue 23, 1999, Pages 10403-10406

  Ngai, K L ^a   Yamamuro, Osamu ^b  

^a NAVAL RESEARCH LABORATORY   (United States)

^b OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000404619     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.480394     Document Type: Article

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14. -1, which is 28% of the entropy of fusion), making this interpretation uncertain. A different view is taken by Angell and Moynihan (C. A. Angell, private communication, 1999). They prefer to interpret the toluene glass to have a large configurational component and the configurational entropy to be evaluated directly from [S(liquid)/S(crystal)]. We present the results of the scaled configurational entropy of toluene and EBZ obtained by both ways in Figs. 1 and 3.
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