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46749157063
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The majority of the holes (the donors) induced by the radiation are formed in clusters. This influences the distance distribution between donors and acceptors and thus affects the probability for transfer. The degree of clustering is unknown, and since the issues of interest here are the relative effects of temperature and deuterium substitution KIE, a random distribution of donors and acceptors will be assumed
-
The majority of the holes (the donors) induced by the radiation are formed in clusters. This influences the distance distribution between donors and acceptors and thus affects the probability for transfer. The degree of clustering is unknown, and since the issues of interest here are the relative effects of temperature and deuterium substitution (KIE), a random distribution of donors and acceptors will be assumed.
-
-
-
-
34
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-
46749099914
-
-
When using this last expression, it has previously been found that k 0 will be too large by a factor 1.9 see ref 29, When numerical values are quoted, this correction has been made
-
0 will be too large by a factor 1.9 (see ref 29). When numerical values are quoted, this correction has been made.
-
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-
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35
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-
46749122014
-
-
0 values than those reported.
-
0 values than those reported.
-
-
-
-
40
-
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46749100315
-
-
The EPR signal of radical RS will be similar and well-separated from the spectral bulk whether deprotonated or not. Thus, PT2 as a subsequent step will not contribute to the KIE
-
The EPR signal of radical RS will be similar and well-separated from the spectral bulk whether deprotonated or not. Thus, PT2 as a subsequent step will not contribute to the KIE.
-
-
-
-
41
-
-
46749114550
-
-
The possibility of a stepwise reaction for the normal crystals, with HT being rate-limiting, and a concerted transfer for the deuterated crystals is not considered likely as the larger coupling for PT1/HT would be more likely to override the lower barrier for HPT1 for systems with deuterium than for systems with hydrogen.
-
The possibility of a stepwise reaction for the normal crystals, with HT being rate-limiting, and a concerted transfer for the deuterated crystals is not considered likely as the larger coupling for PT1/HT would be more likely to override the lower barrier for HPT1 for systems with deuterium than for systems with hydrogen.
-
-
-
-
44
-
-
46749086368
-
-
Differences in zero point energies for the N-H and N-D bonds, or different pK values, assumedly do not contribute significantly to the KIE see ref 45
-
Differences in zero point energies for the N-H and N-D bonds, or different pK values, assumedly do not contribute significantly to the KIE (see ref 45).
-
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47
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33847364533
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Kugel, G. E.; Gerbaux, X.; Carabatos, C.; Martel, P.; Powell, B. M. Spectrochim. Acta A 1979, 35, 1155.
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-
50
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-
46749112387
-
-
Since the electrons/holes and the protons generally transfer in different directions the excitation of these modes may not be expected to enhance the electronic coupling between electron/hole donor and acceptor
-
Since the electrons/holes and the protons generally transfer in different directions the excitation of these modes may not be expected to enhance the electronic coupling between electron/hole donor and acceptor.
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51
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0035909710
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