Synthesis and characterization of PEO-PCL-PEO triblock copolymers: Effects of the PCL chain length on the physical property of W1/O/W2 multiple emulsions

Colloids and Surfaces B: Biointerfaces

Volumn 65, Issue 1, 2008, Pages 61-68

  Cho, Heui Kyoung ^a   Cho, Kwang Soo ^a   Cho, Jin Hun ^b   Choi, Sung Wook ^b   Kim, Jung Hyun ^b   Cheong, In Woo ^a  

^a Kyungpook National University   (South Korea)

^b Yonsei University   (South Korea)

Author keywords

Amphiphilic; Ascorbic acid 2 glucoside; Biodegradable; Multiple emulsions; PEO PCL PEO; Water in oil in water

Indexed keywords

BIODEGRADABLE POLYMERS; CHAIN LENGTH; CRYSTAL STRUCTURE; EMULSIONS; MOLECULAR WEIGHT; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

MODEL REAGENTS; MULTIPLE EMULSIONS; POLARIZED OPTICAL MICROSCOPY (POM); WATER-IN-OIL-IN-WATER;

BLOCK COPOLYMERS;

AMPHOPHILE; ASCORBIC ACID; ASCORBIC ACID 2 GLUCOSIDE; COPOLYMER; GLUCOSIDE; MACROGOL; OIL; POLY(ETHYLENE GLYCOL) BLOCK POLY(EPSILON CAPROLACTONE) BLOCK POLY(ETHYLENE GLYCOL); POLYCAPROLACTONE; REAGENT; TRIBLOCK COPOLYMER; WATER;

ARTICLE; BIODEGRADABILITY; CONFOCAL LASER MICROSCOPY; CRYSTALLIZATION; DIFFERENTIAL SCANNING CALORIMETRY; EMULSION; FLOW MEASUREMENT; IMAGE ANALYSIS; INFRARED SPECTROSCOPY; MICROSCOPY; MOLECULAR WEIGHT; PARTICLE SIZE; PHYSICAL CHEMISTRY; POLARIZED OPTICAL MICROSCOPY; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; RIGIDITY; SYNTHESIS; VISCOSITY; X RAY DIFFRACTION; YOUNG MODULUS;

CALORIMETRY, DIFFERENTIAL SCANNING; EMULSIONS; MICROSCOPY; OILS; POLYESTERS; POLYETHYLENE GLYCOLS; WATER;

EID: 44749093045     PISSN: 09277765     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.colsurfb.2008.02.017     Document Type: Article

References (41)

1. He C., Sun J., Zhao T., Hong Z., Zhuang X., Chen X., and Jing X. Biomacromolecules 7 (2006) 252
2. He C., Sun J., Ma J., Chen X., and Jing X. Biomacromolecules 7 (2006) 3482
3. Jiang S., He C., An L., Chen X., and Jiang B. Macromol. Chem. Phys. 205 (2004) 2229
4. Floudas G., Reiter G., Lambert O., Dumas P., and Chu B. Polym. Mater. Sci. Eng. 79 (1998) 375
5. Li L., Meng F., Zhong Z., Byelov D., de Jeu W.H., and Feijen J. J. Chem. Phys. 126 (2007) 024904
6. Na Y.-H., He Y., Shuai X., Kikkawa Y., Doi Y., and Inoue Y. Biomacromolecules 3 (2002) 1179
7. Li S., Garreau H., Pauvert B., McGrath J., Toniolo A., and Vert M. Biomacromolecules 3 (2002) 525
8. Bernerd F. J. Soc. Biol. 199 (2006) 313
9. Elias P.M. J. Invest. Dermatol. 125 (2005) 183
10. Elias Peter M., and Choi Eung H. Exp. Dermatol. 14 (2005) 719
11. Kumar M.A., Babu M.F.S., Srinivasulu K., Kiran Y.B., and Reddy C.S. J. Mol. Catal. A: Chem. 265 (2007) 268
12. Akala E.O., Okunola O., and Pan G. Abstracts, 37th Middle Atlantic Regional Meeting of the American Chemical Society, GENE-077. New Brunswick, NJ, United States, May 22-25 (2005)
13. Bei J.-Z., Li J.-M., Wang Z.-F., Le J.-C., and Wang S.-G. Polym. Adv. Technol. 8 (1997) 693
14. Jeong B., Bae Y.H., Lee D.S., and Kim S.W. Nature (London) 388 (1997) 860
15. Chen S., Pieper R., Webster D.C., and Singh J. Int. J. Pharm. 288 (2005) 207
16. Nam Y.S., Choi D.W., Kim J., Han S.-H., and Chang I.-S. PMSE Preprints 90 (2004) 836
17. Park S.-J., Yang Y.-J., Lee J.-R., and Suh D.-H. Kongop Hwahak 14 (2003) 354
18. Haw J.-R., and Kim C.-H. Kongop Hwahak 8 (1997) 560
19. Jiao J., Rhodes D.G., and Burgess D.J. J. Colloid Interf. Sci. 250 (2002) 444
20. Jiao J., and Burgess D.J. Pharm. Sci. 5 (2003) 62
21. Michaut F., Hebraud P., and Perrin P. Polym. Int. 52 (2003) 594
22. Kiyoyama S., Shiomori K., Kawano Y., and Hatate Y. J. Microencapsul. 20 (2003) 497
23. An J.H., Kim H.S., Chung D.J., Lee D.S., and Kim S. J. Mater. Sci. 36 (2001) 715
24. Wunderlich B. Macromol. Phys. Cryst. Nucleation Growth Anneal. 2 (1976) 168
25. He C., Sun J., Deng C., Zhao T., Deng M., Chen X., and Jing X. Biomacromolecules 5 (2004) 2042
26. Takeshita H., Fukumoto K., Ohnishi T., Ohkubo T., Miya M., Takenaka K., and Shiomi T. Polymer 47 (2006) 8210
27. Arnal M.L., Lopez-Carrasquero F., Laredo E., and Muller A.J. Eur. Polym. J. 40 (2004) 1461
28. Federico R., Cona A., Caliceti P., and Veronese F.M. J. Control. Rel. 115 (2006) 168
29. Shiomi T., Imai K., Takenaka K., Takeshita H., Hayashi H., and Tezuka Y. Polymer 42 (2001) 3233
30. Cheong I.W., Nomura M., and Kim J.H. Macromol. Chem. Phys. 201 (2000) 2221
31. Lu C.-F., Guo S.-R., Zhang Y.-Q., and Yao Y.-Q. Huadong Ligong Daxue Xuebao. Ziran Kexueban 32 (2006) 655
32. Choi C., Chae S.Y., Kim T.-H., Jang M.-K., Cho C.S., and Nah J.-W. Bull. Korean Chem. Soc. 26 (2005) 523
33. Choi C., Chae S.Y., Kim T.-H., Kweon J.K., Cho C.S., Jang M.-K., and Nah J.-W. J. Appl. Polym. Sci. 99 (2006) 3520
34. Aragon S.R., and Pecora R. J. Chem. Phys. 64 (1976) 2395
35. Bae S.J., Suh J.M., Sohn Y.S., Bae Y.H., Kim S.W., and Jeong B. Macromolecules 38 (2005) 5260
36. Kim M.S., Hyun H., Seo K.S., Cho Y.H., Lee J.W., Lee C.R., Khang G., and Lee H.B. J. Polym. Sci. A 44 (2006) 5413
37. Bae S.J., Joo M.K., Jeong Y., Kim S.W., Lee W.-K., Sohn Y.S., and Jeong B. Macromolecules 39 (2006) 4873
38. Jeong B., Lee D.S., Shon J.-I., Bae Y.H., and Kim S.W. J. Polym. Sci. A 37 (1999) 751
39. Vasiljevic D., Parojcic J., Primorac M., and Vuleta G. Int. J. Pharm. 309 (2006) 171
40. Velankar S., and Cooper S.L. Macromolecules 33 (2000) 395-403
41. Yang I.K., and Hu C.-C. Eur. Polym. J. 42 (2006) 402-409