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The reaction also takes place for complexes with a Ge-Ge bond and an Ru-Ru bond; see: a
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A similar case has been reported in the case of 1,1,1,3,3,3- hexamethyltrisilylene-bridged bis(cyclopentadienyl) complexes; see: Sun, H.; Zhang, Z. Polyhedron 2007, 26, 1211-1216.
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A similar case has been reported in the case of 1,1,1,3,3,3- hexamethyltrisilylene-bridged bis(cyclopentadienyl) complexes; see: Sun, H.; Zhang, Z. Polyhedron 2007, 26, 1211-1216.
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Synthesis of 4 by method B: to a suspension of 1,4-dilithiotetraphenylbuta-1,3-diene in 100 mL of diethyl ether at-78 °C, obtained from 5.50 g (31 mmol) of diphenylacetylene and 0.216 g (31 mmol) of lithium according to the literature procedure,13 was added 3.80 g (15.5 mmol) of 2,2-dichlorohexamethyltrisilane. A 100 mL portion of THF was added, and the resulting mixture was heated to reflux for 2 h. It was cooled to room temperature and hydrolyzed with water. The organic layer was separated, washed with water, and dried over anhydrous sodium sulfate. Removal of the solvent, followed by separation through a column (silica, petroleum ether, gave 864 mg of 4 (5.7% yield) contaminated by a byproduct characterized as 1,4-bis(trimethylsilyl)tetraphenyldutadiene. The origin of the byproduct has not yet been determined. Pure 4 was obtained by fractional crystallization of the product in pentane at-20 °C, b) Synthesis of 6: 200 mg (0.38 mmol) of 4
-
-1.
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41
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44649113688
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-
Crystallographic data for 6: Mo Kα (λ, 0.710 73 Å) radiation, monoclinic, space group P21/n, a, 8.965(3) Å, b, 19.433(5) Å, c, 18.239(4) Å, α, 90°, β, 95.184(6)°, γ, 90°, Z, 4, full-matrix least squares on F 2, GOF 0.974, R1, 0.0669/wR2, 0.1217 for 5571 reflections (I > 2σI, R1, 0.1700/WR2, 0.1658 for all data
-
2, GOF 0.974, R1 = 0.0669/wR2 = 0.1217 for 5571 reflections (I > 2σ(I)), R1 = 0.1700/WR2 = 0.1658 for all data.
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