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Volumn 25, Issue 1, 2006, Pages 133-139

Stereochemistry of the thermal rearrangement through intramolecular metathesis of Si-Si and Fe-Fe bonds: First evidence for a nonconcerted mechanism

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; IRON COMPOUNDS; ISOMERS; STEREOCHEMISTRY; SYNTHESIS (CHEMICAL);

EID: 30344432705     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om050622z     Document Type: Article
Times cited : (13)

References (72)
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    • 0000185390 scopus 로고
    • (d) Horn, K. A. Chem. Rev. 1995, 95, 1317-1350.
    • (1995) Chem. Rev. , vol.95 , pp. 1317-1350
    • Horn, K.A.1
  • 42
    • 0003644229 scopus 로고
    • Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon: Oxford
    • West, R. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon: Oxford, 1983; Vol. 9, p 365.
    • (1983) Comprehensive Organometallic Chemistry , vol.9 , pp. 365
    • West, R.1
  • 43
    • 30344479606 scopus 로고    scopus 로고
    • Sun, H.; Wang, F.; et al. Unpublished results
    • Sun, H.; Wang, F.; et al. Unpublished results.
  • 57
    • 30344433117 scopus 로고    scopus 로고
    • note
    • The stereorandomization cannot take place after the rearrangement. This has been confirmed experimentally by treating the pure isomers of the rearranged products under thermal conditions.
  • 58
    • 30344467086 scopus 로고    scopus 로고
    • note
    • 6a), which renders the system very complicated and not suitable for in situ ESR study.
  • 72
    • 30344436525 scopus 로고    scopus 로고
    • note
    • One of the reviewers of this paper provided the valuable suggestion that there is a third possible pathway to generate a vacant coordination site on the iron center: i.e., through changing one of the bridging CO groups into a terminal one and breaking the Fe-Fe bond. This pathway, which would involve formation of intermediates with coordination modes rather similar to those of the CO-loss pathway, will be considered together with the CO-loss mechanism in a forthcoming paper.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.