Reactions of vinyldisilanes with ruthenium carbonyl

Chemistry Letters

Volumn , Issue 8, 1999, Pages 717-718

  Dai, Xiaosu ^a   Kano, Naokazu ^a   Kako, Masahiro ^a   Nakadaira, Yasuhiro ^a  

^a UNIVERSITY OF ELECTRO COMMUNICATIONS   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0033245541     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1999.717     Document Type: Article

References (17)

1. H. Sakurai, Y. Kamiyama, and Y. Nakadaira, J. Organomet. Chem., 184, 13 (1980).
2. 3-1-silapropenyl transition metal complex has been isolated so far with sufficient structural evidence. a) H. Sakurai, Y. Kamiyama, and Y. Nakadaira, J. Am. Chem. Soc., 98, 7453 (1976); H. Sakurai, Y. Kamiyama, A. Mikoda, T. Kobayashi, K. Sasaki, and Y. Nakadaira, J. Organomet. Chem., 201, C14 (1980).
3. 3-1-silapropenyl transition metal complex has been isolated so far with sufficient structural evidence. a) H. Sakurai, Y. Kamiyama, and Y. Nakadaira, J. Am. Chem. Soc., 98, 7453 (1976); H. Sakurai, Y. Kamiyama, A. Mikoda, T. Kobayashi, K. Sasaki, and Y. Nakadaira, J. Organomet. Chem., 201, C14 (1980).
4. b) P. Radnia and J. S. Mckennis, J. Am. Chem. Soc., 102, 6349 (1980).
5. c) Y. Kabe, T. Yamamoto, and W. Ando, Organometallics, 13, 4606 (1994).
6. All reactions were carried out under an argon atmosphere. Chemical yields except those of 9 were determined by GLC. The yields in this paper are based on the vinyldisilanes and the vinylsilanes consumed. All new products showed satisfactory spectral data.
7. The isomerization of 2b to 2a was not observed under these reaction conditions.
8. For example, a) Hydrosilylation, I. Ojima, Z. Li, and J. Zhu, in "The Chemistry of Organosilicon Compounds, Vol.2," ed by Z. Rappoport and Y. Apeloig, John Wiley & Sons, Chichester (1998), chap. 29.
9. b) Bis-silylation, M. Suginome, H. Oike, S.-S. Park, and Y. Ito, Bull. Chem. Soc. Jpn., 69, 289 (1996).
10. c) F. Ozawa and T. Hikida, Organometallics, 15, 4501 (1996).
11. For example, R. Okazaki and R. West, in "Multiply Bonded Main Group Metals and Metalloids," ed by R. West and F. G. A. Stone, Academic Press, New York (1996), pp. 231.
12. J. D. Feldman, G. P. Mitchell, J-O. Nolte, and T. D. Tilly, J. Am. Chem. Soc., 120, 11184 (1998), and references cited therein.
13. Y. Seki, K. Takeshita, K. Kawamoto, S. Murai, and N. Sonoda, J. Org. Chem., 51, 3890 (1986).
14. H. Sakurai, Y. Kamiyama, and Y. Nakadaira, J. Am. Chem. Soc., 99, 3879 (1977); D. Seyferth, M. L. Shannon, S. C. Vick, and T. F. O. Lim, Organometallics, 4, 57 (1985).
15. H. Sakurai, Y. Kamiyama, and Y. Nakadaira, J. Am. Chem. Soc., 99, 3879 (1977); D. Seyferth, M. L. Shannon, S. C. Vick, and T. F. O. Lim, Organometallics, 4, 57 (1985).
16. M. Ephritikhine, B. R. Francis, M. L. H. Green, R. E. Mackenzie, and M. J. Smith, J. Chem. Soc., Dalton Trans., 1977, 1131.
17. 11 5b would be possibly transferred to one of the complexes 5a, 11a, and 12 by way of silyl and skeletal rearrangements.