Solvent-free enzymatic synthesis of structured lipids containing CLA from coconut oil and tricaprylin

JAOCS, Journal of the American Oil Chemists' Society

Volumn 81, Issue 7, 2004, Pages 685-689

  Rocha Uribe, Alejandro ^a,b   Hernandez, Ernesto ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

^b Univ Autonoma de San Luis Potosi   (Mexico)

Author keywords

Coconut oil; Conjugated linoleic acid; Lipases; Solvent free acidolysis; Structured lipids; Tricaprylin

Indexed keywords

CONCENTRATION (PROCESS); ENZYMES; LIPIDS; METABOLISM; SOLVENTS; SUBSTRATES; SYNTHESIS (CHEMICAL);

COCONUT OIL; CONJUGATED LINOLEIC ACIDS; LIPASES; SOLVENT-FREE ACIDOLYSIS; STRUCTURED LIPIDS; TRICAPRYLIN;

VEGETABLE OILS;

MUCOR; RHIZOMUCOR MIEHEI;

EID: 4444351486     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11746-004-962-z     Document Type: Article

References (20)

1. Ip, C., J.A. Scimeca, and H.J. Thompson, Conjugated Linoleic Acid. A Powerful Anticarcinogen from Animal Fat Sources, Cancer 74:1050-1054 (1994).
2. Lee, K.N., D. Kritchevsky, and M.W. Pariza, Conjugated Linoleic Acid and Atherosclerosis in Rabbits, Atherosclerosis 108:19-25 (1994).
3. Park, Y., K.J. Albright, W. Liu, J.M. Storkson, M.E. Cook, and M.W. Pariza, Effect of Conjugated Linoleic Acid on Body Composition in Mice, Lipids 32:853-858 (1997).
4. Garcia, H.S., J.M. Storkson, M.W. Pariza, and C.G. Hill, Enrichment of Butteroil with Conjugated Linoleic Acid via Enzymatic Interesterification (acidolysis) Reactions, Biotechnol. Lett. 20:393-395 (1998).
5. Arcos, J.A., C. Otero, and C.G. Hill, Rapid Enzymatic Production of Acylglycerols from Conjugated Linoleic Acid and Glycerol in a Solvent-Free System, Ibid. 30:617-621 (1998).
6. Martinez, C.E., J.C. Vinay, M.R. Brieva, C.G. Hill, and H.S. Garcia, Lipase-Catalyzed Interesterification (acidolysis) of Corn Oil and Conjugated Linoleic Acid in Organic Solvents, Food Biotechnol. 13:183-193 (1999).
7. Garcia, H.S., J.A. Arcos, D.J. Ward, and C.G. Hill, Jr., Synthesis of Glycerides Containing n-3 Fatty Acids and Conjugated Linoleic Acid by Solvent-Free Acidolysis of Fish Oil, Biotechnol. Bioeng. 70:587-591 (2000).
8. Torres, C.F., E. Barrios, and C.G. Hill, Jr., Lipase-Catalyzed Acidolysis of Menhaden Oil with CLA: Optimization by Factorial Design, J. Am. Oil Chem. Soc. 79:457-466 (2002).
9. Torres, C.F., F. Munir, L.P. Lessard, and C.G. Hill, Jr., Lipase-Mediated Acidolysis of Tristearin with CLA in a Packed-Bed Reactor: A Kinetic Study, Ibid. 79:655-661 (2002).
10. Akoh, C.C., Structured Lipids - Enzymatic Approach, inform 6:1055-1061 (1995).
11. Kim, I.H., C.S. Yoon, and K.W. Lee, Transesterification of Conjugated Linoleic Acid and Tricaprylin by Lipases in Organic Solvent, Food Res. Int. 34:301-306 (2001).
12. Kim, I.-H., C.-S. Yoon, S.-H. Cho, K.-W. Lee., S.-H. Chung, and B.-S Tae, Lipase Catalyzed Incorporation of Conjugated Linoleic Acid into Tricaprylin, J. Am. Oil Chem. Soc. 78:547-551 (2001).
13. Lee, K., and C.C. Akoh, Solvent-Free Enzymatic Synthesis of Structured Lipids from Peanut Oil and Caprylic Acid in a Stirred Tank Batch Reactor, Ibid. 75:1533-1537 (1998).
14. Ip, C., S.F. Chin, J.A. Scimeca, and M.W. Pariza, Mammary Cancer Prevention by Conjugated Dienoic Derivatives of Linoleic Acid, Cancer Res. 51:6118-6124 (1991).
15. McNeill, G.P., C. Rawlins, and A.C. Peilow, Enzymatic Enrichment of Conjugated Linoleic Acid Isomers and Incorporation into Triglycerides, J. Am. Oil Chem. Soc. 76:1265-1268 (1999).
16. Official Methods and Recommended Practices of the American Oil Chemists' Society, edited by D. Firestone, AOCS, Champaign, 1998, Methods Ca 5a-40, Cd 8-53, Cd 18-90, Ja 14-91, Cd 3-25.
17. Huang, K.-H., and C.C. Akoh, Lipase-Catalyzed Incorporation of n-3 Polyunsaturated Fatty Acids into Vegetable Oils, J. Am Oil Chem. Soc. 71:1277-1280 (1994).
18. Yankah, V.V., and C.C. Akoh, Lipase-Catalyzed Acidolysis of Tristearin with Oleic or Caprylic Acids to Produce Structured Lipids, Ibid. 77:495-500 (2000).
19. Reena, R., S. Divakar, and B.R. Lokesh, Plackett-Burman Design for Determining the Preference of Rhizomucor miehei Lipase for FA in Acidolysis Reactions with Coconut Oil, Ibid. 79:555-560 (2002).
20. Akoh, C.C., and C.O. Moussata, Characterization and Oxidative Stability of Enzymatically Produced Fish and Canola Oil-Based Structured Lipids, Ibid. 78:25-30 (2001).