Lipase-catalyzed interesterification (acidolysis) of corn oil and conjugated linoleic acid in organic solvents

Food Biotechnology

Volumn 13, Issue 2, 1999, Pages 183-193

  Martinez, Cecilia E ^a   Vinay, Julio C ^a   Brieva, Rosario ^b   Hill Jr , Charles G ^c   Garcia, Hugo S ^a  

^a INSTITUTO TECNOLÓGICO DE VERACRUZ   (Mexico)

^b UNIVERSITY OF OVIEDO   (Spain)

^c University of Wisconsin Madison   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ENZYME MECHANISM; ESTERIFICATION; FOOD ANALYSIS; FOOD PROCESSING; OIL PROCESSING; TRIACYLGLYCEROL LIPASE;

CANDIDA ANTARCTICA; MUCOR MIEHEI;

EID: 0032839134     PISSN: 08905436     EISSN: None     Source Type: Journal    
DOI: 10.1080/08905439909549970     Document Type: Article

References (22)

1. Arcos, J. A., Otero, C., and Hill, Jr. C. G. 1998. Rapid enzymatic production of acylglycerols from conjugated linoleic acid and glycerol in a solvent-free system. Biotechnology Letters 20(6): 617-621.
2. Belury, M. A., Nickel, K. P., Bird, C. E., and Wu, Y. 1996. Dietary conjugated linoleic acid modulation of phorbol ester skin tumor promotion. Nutrition and Cancer 26(2): 149-157.
3. Chin, S. F., Liu, W., Storkson, J. M., Ha, Y. L., and Pariza, M. W. 1992. Dietary sources of conjugated dienoic isomers of linoleic acid, a newly recognized class of anticarcinogens. Journal of Food Composition and Analysis 5: 185-197.
4. Chin, S. F., Storkson, J. M., Albright, K. J., Cook, M. E., and Pariza, M. W. 1994. Conjugated linoleic acid is a growth factor for rats as shown by enhanced weight gain and improved feed efficiency. Journal of Nutrition 124(12): 2344-2349.
5. Friedenauer, S. and Berlet, H. H. 1989. Sensitivity and variability of the Bradford protein assay in the presence of detergents. Analytical Biochemistry 178: 263-268.
6. Garcia, H. S., Storkon, J. M., Pariza, M. W., and Hill, C. G., Jr. 1998. Enrichment of butteroil with conjugated linoleic acid via enzymatic interesterification (acidolysis) reactions. Biotechnology Letters 20: 393-395.
7. Ha, Y. L., Storkson, J., and Pariza, M. W. 1990. Inhibition of benzo(a)pyrene-induced mouse forestomach neoplasia by conjugated dienoic derivatives of linoleic acid. Cancer Research 50: 1097-1101.
8. Ip, C., Briggs, S. P., Haegele, A. D., Thompson, H. J., Storkson, J., and Scimeca, J. A. 1990. The efficacy of conjugated linoleic acid in mammary cancer prevention is independent of the level or type of fat in the diet. Carcinogenesis 17(5): 1045-1050.
9. Ip, C., Chin, S. F., Scimeca, J. A., and Pariza, M. W. 1991. Mammary cancer prevention by conjugated dienoic derivative of linoleic acid. Cancer Research 51: 6118-6124.
10. Ip, C., Lisk, D. J., and Scimeca, J. A. 1994a. Potential of food modification in cancer prevention. Cancer Research (supplement) 54: 1957s-1959s.
11. Ip, C., Scimeca, J. A., and Thompson, H. J. 1994b. Conjugated linoleic acid. Cancer Supplement 74(3): 1050-1054.
12. Ip, C., Singh, M., Thompson, H. J., and Scimeca, J. A. 1994c. Conjugated linoleic acid suppresses mammary carcinogenesis and proliferative activity of the mammary gland in the rat. Cancer Research 54: 1212-1215.
13. Kepler, C. R., Hirons, K. P., McNeill, J. J., and Tove, S. B. 1966. Intermediates and products of the biohydrogenation of linoleic acid by Butyrivibrio fibrisolvens. Journal of Biological Chemistry 241(6): 1350-1354.
14. Kramer, J. K. G., Sehat, N., Dugan, M. E. R., Mossoba, M. M., Yurawecz, M. P., Roach, J. A. G., Eulitz, K., Aalhus, J. L., Schaefer, A. L., and Ku, Y. 1998. Distributions of conjugated linoleic acid (CLA) isomers in tissue lipid classes of pigs fed a commercial CLA mixture determined by gas chromatography and silver ion-high performance liquid chromatography. Lipids 33(6): 549-558.
15. Kvittingen, L. 1994. Some aspects of biocatalysts in organic solvents. Tetrahedron 50(28): 8253-8274.
16. Laane, C., Boeren, S., Hilhorst, R., and Veeger, C. 1987. Rules for optimization of biocatalysis in organic solvent. Biotechnology and Bioengineering 30: 81-87.
17. Lee, K. N., Kritchevsky, D., and Pariza, M. W. 1994. Conjugated linoleic acid and atherosclerosis in rabbits. Atherosclerosis 108: 19-25.
18. Li, Z.-Y., and Ward, O. P. 1993. Lipase-catalyzed esterification of glycerol and n-3 polyunsaturated fatty acid concentrate in organic solvent. Journal of the American Oil Chemists' Society 70(8): 745-748.
19. Parodi, P. W. 1994. Conjugated linoleic acid: an anticarcinogenic fatty acid present in milk fat. The Australian Journal of Dairy Technology 49: 93-97.
20. Parodi, P. W. 1996. Milk fat components: Possible chemopreventive agents for cancer and other diseases. The Australian Journal of Dairy Technology 51: 24-32.
21. Shultz, T. D., Chew, B. P., Seaman, W. R., and Luedecke, L. O. 1992. Inhibitory effect of conjugated dienoic derivatives of linoleic acid and beta-carotene on the in vitro growth of human cancer cells. Cancer Letters 63: 125-133.
22. Yang, B., Kuo, S.-J., Hariyadi, P., and Parkin, K. L. 1994. Solvent suitability for lipase-mediated acyltransfer and esterification reactions in microaqueous milieu is related to substrate and product polarities. Enzyme and Microbial Technology 16: 577-583.