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Volumn 108, Issue 35, 2004, Pages 7139-7146

Dynamical solvent control of electron transfer in a flexible, tethered donor - Acceptor pair

Author keywords

[No Author keywords available]

Indexed keywords

DYNAMICAL SOLVENT CONTROL; MARCUS THEORY; TIME-CORRELATED PHOTON COUNTING (TCPC); TIME-DEPENDENT STOKES SHIFTS (TDSS);

EID: 4444351255     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp048279j     Document Type: Article
Times cited : (6)

References (81)
  • 2
    • 4444241560 scopus 로고    scopus 로고
    • note
    • The following references only enumerate a few of the early papers in this area, and a few recent articles. For a recent review of electron-transfer theory, see ref 3.
  • 11
    • 4444221017 scopus 로고    scopus 로고
    • note
    • 5 have recently found that the methodology utilized in ref 8 is problematic. They derived a "generalized Zusman equation" in phase space that corrects these problems. Simulations utilizing the corrected theory are compared in ref 5 with Zusman's analytical expression, which is very similar to eq 1. The comparison demonstrates excellent agreement between theory and the analytical result in the moderate to strong damping regime. Mühlbacher and Egger have made a similar comparison in ref 9, and have prepared a "phase diagram" that parametrizes the conditions under which eq 1 is expected to hold.
  • 70
    • 4444350180 scopus 로고    scopus 로고
    • note
    • In ref 69. Mataga and co-workers have suggested that the LH state emits at wavelengths longer than the SH emission. We have not observed this emission in polar solvents.
  • 74
    • 4444332119 scopus 로고    scopus 로고
    • note
    • We have tested this assumption in polar and nonpolar viscous liquids, in which the probability of electron transfer is exceedingly small, and we find that APP is indeed a good model for the ADMA fluorescence spectrum and lifetime in the absence of electron transfer.
  • 78
    • 4444375721 scopus 로고    scopus 로고
    • note
    • The assumption that the fast decay time is equal to the electron-transfer time is questionable for octanol and decanol as discussed in Section III, and therefore these data points were not utilized for the linear regression analysis.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.