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Volumn 118, Issue 1, 2003, Pages 291-303

The role of different reorganization energies within the Zusman theory of electron transfer

Author keywords

[No Author keywords available]

Indexed keywords

APPROXIMATION THEORY; ELECTRON TUNNELING; NUMERICAL METHODS; PARTIAL DIFFERENTIAL EQUATIONS; RATE CONSTANTS; SOLVENTS;

EID: 0037260920     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1525799     Document Type: Article
Times cited : (25)

References (37)
  • 1
    • 0011526199 scopus 로고    scopus 로고
    • Electron transfer: From isolated molecules to biomolecules
    • edited by J. Jortner and M. Bixon
    • Electron Transfer: From Isolated Molecules to Biomolecules, edited by J. Jortner and M. Bixon, Adv. Chem. Phys. 106 (Part I) (1999)
    • (1999) Adv. Chem. Phys. , vol.106 , Issue.PART I
  • 2
    • 0013020045 scopus 로고    scopus 로고
    • 107 (Part II) (1999).
    • (1999) Adv. Chem. Phys. , vol.107 , Issue.PART II
  • 34
    • 0012915733 scopus 로고    scopus 로고
    • Note
    • It should be noted, however, that our new results are only valid for sufficiently small reorganization energies. The use of Zusman equations beyond the contract approximation should thus be restricted to similar cases. On the other hand, the contact approximation results (Refs. 15 and 18) can be extrapolated onto the case of large reorganization energies. These earlier results are consistent with the detailed balance relation (for nonadiabatic to solvent controlled adiabatic ET) and do not yield such nonphysical features as negative reaction rates.
  • 35
    • 0012968043 scopus 로고    scopus 로고
    • Note
    • 2)]}, which is obviously positive for t>0.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.