Methanol-inhibitor or promoter of the formation of gas hydrates from deuterated ice?

American Mineralogist

Volumn 89, Issue 8-9, 2004, Pages 1208-1214

  Bobev, Svilen ^a   Tait, Kimberly T ^a  

^a LOS ALAMOS NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON DIOXIDE; DEUTERIUM; HYDRATION; ICE; KINETICS; METHANOL;

HYDRATE FORMATION; ISOTOPIC COMPOSITION; KINETIC PROMOTERS; KINETIC STUDY; ORDERS OF MAGNITUDE; PRESSURE AND TEMPERATURE; THERMODYNAMIC INHIBITORS; TIME-OF-FLIGHT NEUTRON POWDER DIFFRACTION;

GAS HYDRATES;

CLATHRATE; FORMATION MECHANISM; GAS HYDRATE; METHANOL; REACTION RATE;

EID: 4444281331     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am-2004-8-907     Document Type: Article

References (35)

1. Blake, D., Allamandola, L., Sandford, S., Hudgins, D., and Freund, F. (1991) Clathrate hydrate formation in amorphous cometary ice analogs in vacuo. Science, 254, 548-551.
2. 4 hydrate. Journal of Physical Chemistry B, 107, 5529-5539.
3. Davidson, D.W. and Ripmeester, J.A. (1984) NMR, NQR, and dielectric properties of clathrates. In J.E.D. Davies and D.D. MacNichol, Eds., Inclusion Compounds, Vol. 3, Chapter 3. Academic Press, New York.
4. Halpern, Y., Thieu, V., Henning, R.W., Wang, X.P., and Schultz, A.J. (2001) Time-resolved in situ neutron diffraction studies of gas hydrate: Transformation of structure II (sII) to structure I (sI). Journal of the American Chemical Society, 123, 12826-12831.
5. 2 clathrate hydrate: Formation from deuterated ice. Journal of Physical Chemistry A, 104, 5066-5071.
6. 2 emissions in the deep ocean. Environmental Progress, 10, 64-74.
7. Hwang, M.J., Wright, D.A., Kapur, A., and Holder, G.D. (1990) An experimental-study of crystallization and crystal-growth of methane hydrates from melting ice. Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, 8, 103-116.
8. Koga, Y., Siu, W.Y.W., and Wong, T.Y.H. (1990) Transition of short-range to medium-range order in aqueous-solution of 2-butoxyethanol. Journal of Physical Chemistry, 94, 3879-3881.
9. Koga, K., Tanaka, H., and Nakanishi, K. (1994) Stability of polar guest-encaging clathrate hydrates. Journal of Physical Chemistry, 101, 3127-3134.
10. Koh, C. A., Savidge, J.L., and Tang, C.C. (1996) Time-resolved in-situ experiments on the crystallization of natural gas hydrates. Journal of Physical Chemistry A, 100, 6412-6414.
11. th National Meeting of the American Chemical Society, San Francisco. American Chemical Society, Washington, D.C.
12. Koh, C.A., Westcott, R.E., Zhang, W., Hirachand, K., Creek, J.L., and Soper, A.K. (2002) Mechanisms of gas hydrate formation and inhibition. Fluid Phase Equilibria, 194, 143-151.
13. nd International Conference on Natural Gas Hydrates, Toulouse, France. Institute National Polythechnique, Toulouse, France.
14. Larson, A.C. and Von Dreele, R.B. (1994) GSAS-General Structure Analysis System. LAUR 86-748, Los Alamos National Laboratory, New Mexico.
15. Majumdar, A., Mahmoodaghdan, E., and Bishnoi, P.R. (2000) Equilibrium hydrate formation conditions for hydrogen sulfide, carbon dioxide, and ethane in aqueous solutions of ethylene glycol and sodium chloride. Journal of Chemical and Engineering Data, 45, 20-22.
16. Mak, T.C. and McMullan, R.K. (1965) Polyhedral clathrate hydrates X. Structure of double hydrate of tetrahydrofuran and hydrogen sulfide. Journal of Chemical Physics, 42, 2732-2740.
17. McMullan, R.K. and Jeffrey, G.A. (1965) Polyhedral clathrate hydrates 0.9 structure of ethylene oxide hydrate. Journal of Chemical Physics, 42, 2725-2733.
18. Mei, D.-H., Liao, J., Yang, J.-T., and Guo, T.-M. (1996) Experimental and modeling studies on the hydrate formation of a methane plus nitrogen gas mixture in the presence of aqueous electrolyte solutions. Industrial and Engineering Chemistry Research, 35, 4342-4347.
19. Mittal, K.L. (1977) Micellization, Solubilization and Microemulsions, Vol. 1. Plenum Press, New York.
20. Murthy, S.S.N. (1999) Detailed study of ice clathrate relaxation: Evidence for the existence of clathrate structures in some water-alcohol mixtures. Journal of Physical Chemistry A, 103, 7927-7937.
21. Myers, D. (1988) Surfactant Science and Technology. VCM Publishers, New York.
22. 2 clathrate formation and its properties in the simulated deep ocean. Energy Conversion and Management, 33, 651-657.
23. 2 as a small-cage guest. Energy and Fuels, 12, 197-200.
24. Roux, G., Perron, G., and Desnoyers, J.E. (1978) Heat-capacity evidence for pseudo-phase transitions in aqueous organic binary-systems. Journal of Physical Chemistry, 82, 966.
25. Saji, A., Yoshida, H., Sakai, M., Tanii, T., Kamata, T., and Kitamura, H. (1992) Fixation of carbon-dioxide by clathrate-hydrate. Energy Conversion and Management, 33, 643-649.
26. Sloan, E.D. (1998a) Clathrate Hydrates of Natural Gases, 2nd ed. Marcel Dekker, New York, and the references therein.
27. Sloan, E.D. (1998b) Gas hydrates: Review of physical/chemical properties. Energy and Fuels, 12, 191-196.
28. Staykova, D.K., Kuhs, W.F., Salamatin, A.N., and Hansen, T. (2003) Formation of porous gas hydrates from ice powders: diffraction experiments and multistage model. Journal of Physical Chemistry B, 107, 10299-10311.
29. Stern, L.A., Kirby, S.H., and Durham, W.B. (1996) Peculiarities of methane clathrate hydrate formation and solid-state deformation, including possible superheating of water ice. Science, 273, 1843-1848.
30. Stern, L.A., Hogenboom, D.L., Durham, W.B., Kirby, S.H., and Chou, I-M. (1998a) Optical cell evidence for superheated ice under gas-hydrate-forming conditions. Journal of Physical Chemistry B, 102, 2627-2632.
31. Stern, L.A., Kirby, S.H., and Durham, W.B. (1998b) Polycrystalline methane hydrate: synthesis from superheated ice, and low-temperature mechanical properties. Energy and Fuels, 12, 201-211.
32. Subramanian, S. and Sloan, E.D. (1999) Molecular measurements of methane hydrate formation. Fluid Phase Equilibria, 158-160, 813-820.
33. 2 hydrate by X-ray diffraction. In G. Holder and P. Bishnoi, Eds., Gas Hydrates: Challenges for the Future, p. 973-982. New York Academy of Sciences, New York.
34. Wang, X.P., Schultz, A.J., and Halpern, Y. (2002) Kinetics of methane hydrate formation from polycrystalline deuterated ice. Journal of Physical Chemistry A, 106, 7304-7309.
35. Williams, K.D. and Devlin, J.P. (1997) Formation and spectra of clathrate hydrates of methanol and methanol-ether mixtures. Journal of Molecular Structure, 416, 277-286.