Field sampling method for quantifying odorants in humid environments

Environmental Science and Technology

Volumn 42, Issue 10, 2008, Pages 3745-3750

  Trabue, Steven L ^a   Scoggin, Kenwood D ^a   Li, Hong ^b   Burns, Robert ^b   Xin, Hongwei ^b  

^a AGRICULTURAL RESEARCH SERVICE   (United States)

^b Iowa State University of Science and Technology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC HUMIDITY; DESORPTION; MOLECULAR SIEVES; THERMAL EFFECTS;

CARBON MOLECULAR SIEVE (CMS); SEMIVOLATILE ORGANIC COMPOUNDS (SVOC);

AIR QUALITY;

4 ETHYLPHENOL; BUTYRIC ACID; INDOLE; ORGANIC COMPOUND; PARA CRESOL; SEMIVOLATILE ORGANIC COMPOUND; SKATOLE; SORBENT; VOLATILE AGENT;

AIR QUALITY; ATMOSPHERIC HUMIDITY; DESORPTION; MOLECULAR SIEVES; THERMAL EFFECTS;

AIR QUALITY; AIR SAMPLING; CARBON; DESORPTION; DETECTION METHOD; FATTY ACID; FIELD METHOD; HEATING; HUMID ENVIRONMENT; ODOR; PHENOL; PIG; POULTRY; RELATIVE HUMIDITY; SORPTION; VOLATILE SUBSTANCE;

AIR QUALITY; ARTICLE; ATMOSPHERE; CARBON MOLECULAR SIEVE TUBE; ENVIRONMENTAL TEMPERATURE; GRAPHITIZED CARBON TUBE; HEATING; HUMIDITY; ODOR; POULTRY; REPRODUCIBILITY; SAMPLING; SWINE; TENAX TUBE; TUBE; WATER ABSORPTION;

GAS CHROMATOGRAPHY-MASS SPECTROMETRY; HUMIDITY; ODORS; ORGANIC CHEMICALS; VOLATILIZATION;

SUIDAE;

EID: 43749118526     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es7031407     Document Type: Article

References (39)

1. National Research Council. Air Emission from Animal Feeding Operations Current Knowledge Future Needs; The National Academies Press: Washington,D.C., 2003.
2. Animal feeding operations consent agreement and final order. Fed. Regist. 200570, 4958-4977.
3. Zahn, J.; Hatfield, J. Y; Do, A.; DiSpirito; Laird, D.; Pfeiffer, R. Characterization of volatile organic emissions and wastes from a swine production facility. J. Environ. Qual. 1997, 26, 1687-1696.
4. Schiffman, S.; Bennett, I.; Raymer, J. Quantification of odors and odorants from swine operations in North Carolina. Agric. For. Meteorol. 2001, 108, 213-240.
5. Zahn, J.; Hatfield; Laird, D; Hart, T; Do, Y.; DiSpirito, A. Functional classification of swine manure management systems based on effluent and gas emission characteristics. J. Environ. Qual. 2001, 30, 635-642.
6. Rabud, N.; Ebeler, S.; Ashaugh, L.; Flocchini, R. 2003. Characterization and quantification of odorous and non-odorous volatile organic compounds near a commercial dairy in California. Atmos. Environ. 2003, 37, 933-940.
7. Blunden, J.; Aneja, V.; Lonneman, W. Characterization of non-methane volatile organic compounds at swine facilities in eastern North Carolina. Atmos. Environ. 2005, 39, 6707-6718.
8. Filipy, J.; Rumburg, B.; Mount, G; Westberg, H.; Lamb, B. Identification and quantification of volatile organic compounds from a dairy. Atmos. Environ. 2006, 40, 1480-1494, 2006.
9. Thu, K.; Donham, K; Ziegenhorn, R; Reynolds, S; Thorne, P; Subramanian, P; Whiten, P.; Stookesberry, J. A control study of the physical and mental health of residents living near a large-scale swine operation. J. Agric. Saf. Health 1997, 3, 13-26.
10. Wing, S.; Wolf, S. Intensive livestock operations, health, and quality of life among eastern North Carolina residents. Environ. Health Perspect. 2000, 108, 233-238.
11. Palmquist, R.; Roka, F.; Vukina, T. Hog operations, environmental effects, and residential property values. Land Economics 1997, 73, 114-124.
12. Schiffman, S.; Williams, C. Science of odor as a potential health issue. J. Environ. Qual. 2005, 34, 129-138.
13. Schiffman, S.; Studwell, C.; Landerman, L.; Berman, K.; Sundy, J. Symptomatic effects of exposure to diluted air sampled from a swine confinement atmosphere on healthy human subjects. Environ. Health Perspect. 2005, 113, 567-576.
14. Koziel, J.; Spinhirne, J; Lloyd, J; Parker, D; Wright, D.; Kuhrt, F. Evaluation of sample recovery of malodorous livestock gases from air sampling bags, solid phase microextraction fibers, Tenax TA sorbent tubes, and sampling canisters. J. Air Waste Manage. Assoc 2005, 55, 1147-1157.
15. Namiesnick, J; Gorlo, D.; Walska, L; Zygmunt, B. Analysis of selected gaseous organic micro-pollutants in air by means of solid phase microextraction gas chromatography mass spectrometry, calibration problems. Analysis 1998, 26, 170-174.
16. Namiesnick, J.; Jastrzebska, A. ]?〉; Zygmunt, B. Determination of volatile aliphatic amines in air by solid-phase microextraction coupled with gas chromatography with flame ionization detection. J. Chromatogr., A. 2003, 1016, 1-9.
17. Lestremau, F.; Andersson, F. A. T.; Desauziers, V.; Fanlo., J. L. Evaluation of solid-phase microextraction for time-weighted average sampling of volatile sulfur compounds at ppb concentrations. Anal. Chem. 2003, 75, 2626-2632.
18. Helmig, D.; Vierling, L. Water adsorption capacity of the solid adsorbents Tenax TA, Tenax GR, Carbotrap, Carbotrap C, Carbosieve SIII, and Carboxen 569 and water management techniques for the atmospheric sampling of volatile organic trace gases. Anal. Chem. 1995, 67, 4380-4386.
19. Gawlowski, J.; Gierczak, T; Jezo, A.; Niedzielski., J. Adsorption of water vapour in the solid sorbents used for the sampling of volatile organic compounds. Analyst 1999, 124, 1553-1558.
20. Fastyn, P.; Kornacki, W; Kardas, M; Gawlosski, J.; Niedzielski, J. Adsorption of water vapour from humid air in carbon molecular sieves: Carbosieve S-III and Carboxen 569, 1000, and 1001. Analyst 2003, 128, 198-203.
21. Fastyn, P.; Kornacki, W; Kardas, M; Gawlosski, J.; Niedzielski., J. Adsorption of water vapour from humid air by selected carbon adsorbents. J. Chromtogr., A. 2005, 1078, 7-12.
22. MacLeod, G.; Ames, J. Comparative assessment of the artifact background on thermal desorption of Tenax GC and Tenax TA. J. Chromatrogr. 1986, 393, 398.
23. Lee, J. H.; Batterman, S; Jia, C.; Chernyak, S. Ozone artifacts and carbonyl measurements using Tenax GR, Tenax TA, Carbopack B, and Carbopack X adsorbents. J. Air Waste Manage. Assoc. 2006, 56, 1503-1517.
24. McClenny, W. H.; Jacumin, K; Oliver, E.; Daughtrey, D.; Whitaker. Comparison of 24 h averaged VOC monitioring results for residential indoor and outdoor air using Carbopack X-filled diffusive samplers and active sampling - A pilot study. J. Environ. Monitor. 2006, 8, 263-269.
25. Strandberg, B.; Sunesson, A.; Sundgren, M; Levin, J; Sallsten, G.; Barregard, L. Field evaluation of two diffusive samplers and two adsorbent media to determine 1,2-butadiene and benzene levels in air. Atmos. Environ. 2006, 40, 7686-7695.
26. Odam, E. M., Page, J. Townsend M. G., and Wilkins J. Identification of volatile components in heaspace from animal slurries. In Odour Prevention and Control of Organic Sludge and Livestock Farming, Nielsen, V. C., Voorburg, J. H., L'Hermite, P., Eds.; Elsevier Applied Science: New York, 1986.
27. Guidance for Industry: Bioanlytical Method Validation, U.S. Department of Health and Human Services, Food and Drug Administration, Rockville, MD; May, 2001; http://www.fda.gov/cder/guidance/4252fnl.pdf. (verified February 8, 2008).
28. Brennan, J.; Bandosz, T; Thomson, K.; Gubbins, K. Review: Water in porous carbons. Colloids Surf. 2001, 187-188, 539-568.
29. 14 hydrocarbons involved in photochemical smog formation. J High Resolut Chromatogr. 1992, 15, 75-84.
30. Woolfenden, E. Monitoring VOCs in air using sorbent tubes followed by thermal desorption-capillary GC analysis: summary of data and practical guidelines. J. Air Waste Manage. Assoc. 1997, 47, 20-36.
31. Rabud, N.; Ebeler, S.; Ashaugh, L.; Flocchini, R. The application of thermal desorption GC/MS with simultaneous olfactory evaluation for the characterization and quantification of odor compounds from a dairy. J. Agric. Food Chem. 2002, 50, 5139-5145.
32. Gawrys, M.; Fastyn, P.; Gawloski, J.; Gierczak, T.; Niedzielski, J. Prevention of water vapour adsorption by carbon molecular sieves in sampling humid gases. J. Chromtogr., A. 2001, 933, 107-116.
33. Martin, N.A.; Duckworth, P; Henderson, M. H.; Swann, N. R. W.; Granshaw, S. T.; Lipscombe, R. P.; Goody, B. A. Measurements of environmental 1,3-butadiene with pumped and diffusive samplers using the sorbent Carbopack X. Atmos. Environ. 2005, 39, 1069-1077.
34. Ribes, A.; Carrera, G; Gallego, E; Roca, X; Berenguer, M.; Guardino, X. Development and validation of a method for air-quality and nuisance odors monitoring of volatile organic compounds using multi-sorbent adsorption and gas chromatography/mass spectrometry thermal desorption system. J. Chromtogr., A. 2007, 1140, 44-55.
35. Cai, L.; Koziel, J.; Liang, Y; Nguyen, A.; Xin, H. Evaluation of zeolite for control of odorants emissions from simulated poultry manure storage. J. Environ. Qual. 2007, 36, 184-193.
36. Zahn, J.; DiSpirito, A.; Do, Y; Brooks, B; Cooper, E.; Hatfield, J. Correlation of human olfactory responses to airborne concentrations of malodorous volatile organic compounds emitted from swine effluent. J. Environ. Qual. 2001, 30, 624-634.
37. Lim, T-T.; Heber, A; Ni, J.-Q; Sutton, A.; Shao, P. Odor and gas release from anaerobic treatment lagoons for swine manure. J. Environ. Qual. 2003, 32, 406-416.
38. Kornacki, W.; Fastyn, P.; Gawlowski, J; Gierczak, T.; Niedzielski, J. Chemical transformation of alcohols sampled with the use of adsorptive enrichment on the carbon adsorbent traps followed by thermal desorption. Analyst 2005, 130, 632-636.
39. Devos,M; Patte, F.; Rouault, J.; Laffort, P.; Van Gemert, L. Standardized Human Olfactory Thresholds; IRI Press at Oxford University Press: New York, 1990.