Extended metal atom chains (EMACs) of five chromium or cobalt atoms: Symmetrical or unsymmetrical?

Dalton Transactions

Volumn , Issue 15, 2004, Pages 2297-2302

  Berry, John F ^a   Cotton, F Albert ^a   Fewox, Christopher S ^a   Lu, Tongbu ^a,b   Murillo, Carlos A ^a   Wang, Xiaoping ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

^b SUN YAT SEN UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; COBALT; COMPLEXATION; OXIDATION; QUANTUM THEORY; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL);

EXTENDED METAL ATOM CHAINS (EMAC); LIGANDS; STRUCTURAL MOTIFS;

CHROMIUM;

EID: 4344675332     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/b405629a     Document Type: Article

References (43)

1. J. F. Berry, F. A. Cotton, P. Lei, T. Lu and C. A. Murillo, Inorg. Chem., 2003, 42, 3534.
2. A. P. Alivisatos, Science, 1996, 271, 933.
3. Nanoscale Materials Special Issue, ed. J. M. Heath, Acc. Chem. Res. 1999, 32.
4. (a) S. Aduldecha and B. Hathaway, J. Chem. Soc., Dalton Trans., 1991, 993;
5. (b) R. Clérac, F. A. Cotton, K. R. Dunbar, C. A. Murillo, I. Pascual and X. Wang, Inorg. Chem., 1999, 38, 2655.
6. (a) G. J. Pyrka, M. El-Mekki and A. A. Pinkerton, J. Chem. Soc., Chem. Commun., 1991, 84;
7. (b) L.-P. Wu, P. Field, T. Morrissey, C. Murphy, P. Nagle, B. Hathaway, C. Simmons and P. Thornton, J. Chem. Soc., Dalton Trans., 1990, 3835;
8. (c) J. F. Berry, F. A. Cotton, P. Lei and C. A. Murillo, Inorg. Chem., 2003, 42, 377.
9. (a) E.-C. Yang, M.-C. Cheng, M.-S. Tsai and S.-M. Peng, J. Chem. Soc., Chem. Commun., 1994, 2377;
10. (b) F. A. Cotton, L. M. Daniels and G. T. Jordan, IV, Chem. Commun., 1997, 421.
11. F. A. Cotton, L. M. Daniels, C. A. Murillo and I. Pascual, J. Am. Chem. Soc., 1997, 119, 10223.
12. (a) J. T. Sheu, C.-C. Lin, I. Chao, C.-C. Wang and S.-M. Peng, Chem. Commun., 1996, 315;
13. (b) J. F. Berry, F. A. Cotton and C. A. Murillo, Inorg. Chim. Acta, accepted.
14. S.-J. Shieh, C.-C. Chao, G.-H. Lee, C.-C. Wang and S.-M. Peng, Angew. Chem., Int. Ed., 1997, 36, 56.
15. J. F. Berry, F. A. Cotton, P. Lei, T. Lu and C. A. Murillo, Inorg. Chem., 2003, 42, 3534.
16. (a) S.-Y. Lai, T.-W.Lin, Y.-H. Chen, C.-C. Wang, G.-H. Lee, M.-H. Yang, M.-K. Leung and S.-M. Peng, J. Am. Chem. Soc., 1999, 121, 250;
17. (b) S.-M. Peng, C.-C. Wang, Y.-L. Jang, Y.-H. Chen. F.-Y. Li, C.-Y. Mou and M.-K. Leung, J. Magn. Magn. Mater., 2000, 209, 80.
18. J. F. Berry, F. A. Cotton, L. M. Daniels, C. A. Murillo and X.Wang, Inorg. Chem., 2003, 42, 2418.
19. (a) M.-M. Rohmer and M. Bénard, J. Am. Chem. Soc., 1998, 120, 9372;
20. (b) M.-M. Rohmer, A. Stirch, M. Bénard and J.-P. Malrieu, J. Am. Chem. Soc., 2001, 123, 9126;
21. (c) N. Benbellat, M.-M. Rohmer and M. Bénard, Chem. Commun., 2001, 2368;
22. (d) M.-M. Rohmer and M. Bénard, J. Cluster Sci., 2002, 13, 333.
23. See for example: (a) N. Robertson and C. A. McGowan, Chem. Soc. Rev., 2003, 32, 96; (b) J. M. Tour, Acc. Chem. Res., 2000, 33, 791; (c) R. L. Carroll and C. B. German, Angew. Chem., Int. Ed., 2002, 41, 4378.
24. See for example: (a) N. Robertson and C. A. McGowan, Chem. Soc. Rev., 2003, 32, 96; (b) J. M. Tour, Acc. Chem. Res., 2000, 33, 791; (c) R. L. Carroll and C. B. German, Angew. Chem., Int. Ed., 2002, 41, 4378.
25. See for example: (a) N. Robertson and C. A. McGowan, Chem. Soc. Rev., 2003, 32, 96; (b) J. M. Tour, Acc. Chem. Res., 2000, 33, 791; (c) R. L. Carroll and C. B. German, Angew. Chem., Int. Ed., 2002, 41, 4378.
26. (a) J. F. Berry, F. A. Cotton, T. Lu, C. A. Murillo and X. Wang, Inorg. Chem., 2003, 42, 3595;
27. (b) J. F. Berry, F. A. Cotton, T. Lu and C. A. Murillo, Inorg. Chem., 2003, 42, 4425.
28. R. Clérac, F. A. Cotton, L. M. Daniels, K. R. Dunbar, K. Kirschbaum, C. A. Murillo, A. A. Pinkerton, A. J. Schultz and X. Wang, J. Am. Chem. Soc., 2000, 122, 6226.
29. (a) R. Clérac, F. A. Cotton, L. M. Daniels, K. R. Dunbar, C. A. Murillo and I. Pascual, Inorg. Chem., 2000, 39, 748;
30. (b) J. F. Berry, F. A. Cotton, T. Lu, C. A. Murillo, B. K. Roberts and X. Wang, J. Am. Chem. Soc., 2004, 126, 7082.
31. F. A. Cotton, L. M. Daniels, T. Lu, C. A. Murillo and X. Wang, J. Chem. Soc., Dalton Trans., 1999, 517.
32. H.-C. Chang, J.-T. Li, C.-C. Wang, T.-W. Lin, H.-C. Lee, G.-H. Lee and S.-M. Peng, Eur. J. Inorg. Chem., 1999, 1243.
33. F. A. Cotton, L. M. Daniels, C. A. Murillo, X. Wang and C. A. Murillo, Chem. Commun., 1999, 2461.
34. Y.-H. Chen, C.-C. Lee, C.-C. Wang, G.-H. Lee, S.-Y. Lai, F.-Y. Li, C.-Y. Mou and S.-M. Peng, Chem. Commun., 1999, 1667.
35. S.-Y. Lin, I.-W. P. Chen, C.-h. Chen, M.-H. Hsieh, C.-Y. Yen, T.-W. Lin, Y.-H. Chen and S.-M. Peng, J. Phys. Chem. B, 2004, 108, 959.
36. Similar reactions of fluorinated anions have been noted before. See for example: R. Clérac, F. A. Cotton, L. M. Daniels, K. R. Dunbar, C. A. Murillo and I. Pascual, Inorg. Chem., 2000, 39, 752.
37. C.-Y. Yeh, C.-H. Chou, K.-C. Pan, C.-C. Wang, G.-H. Lee, Y.-O. Su and S.-M. Peng, J. Chem. Soc., Dalton Trans., 2002, 2670.
38. R. E. Peierls, Quantum Theory of Solids, Oxford University Press, Oxford, 1955, p. 108.
39. This is a well-known phenomenon in physics. See for example: Extended Linear Chain Compounds, ed. J. S. Miller, Plenum Press, New York, 1982, vol. 2.
40. SMART, Software for the CCD Detector System, V5.618, Bruker Analytical X-Ray Systems, Inc., Madison, WI, USA.
41. SAINT, Data Reduction Software. V6.45, Bruker Analytical X-Ray Systems, Inc., Madison, WI, USA.
42. SADABS, Bruker/Siemens Area Detector Absorption and Other Corrections. V2.05, Bruker Analytical X-ray Systems, Inc., Madison, WI, USA.
43. G. M. Sheldrick, SHELXL, V6.12., Bruker Analytical X-ray Systems, Inc., Madison, WI, USA.