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43149104285
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A solution of (iPr2PTe)2NNa·TMEDA (0.417 g, 0.648 mmol) in THF (10 mL) was added via cannula to a solution of NiBr2·DME (0.100 g, 0.324 mmol) in THF (20 mL) at 23°C. A color change from pink to brown occurred immediately upon the addition. The solution was allowed to stir for 1 h before the solvent was removed in vacuo. Fresh THF (10 mL) was added and, after filtration, hexane (25mL) was added, and this was left overnight to recrystallize. Complex 3 was obtained as brown crystals (0.259 g, 75, after 16 h at -35°C. Anal. Found (calcd) for C 24H56N2NiP4Te4, C, 27.34 (27.05, H, 5.38 (5.30, N, 2.68 (2.63, 31P{1H} NMR: δ 32.1 (s, 1J(P,Te, 1365 Hz, 3J(P,Te, 142 Hz, 873.2(s, 125Te{1H} NMR: δ-466 (dt, 1J(P,Te, 1362 Hz, 3JP,T
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1H} NMR: δ -621.6 (s).
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0001912547
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Cupertino, D.1
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Woollins, J.D.4
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31
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37049075202
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16144368861
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0035796212
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Simon-Manso, E.1
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34250882739
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Brandl, M.1
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Vigier-Juteau, E.6
Zabel, M.7
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35
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0037504087
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Hsieh, C. H.; Hsu, I. J.; Lee, C. M.; Ke, S. C.; Wang, T. Y.; Lee, G. H.; Wang, Y.; Chen, J. M.; Lee, J. F.; Liaw, W. F. Inorg. Chem. 2003, 42, 3925-3933.
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Hsieh, C.H.1
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Lee, G.H.6
Wang, Y.7
Chen, J.M.8
Lee, J.F.9
Liaw, W.F.10
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36
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Td) in each case.
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Td) in each case.
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37
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0002185640
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Birdsall, D. J.; Novosad, J.; Slawin, A. M. Z.; Woollins, J. D. J. Chem. Soc., Dalton Trans. 2000, 435-439.
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Birdsall, D.J.1
Novosad, J.2
Slawin, A.M.Z.3
Woollins, J.D.4
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38
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43149106093
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d and SP isomers of complex 2.
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d and SP isomers of complex 2.
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