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Regarding the behavior of the calculated SF 6- potential curve near the SF6 equilibrium, where it lies above the SF6 curve, it is worth quoting Ref.: "There is no justification whatever for assuming that such a curve determines, for example, the position of some quasistationary state.... "
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Below 90 meV the experimental attachment cross section is described accurately by σatt =σ/ε [1-exp (-βε)], where σ=7130 2 meV, β=0.405 meV-1/2, and the electron energy ε is in meV.
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This wave function matches the standard harmonic oscillator eigenstates used in deriving Eq. 10.
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This wave function matches the standard harmonic oscillator eigenstates used in deriving Eq. 10.
-
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-
|