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4a: mp 63-05 °C; IR (KBr, 1609 cm-1 (aromatic C=C, 1667 (C=O, 1059, N-C=O, 3299, COOH) cm-1; 1H NMR (DMSOd6, δ 6.8- 7.6 (m, 12H, Ar-H, 2.9 (d, Ha, CH, 2.5 (d, Hb, CH, 12.2 (s, COOH, 2.0 (a, CH2) Anal. Calcd for C23H17O4NFCl (426, C, 68.48; H, 4.07; N, 3.80. Found: C, 68.38; H, 4.02; N, 3.75. 4b: mp 85-87 °C; IR (KBr, 1620 cm-1 (aromatic C=C, 1681 (C=O, 1059, N-C=O, 3344, COOH) cm-1; 1H NMR (DMSO-d6, δ 6.4- 7.7 (m, 12H Ar-H, 2.8 (d, Ha CH, 3.5 (d, Hb, CH, 12.1 (s, COOH, 2.2 (s, CH2).Anal. Calcd for C23H17O5NFCl (442, C, 65.79; H, 3.91; N, 3.65. Found: C, 65.59; H, 3.86. N, 3.62. 4c: mp 71-73 °C; IR (KBr);1637 cm-1 (aromatic C=C, 1651 (C=O, 1031, N-C=O, 3234, COOH)'cm-1; 1H NMR
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2FCl (486): C, 58.74; H, 3.26, N, 6.53. Found: C, 58.32; H, 3.11; N, 6.32.
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