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In the de-intercalated sample, the π + σ plasmon is still at the higher energy compared with that of the pristine. One reason is the de-intercalation temperature (500°C) is not high enough to achieve a complete recovery of the pristine sample but the trends show that the de-intercalation process is essentially reversible. Furthermore, in electron diffraction we observe a recovery of the original pattern concomitant with a higher background which might be due to reasons like a partial decomposition of the sample upon the heat treatment. This can also explain the incomplete recovery of the π+ σ plasmon in the low energy loss function.
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