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Treatment of 1-Cl with KF under similar conditions resulted in full recovery of the starting material, indicating that transfer of alkyl groups does not occur under these conditions.
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Treatment of 1-Cl with KF under similar conditions resulted in full recovery of the starting material, indicating that transfer of alkyl groups does not occur under these conditions.
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Not surprisingly, these intermolecular reactions proceed considerably more slowly at the temperature of 45°C used for the synthesis of compounds 2-R.
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Not surprisingly, these intermolecular reactions proceed considerably more slowly at the temperature of 45°C used for the synthesis of compounds 2-R.
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Indeed, the mixture with KF in the absence of 18-crown-6 remains turbid throughout the reaction, indicating the presence of insoluble potassium salts.
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Indeed, the mixture with KF in the absence of 18-crown-6 remains turbid throughout the reaction, indicating the presence of insoluble potassium salts.
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62
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For recent examples of anion binding to organoboranes see: a
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