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Volumn 10, Issue 15, 2004, Pages 3632-3639

Thermodynamic stability of hydrogen-bonded nanostructures: A calorimetric study

Author keywords

Calorimetry; Hydrogen bonds; Polar solvents; Self assembly; Thermodynamics

Indexed keywords

CALORIMETRY; HYDROGEN BONDS; PARAMETER ESTIMATION; SELF ASSEMBLY; STOICHIOMETRY; THERMODYNAMICS;

EID: 4243117260     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200400085     Document Type: Article
Times cited : (32)

References (52)
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    • G.
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    • note
    • -1).
  • 43
    • 4243169609 scopus 로고    scopus 로고
    • note
    • For a detailed description of the ITC experiments see the Experimental Section.
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    • note
    • -8.
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    • 4243153395 scopus 로고    scopus 로고
    • note
    • 6) for double rosette assemblies.
  • 47
    • 4243128682 scopus 로고    scopus 로고
    • note
    • The broken line in the EEC plot describes the behavior when the enthalpy changes are completely compensated by entropy changes. Beneath this line ΔG° < 0, and above it ΔG° > 0. At the point where the experimental line (solid) crosses the broken line Δ° = TΔS° and TΔG° = 0.
  • 49
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    • note
    • N scale ranges from 0 for TMS, the least polar solvent, to 1 for water, the most polar solvent.
  • 50
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    • note
    • Possibly the hydrophobic surface of the assembly is better solvated by the methyl groups of methanol and therefore results in less competition in hydrogen bonding.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.