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The nature of the hydrogen bond depends on the distance between the donor (D) and acceptor (A) atoms, which in turn is dependent on their electronegativities.
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4243169609
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For a detailed description of the ITC experiments see the Experimental Section.
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44
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4243103289
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45
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6) for double rosette assemblies.
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The broken line in the EEC plot describes the behavior when the enthalpy changes are completely compensated by entropy changes. Beneath this line ΔG° < 0, and above it ΔG° > 0. At the point where the experimental line (solid) crosses the broken line Δ° = TΔS° and TΔG° = 0.
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49
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4243191918
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note
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N scale ranges from 0 for TMS, the least polar solvent, to 1 for water, the most polar solvent.
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-
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50
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4243119027
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Possibly the hydrophobic surface of the assembly is better solvated by the methyl groups of methanol and therefore results in less competition in hydrogen bonding.
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