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17344363474
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In general, the molecule is considered as a rigid body isotropically tumbling
-
In general, the molecule is considered as a rigid body isotropically tumbling.
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21
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0024490495
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note
-
In the case of overlapping resonances, an average value was used for the normalization constant (see Experimental Section).
-
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23
-
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17344365389
-
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note
-
Equation 15 strictly applies for neutral spheres under the assumption of stick boundary conditions. Due to the low cyclodextrin concentration (2 mM) and the presence of a large concentration of supporting salt (50 mM KCl), this equation is still a good approximation. Indeed under the present conditions, one can neglect both the hydrodynamic coupling between the identically charged cyclodextrins and the Wien effect.
-
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-
25
-
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17344372833
-
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note
-
1H NMR spectra of the CD7(Ac), CD7(Am), and CD7(Ac):CD7(Am) 1:1 mixture suggests that the amount of large aggregates is marginal if any.
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-
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17344372447
-
-
note
-
Compare the average distance between adjacent 6-glucose positions (about 1 nm) with the inverse Debye length at 50 mM KCl (about 1.5 nm).
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36
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0026619551
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