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Power conversion efficiencies of around 1% were recently reported by Roncali et al. for bulk heterojunction devices prepared from PCBM and different triphenylamine derivatives: (a) Roquet, S.; Cravino, A.; Leriche, P.; Alévêque, O.; Frère, P.; Roncali, J. J. Am. Chem. Soc. 2006, 128, 3459-3466.
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Power conversion efficiencies of around 1% were recently reported by Roncali et al. for bulk heterojunction devices prepared from PCBM and different triphenylamine derivatives: (a) Roquet, S.; Cravino, A.; Leriche, P.; Alévêque, O.; Frère, P.; Roncali, J. J. Am. Chem. Soc. 2006, 128, 3459-3466.
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The substitution pattern, conjugation, and electronic structure of functionalized phenylacetylene and phenylvinylene structures are known to exhibit remarkable optical and electronic properties because of their multiple conjugated pathways. For recent examples, see: a
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The substitution pattern, conjugation, and electronic structure of functionalized phenylacetylene and phenylvinylene structures are known to exhibit remarkable optical and electronic properties because of their multiple conjugated pathways. For recent examples, see: (a) Marsden, J. A.; Miller, J. J.; Shirtcliff, L. D.; Haley, M. M. J Am. Chem. Soc. 2005, 128, 2464-2476.
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Unambiguous assignment of these weak waves to oxidative processes corresponding to the central π-conjugated oligomer was achieved using DPV measurements.
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We note that, especially for 5b, the lifetime of the singlet excited state inferred from transient absorption and fluorescence spectroscopy is different. Since the fluorescence can be measured very sensitively over several orders of magnitude and over a longer time period, these values are likely more accurate
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