Broad bandwidth near-IR two-photon absorption in conjugated porphyrin-core dendrimers

Proceedings of SPIE - The International Society for Optical Engineering

Volumn 6653, Issue , 2007, Pages

  Rebane, Aleks ^a   Makarov, Nikolay ^a   Drobizhev, Mikhail ^a   Spangler, Charles W ^a,b   Gong, Aijun ^b   Meng, Fanqing ^b  

^a MONTANA STATE UNIVERSITY   (United States)

^b Rasiris Inc   (United States)

Author keywords

Cooperative enhancement; Dendrimers; Porphyrins; Two photon absorption

Indexed keywords

BANDWIDTH; ELECTRON ABSORPTION; FLUORESCENCE; PHOTOEXCITATION; PORPHYRINS;

COOPERATIVE ENHANCEMENT; EXCITATION SPECTRA; PHTHALOCYANINE; TWO-PHOTON ABSORPTION;

DENDRIMERS;

EID: 42149152296     PISSN: 0277786X     EISSN: None     Source Type: Conference Proceeding    
DOI: 10.1117/12.734475     Document Type: Conference Paper

References (22)

1. R.L. Sutherland, M.C. Brant, J. Heinrichs, J.E. Rogers, J.E. Slagle, D.G. McLean, P.A. Fleitz, "Excited-state characterization and effective three-photon absorption model of two-photon-induced excited-state absorption in organic push-pull charge-transfer chromophores," J. Opt. Soc. Am. B 22 (9), pp. 1939-1948 (2005).
2. A. Baev, O. Rubio-Pons, F. Gelmukhanov, H. Agren, "Optical limiting properties of Zinc- and Platinum-based organo-metallic compounds," J. Phys. Chem. A 108, pp. 7406-7416 (2004).
3. N. S. Makarov, A. Rebane, M. Drobizhev, H. Wolleb, and H. Spahni, "Optimizing two-photon absorption for volumetric optical data storage," J. Opt. Soc. Am. B 24, pp. 1874-1885 (2007).
4. A. Karotki, M. Kruk, M. Drobizhev, A. Rebane, E. Nickel, C.W. Spangler, "Efficient singlet oxygen generation upon two-photon excitation of new porphyrin with enhanced nonlinear absorption", IEEE J. Select. Topics Quant. Electron., 7, pp. 971-975, (2001).
5. C. W. Spangler, J. R. Starkey, A. Rebane, F. Meng, A. Gong, M. Drobizhev, "Synthesis, characterization, and preclinical studies of two-photon-activated targeted PDT therapeutic triads," Proc. SPIE Vol. 6139, 61390 in: Optical Methods for Tumor Treatment and Detection: Mechanisms and Techniques in Photodynamic Therapy XV; David Kessel, Ed. (2006).
6. J.R. Starkey, A. Rebane, M. Drobizhev, F. Meng, A. Gong, A. Elliott, K. McInnery, C.W. Spangler, "New photodynamic therapy sensitizers induce xenograft tumor regressions after NIR laser treatment through the body of the host mouse," (in preparation).
7. M. Drobizhev, A. Karotki, A. Rebane, and C.W. Spangler, "New dendrimer molecules with record large two-photon absorption cross-section," Opt. Lett. 26, pp. 1081-1083 (2001).
8. A. Karotki, M. Drobizhev, M. Kruk, Ch. Spangler, E. Nickel, N. Mamardashvili and A. Rebane, "Enhancement of two-photon absorption in tetrapyrrolic compounds," J. Opt. Soc. Am. B 20, pp.321- 332 (2003).
9. A. Karotki, M. Drobizhev, Y. Dzenis, P. N. Taylor, H. L. Anderson, and A. Rebane, "Dramatic enhancement of intrinsic two-photon absorption in a conjugated porphyrin dimer," Phys. Chem. Chem. Phys, 6 (1), pp. 7-10 (2004).
10. M. Drobizhev, Y. Stepanenko, Y. Dzenis, A. Karotki, A. Rebane, P. N. Taylor, and H.. Anderson, "Understanding strong two-photon absorption in π-conjugated porphyrin dimers via double-resonance enhancement in a three-level model," J. Am. Chem. Soc., 126 (47), pp. 15352-15353 (2004).
11. M. Drobizhev, Y. Stepanenko, Y. Dzenis, A. Karotki, A. Rebane, P. N. Taylor, and H. L. Anderson, "Extremely strong near-IR two-photon absorption in conjugated porphyrin dimers: Quantitative description with three essential states model," J. Phys. Chem. B, 109 (15) pp. 7223-7236 (2005).
12. M. Drobizhev,. Y. Stepanenko, A. Rebane, C.J. Wilson, T. E.O. Screen, H.L. Anderson, "Strong cooperative enhancement of two-photon absorption in double-strand conjugated porphyrin ladder arrays," J. Am. Chem. Soc., 128 (38), pp. 12432-12433 (2006).
13. E. Nickel, C. W. Spangler, A. Rebane, "Porphyrins with enhanced multi-photon absorption cross-sections for photodynamic therapy," US Patent 6953570 (2006).
14. M. Drobizhev, A. Karotki, M, Kruk, Y. Dzenis, A. Rebane, F. Meng, E. Nickel, C.W. Spangler, "Strong two-photon absorption in new porphyrins with asymmetrical meso-substitution," SPIE Proc v. 5211, pp. 63-74 (2003).
15. M. Drobizhev, F. Meng, A. Rebane, Y. Stepanenko, E. Nickel, and C. W. Spangler, "Strong two-photon absorption in new asymmetrically-substituted porphyrins: interference between charge-transfer and intermediate-resonance pathways." J. Phys. Chem. B 110 (20), pp. 9802-9814 (2006).
16. B. Wang, X., Wang, W. Jiang, Z. Wang, P. Yang, D. Hu, Y. Yan, S. Qian, "Synthesis of multibranched porphyrins with two-photon absorption and intramolecular energy transfer," Acta Chimica Sinica, 65 (10), pp. 887-893 (2007) (in Chinese).
17. T. Morotti, M. Pizzotti, R. Ugo, S. Quici, M. Bruschi, P. Mussini, S. Righetto, "Electronic characterisation and significant second-order NLO response of 10,20-diphenylporphyrins and their Zn(II) complexes substituted in the meso position with πt-delocalised linkers carrying push or pull groups." Eur. J. Inorg. Chem. (9), pp. 1743-1757 (2006).
18. P.N. Day, K. A. Nguyen, R. Pachter, "Calculation of two-photon absorption spectra of donor-pi-acceptor compounds in solution using quadratic response time-dependent density functional theory," J. Chem. Phys. 125 (9), Art. No. 094103 (2006).
19. M. Drobizhev, A. Karotki, M. Kruk, A. Krivokapic, H.L. Anderson, and A. Rebane, "Photon energy upconversion in porphyrins: One-photon hot-band versus two-photon absorption", Chem. Phys. Lett., 370, pp. 690-699 (2003).
20. O.S. Finikova, T. Troxler, A. Senes, W. F. DeGrado, R. M. Hochstrasser, S.A. Vinogradov, "Energy and electron transfer in enhanced two-photon absorbing systems with triplet cores," J. Phys. Chem A111 (30), pp. 6977-6990 (2007).
21. M. A. Oar, W. R. Dichtel, J. M. Serin, J. M. J. Fréchet, J. E. Rogers, J. E. Slagle, P. A. Fleitz, Loon-Seng Tan, T. Y. Ohulchanskyy, P. N. Prasad, "Light-harvesting chromophores with metalated porphyrin cores for tuned photosensitization of singlet oxygen via two-photon excited FRET," Chem. Mater. 18 (16), pp 3682 - 3692 (2006).
22. W. R. Dichtel, J. M. Serin, C. Edder, J. M. J. Fréchet, M. Matuszewski, Loon-Seng Tan, T. Y. Ohulchanskyy, P. N. Prasad, "Singlet oxygen generation via two-photon excited FRET," J. Am. Chem. Soc 126(17), pp 5380 - 5381 (2004).