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84917807032
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For the synthesis of strongly related palladacycles, see for example: a
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42149164673
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It finally turned out that this reaction mixture contained bis(benzyldiisopropylphosphine)palladium, benzyldiisopropylphosphine)(o- benzyldiisopropylphosphine)chloropalladium, bis(benzyldiisopropylphosphine) chlorohydridopalladium, bis(benzyldiisopropylphosphine)dichloropalladium, and both isomeric forms of bis(o-benzyldiisopropylphosphine)palladium
-
It finally turned out that this reaction mixture contained bis(benzyldiisopropylphosphine)palladium, (benzyldiisopropylphosphine)(o- benzyldiisopropylphosphine)chloropalladium, bis(benzyldiisopropylphosphine) chlorohydridopalladium, bis(benzyldiisopropylphosphine)dichloropalladium, and both isomeric forms of bis(o-benzyldiisopropylphosphine)palladium.
-
-
-
-
21
-
-
42149167124
-
-
See the Experimental Section
-
See the Experimental Section.
-
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-
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22
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0001137374
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For examples of bis-cyclopalladated complexes containing phosphine ligands see: Longoni, G, Fantucci, P, Chini, P, Canziani, F. J. Organomet. Chem. 1972, 39, 413
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(a) For examples of bis-cyclopalladated complexes containing phosphine ligands see: Longoni, G.; Fantucci, P.; Chini, P.; Canziani, F. J. Organomet. Chem. 1972, 39, 413.
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23
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42149131879
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For examples of bis-cyclopalladated complexes containing amine ligands, see: (a) Kasahara, A, Izumi, T. Bull. Chem. Soc. Jpn. 1969, 42, 1765
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For examples of bis-cyclopalladated complexes containing amine ligands, see: (a) Kasahara, A.; Izumi, T. Bull. Chem. Soc. Jpn. 1969, 42, 1765.
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0346991648
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41
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42149148484
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Mixtures of 6a and 6b were synthesized in analogy to related derivatives see ref 9c
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Mixtures of 6a and 6b were synthesized in analogy to related derivatives (see ref 9c).
-
-
-
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42
-
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85025757061
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2] (R == bulky tertiary phosphine) by direct reduction of the corresponding dichlorides with Na/ Hg were not successful, palladium metal being formed: Otsuka, S. J. Organomet. Chem. 1980, 200, 191.
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2] (R == bulky tertiary phosphine) by direct reduction of the corresponding dichlorides with Na/ Hg were not successful, palladium metal being formed: Otsuka, S. J. Organomet. Chem. 1980, 200, 191.
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44
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31544457395
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(I) Paul, F.; Patt, J.; Hartwig, J. F. Organometallics 1995, 14, 3030.
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For examples of Pd1 dimer formation upon reduction of Pd 11, see: (a) Portnoy, M, Milstein, D. Organometallics 1994, 13, 600
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11, see: (a) Portnoy, M.; Milstein, D. Organometallics 1994, 13, 600.
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54
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4043092711
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(b) Weissman, H.; Shimon, L. J. W.; Milstein, D. Organometallics 2004, 23, 3931.
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Weissman, H.1
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55
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36348973933
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3], see for example: Han, X.; Weng, Z.; Hor, T. S. A. J. Organomet. Chem. 2007, 692, 5690.
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3], see for example: Han, X.; Weng, Z.; Hor, T. S. A. J. Organomet. Chem. 2007, 692, 5690.
-
-
-
-
56
-
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42149087479
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A theoretical study showing that C-H activation by Pd(0) is possible: Diefenbach, A.; Bickelhaupt, F. M. J. Phys. Chem. 2004, 105, 8460.
-
A theoretical study showing that C-H activation by Pd(0) is possible: Diefenbach, A.; Bickelhaupt, F. M. J. Phys. Chem. 2004, 105, 8460.
-
-
-
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57
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42149146515
-
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2D NMR spectroscopy.
-
2D NMR spectroscopy.
-
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