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Volumn 27, Issue 5, 2008, Pages 894-899

Processes involved in the reduction of a cyclometalated palladium(II) complex

Author keywords

[No Author keywords available]

Indexed keywords

CYCLIC VOLTAMMETRY; HYDROCHLORIC ACID; MOLAR MASS; PALLADIUM COMPOUNDS; REACTION KINETICS;

EID: 42149142955     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om7008815     Document Type: Article
Times cited : (11)

References (57)
  • 1
    • 0042905927 scopus 로고    scopus 로고
    • See, for example: a
    • See, for example: (a) Bedford, R. B. Chem. Commun. 2003, 1787.
    • (2003) Chem. Commun , pp. 1787
    • Bedford, R.B.1
  • 14
    • 84917807032 scopus 로고
    • For the synthesis of strongly related palladacycles, see for example: a
    • For the synthesis of strongly related palladacycles, see for example: (a) Abicht, H. P.; Issleib, K. Z. Antimicrob. Antineoplast. Chemother. 1983, 500, 31.
    • (1983) Antimicrob. Antineoplast. Chemother , vol.500 , pp. 31
    • Abicht, H.P.1    Issleib, K.Z.2
  • 20
    • 42149164673 scopus 로고    scopus 로고
    • It finally turned out that this reaction mixture contained bis(benzyldiisopropylphosphine)palladium, benzyldiisopropylphosphine)(o- benzyldiisopropylphosphine)chloropalladium, bis(benzyldiisopropylphosphine) chlorohydridopalladium, bis(benzyldiisopropylphosphine)dichloropalladium, and both isomeric forms of bis(o-benzyldiisopropylphosphine)palladium
    • It finally turned out that this reaction mixture contained bis(benzyldiisopropylphosphine)palladium, (benzyldiisopropylphosphine)(o- benzyldiisopropylphosphine)chloropalladium, bis(benzyldiisopropylphosphine) chlorohydridopalladium, bis(benzyldiisopropylphosphine)dichloropalladium, and both isomeric forms of bis(o-benzyldiisopropylphosphine)palladium.
  • 21
    • 42149167124 scopus 로고    scopus 로고
    • See the Experimental Section
    • See the Experimental Section.
  • 22
    • 0001137374 scopus 로고    scopus 로고
    • For examples of bis-cyclopalladated complexes containing phosphine ligands see: Longoni, G, Fantucci, P, Chini, P, Canziani, F. J. Organomet. Chem. 1972, 39, 413
    • (a) For examples of bis-cyclopalladated complexes containing phosphine ligands see: Longoni, G.; Fantucci, P.; Chini, P.; Canziani, F. J. Organomet. Chem. 1972, 39, 413.
  • 28
    • 42149131879 scopus 로고    scopus 로고
    • For examples of bis-cyclopalladated complexes containing amine ligands, see: (a) Kasahara, A, Izumi, T. Bull. Chem. Soc. Jpn. 1969, 42, 1765
    • For examples of bis-cyclopalladated complexes containing amine ligands, see: (a) Kasahara, A.; Izumi, T. Bull. Chem. Soc. Jpn. 1969, 42, 1765.
  • 41
    • 42149148484 scopus 로고    scopus 로고
    • Mixtures of 6a and 6b were synthesized in analogy to related derivatives see ref 9c
    • Mixtures of 6a and 6b were synthesized in analogy to related derivatives (see ref 9c).
  • 42
    • 85025757061 scopus 로고    scopus 로고
    • 2] (R == bulky tertiary phosphine) by direct reduction of the corresponding dichlorides with Na/ Hg were not successful, palladium metal being formed: Otsuka, S. J. Organomet. Chem. 1980, 200, 191.
    • 2] (R == bulky tertiary phosphine) by direct reduction of the corresponding dichlorides with Na/ Hg were not successful, palladium metal being formed: Otsuka, S. J. Organomet. Chem. 1980, 200, 191.
  • 53
    • 0000916635 scopus 로고    scopus 로고
    • For examples of Pd1 dimer formation upon reduction of Pd 11, see: (a) Portnoy, M, Milstein, D. Organometallics 1994, 13, 600
    • 11, see: (a) Portnoy, M.; Milstein, D. Organometallics 1994, 13, 600.
  • 55
    • 36348973933 scopus 로고    scopus 로고
    • 3], see for example: Han, X.; Weng, Z.; Hor, T. S. A. J. Organomet. Chem. 2007, 692, 5690.
    • 3], see for example: Han, X.; Weng, Z.; Hor, T. S. A. J. Organomet. Chem. 2007, 692, 5690.
  • 56
    • 42149087479 scopus 로고    scopus 로고
    • A theoretical study showing that C-H activation by Pd(0) is possible: Diefenbach, A.; Bickelhaupt, F. M. J. Phys. Chem. 2004, 105, 8460.
    • A theoretical study showing that C-H activation by Pd(0) is possible: Diefenbach, A.; Bickelhaupt, F. M. J. Phys. Chem. 2004, 105, 8460.
  • 57
    • 42149146515 scopus 로고    scopus 로고
    • 2D NMR spectroscopy.
    • 2D NMR spectroscopy.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.