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Since all ratios were kept constant (4 wt, dextran vs. VAc and [Dextran, V50, 1, see Table 2, expts 7 and 8, an increase of monomer content implied an increase of both initial V50 and dextran concentrations leading to a decrease of the nucleation time, simultaneously with an increase of the polymerization rate (Fig. 4, In emulsion polymerization, the polymerization rate [Rp) mainly depends on the number of particles (Np) as displayed in eq 2 (nbar is the average number of radicals per particles).30 The increase in polymerization rate displayed in Figure 4, dx/dt) expt 8/(dx/dt)expt 7, 1-6] was in good agreement with the increase in Np N p, expt 8/Np, expt 7, 1.7, see Table 2, Rp, M]0 dx/dt, kp[M] p[P*, kp[M
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bar (2)
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