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Volumn 27, Issue 6, 2008, Pages 1267-1274

Octa- and nonamethylfluorenyl complexes of Zr(II), Zr(IV), and Hf(IV). Investigation of steric and electronic effects

Author keywords

[No Author keywords available]

Indexed keywords

DIMETHYL DERIVATIVES; MIXED-LIGAND-METALLOCENES;

EID: 41749093221     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om701133e     Document Type: Article
Times cited : (17)

References (47)
  • 1
    • 29144445161 scopus 로고    scopus 로고
    • For a series of reviews on Metallocene Complexes as Catalysts for Olefin Polymerization see
    • For a series of reviews on "Metallocene Complexes as Catalysts for Olefin Polymerization" see: Coord. Chem. Rev. 2006, 250, 1-272.
    • (2006) Coord. Chem. Rev , vol.250 , pp. 1-272
  • 16
    • 0012154733 scopus 로고    scopus 로고
    • 2 were reported in: O'Hare, D.; Murphy, V. J.; Diamond, G. M.; Arnold, P.; Mountford, P. Organometallics 1994, 13, 4689.
    • 2 were reported in: O'Hare, D.; Murphy, V. J.; Diamond, G. M.; Arnold, P.; Mountford, P. Organometallics 1994, 13, 4689.
  • 22
    • 0000373547 scopus 로고    scopus 로고
    • For examples of unbridged cyclopentadienyl fluorenyl zirconocene derivatives see: Schmid, M. A, Alt, H. G, Milius, W. J. Organomet. Chem. 1995, 501, 101
    • (a) For examples of unbridged cyclopentadienyl fluorenyl zirconocene derivatives see: Schmid, M. A.; Alt, H. G.; Milius, W. J. Organomet. Chem. 1995, 501, 101.
  • 28
    • 41749121591 scopus 로고    scopus 로고
    • A chemical shift of approximately 78 ppm is expected for an η3-coordinated, and 100 ppm for an η5-coordinated fluorenyl ligand; see ref 4
    • 5-coordinated fluorenyl ligand; see ref 4.
  • 30
    • 41749085172 scopus 로고    scopus 로고
    • CSD reference code GEJPEQ
    • CSD reference code GEJPEQ, Bohme, U.; Rittmeister, B., 1998.
    • (1998)
    • Bohme, U.1    Rittmeister, B.2
  • 33
    • 41749116269 scopus 로고    scopus 로고
    • For instance Cp(Flu)ZrMe2 exhibits a peak in the 13C{1H} NMR spectrum at 35.2 ppm for the Zr-Me goups; see ref 14a
    • 1H} NMR spectrum at 35.2 ppm for the Zr-Me goups; see ref 14a.
  • 41
    • 4243560394 scopus 로고    scopus 로고
    • 2 is described as a dark green crystalline compound; see: Antiñolo, A.; Lappert, M. F.; Winterborn, D. J. W. J. Organomet. Chem. 1984, 272, C37.
    • 2 is described as a dark green crystalline compound; see: Antiñolo, A.; Lappert, M. F.; Winterborn, D. J. W. J. Organomet. Chem. 1984, 272, C37.
  • 42
    • 0000751357 scopus 로고    scopus 로고
    • 2: Atwood, J. L.; Rogers, R. D.; Hunter, W. E.; Floriani, C.; Fachinetti, G.; Chiesi-Villa, A. Inorg. Chem. 1980, 19, 3812.
    • 2: Atwood, J. L.; Rogers, R. D.; Hunter, W. E.; Floriani, C.; Fachinetti, G.; Chiesi-Villa, A. Inorg. Chem. 1980, 19, 3812.
  • 44
    • 0037467042 scopus 로고    scopus 로고
    • 2 has appeared in the literature; however no experimental details were given, see: Pool, J. A.; Lobkovsky, E.; Chirik, P. J. J. Am. Chem. Soc. 2003, 125, 2241.
    • 2 has appeared in the literature; however no experimental details were given, see: Pool, J. A.; Lobkovsky, E.; Chirik, P. J. J. Am. Chem. Soc. 2003, 125, 2241.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.