Kinetic modeling of hydrolysis of canola oil in supercritical media

Journal of Supercritical Fluids

Volumn 45, Issue 1, 2008, Pages 94-101

  Moquin, Paul H L ^a   Temelli, Feral ^a  

^a UNIVERSITY OF ALBERTA   (Canada)

Author keywords

Canola oil; Fat splitting; Hydrolysis; Kinetics; Supercritical carbon dioxide

Indexed keywords

CARBON DIOXIDE; HYDROLYSIS; OPTIMIZATION; REACTION KINETICS; SUPERCRITICAL FLUIDS;

CANOLA OIL; FAT SPLITTING; SUPERCRITICAL CARBON DIOXIDE;

FATTY ACIDS;

EID: 40949090054     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.supflu.2007.11.018     Document Type: Article

References (21)

1. Patil T.A., Butala D.N., Raghunathan T.S., and Shankar H.S. Thermal hydrolysis of vegetable oils and fats. 1. Reaction kinetics. Ind. Eng. Chem. Res. 27 (1988) 727-735
2. King J.W., Holliday R.L., and List G.R. Hydrolysis of soybean oil in a subcritical water flow reactor. Green Chem. 1 (1999) 261-264
3. Mills V., and McClain H.K. Fat hydrolysis. Ind. Eng. Chem. 41 (1949) 1982-1985
4. Sturzenegger A., and Sturm H. Hydrolysis of fats at high temperatures. Ind. Eng. Chem. 43 (1951) 510-515
5. Lawrence E.A. Hydrolysis methods. J. Am. Oil Chem. Soc. 31 (1954) 542-544
6. Hartman L. Kinetics of the Twitchell hydrolysis. Nature 167 (1951) 199-1199
7. Lascaray L. Industrial fat splitting. J. Am. Oil Chem. Soc. 29 (1952) 362-366
8. Minami E., and Saka S. Kinetics of hydrolysis and methyl esterification for biodiesel production in two-step supercritical methanol process. Fuel 85 (2006) 2479-2483
9. Ackelsberg O.J. Fat splitting. J. Am. Oil Chem. Soc. 35 (1958) 635-640
10. Lascaray L. Mechanism of fat splitting. Ind. Eng. Chem. 41 (1949) 786-790
11. Holliday R.L., King J.W., and List G.R. Hydrolysis of vegetable oils in sub- and supercritical water. Ind. Eng. Chem. Res. 36 (1997) 932-935
12. Pinto J.S.S., and Lanças F.M. Hydrolysis of corn oil using subcritical water. J. Braz. Chem. Soc. 17 (2006) 85-89
13. 2 supercritical conditions. Nippon Kagaku Kaishi 1 (1995) 79-82
14. Moquin P.H.L., Temelli F., Sovavá H., and Saldaña M.D.A. Kinetic modeling of glycerolysis-hydrolysis of canola oil in supercritical carbon dioxide media using equilibrium data. J. Supercrit. Fluids 37 (2006) 417-424
15. Siemens B.J., and Daun J.K. Determination of the fatty acid composition of canola, flax, and solin by near-infrared spectroscopy. J. Am. Oil Chem. Soc. 82 (2005) 153-157
16. Wright A.J., McGauley S.E., Narine S.S., Willis W.M., Lencki R.W., and Marangoni A.G. Solvent effects on the crystallization behavior of milk fat fractions. J. Agric. Food Chem. 48 (2000) 1033-1040
17. SAS Institute Inc., Version 9.1, Cary, NC, 2003.
18. Noureddini H., Harkey D.W., and Gutsman M.R.A. Continuous process for the glycerolysis of soybean oil. J. Am. Oil Chem. Soc. 81 (2004) 203-207
19. Hyams D.G. CurveExpert Version 1. 37 (2001), Chadwick Court, Hixson, TN
20. Lasdon L., and Allan W. Microsoft Excel Solver (GRG2) (2002), Frontline Systems, Inc., Incline Village, NV
21. Moquin P.H.L., and Temelli F. Production of monoolein from oleic acid and glycerol in supercritical carbon dioxide: a kinetic approach. J. Supercrit. Fluids 44 (2008) 40-47