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Volumn 74, Issue C, 2007, Pages 673-682

An efficient synthesis of nitrogen heterocycles by Cp*Ir-catalyzed N-cycloalkylation of primary amines with diols

Author keywords

[No Author keywords available]

Indexed keywords


EID: 40749084858     PISSN: 03855414     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article
Times cited : (22)

References (54)
  • 4
    • 6444225910 scopus 로고
    • Elderfield R.C. (Ed), John Wiley & Sons, Inc., New York
    • Corwin A.H. In: Elderfield R.C. (Ed). Heterocyclic Compounds Vol. 1 (1950), John Wiley & Sons, Inc., New York 277-342
    • (1950) Heterocyclic Compounds , vol.1 , pp. 277-342
    • Corwin, A.H.1
  • 5
    • 6444225909 scopus 로고
    • Elderfield R.C. (Ed), John Wiley & Sons, Inc., New York
    • Mosher H.S. In: Elderfield R.C. (Ed). Heterocyclic Compounds Vol. 1 (1950), John Wiley & Sons, Inc., New York 617-676
    • (1950) Heterocyclic Compounds , vol.1 , pp. 617-676
    • Mosher, H.S.1
  • 9
    • 2942557280 scopus 로고    scopus 로고
    • and references therein
    • Nakamura I., and Yamamoto Y. Chem. Rev. 104 (2004) 2127 and references therein
    • (2004) Chem. Rev. , vol.104 , pp. 2127
    • Nakamura, I.1    Yamamoto, Y.2
  • 14
    • 0010464742 scopus 로고
    • Liebeskind L.S. (Ed), JAI Press, Greenwich and references therein
    • Murahashi S.-I., and Naota T. In: Liebeskind L.S. (Ed). Advances in Metal-Organic Chemistry Vol. 3 (1994), JAI Press, Greenwich 225-254 and references therein
    • (1994) Advances in Metal-Organic Chemistry , vol.3 , pp. 225-254
    • Murahashi, S.-I.1    Naota, T.2
  • 22
    • 40749115138 scopus 로고    scopus 로고
    • A part of this paper has been reported in a preliminary form.
    • A part of this paper has been reported in a preliminary form.
  • 24
    • 40749141102 scopus 로고    scopus 로고
    • Detailed procedures for the large scale synthesis of N-benzylpiperidine have been published separately.
    • Detailed procedures for the large scale synthesis of N-benzylpiperidine have been published separately.
  • 33
    • 40749101470 scopus 로고    scopus 로고
    • Asymmetric hydrogenation of cyclic imines catalyzed by transition metal complex with chiral ligand is another method for the synthesis of optically active cyclic amines.
    • Asymmetric hydrogenation of cyclic imines catalyzed by transition metal complex with chiral ligand is another method for the synthesis of optically active cyclic amines.
  • 35
    • 40749120435 scopus 로고    scopus 로고
    • note
    • 3 as base (Y = 70% with 87% de). However, a slightly better result was obtained with use of KOAc as base.
  • 36
    • 40749137737 scopus 로고    scopus 로고
    • note
    • A small extent of racemization of the auxiliary 1-phenylethyl group can account for the reduced enantiomeric excess of the products. This racemization would be probably due to isomerization of imine and/or iminium intermediate as is shown below.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.