Synthesis and properties of carboxy-substituted half-sandwich ruthenium complexes with chelating bisphosphine ligands (η5-C5H4CO2H)Ru(η2-L)X (X = I, H)

Journal of Organometallic Chemistry

Volumn 693, Issue 7, 2008, Pages 1382-1388

  Shaw, Anthony P ^a   Guan, Hairong ^a   Norton, Jack R ^a  

^a Och Spine at New York Presbyterian Hospitals   (United States)

Author keywords

Carboxy complexes; Ester hydrolysis; Ruthenium hydrides

Indexed keywords

CYCLIC VOLTAMMETRY; HYDROLYSIS; LIGANDS; PROTONATION; RUTHENIUM;

CARBOXY COMPLEXES; CHELATING BISPHOSPHINE; ESTER HYDROLYSIS; RUTHENIUM HYDRIDES;

METAL COMPLEXES;

EID: 40649089589     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2008.01.030     Document Type: Short Survey

References (41)

1. Butenschön H. Chem. Rev. 100 (2000) 1527
2. Siemeling U. Chem. Rev. 100 (2000) 1495
3. Halterman R.L. Chem. Rev. 92 (1992) 965
4. Macomber D.W., Hart W.P., and Rausch M.D. Adv. Organomet. Chem. 21 (1982) 1
5. Paley R.S. Chem. Rev. 102 (2002) 1493
6. Salmain M., and Jaouen G. C.R. Chim. 6 (2003) 249
7. van Staveren D.R., and Metzler-Nolte N. Chem. Rev. 104 (2004) 5931
8. van Staveren D.R., Weyhermüller T., and Metzler-Nolte N. Organometallics 19 (2000) 3730
9. Shafiq F., Szalda D.J., Creutz C., and Bullock R.M. Organometallics 19 (2000) 824
10. Gorfti A., Salmain M., and Jaouen G. J. Chem. Soc., Chem. Commun. (1994) 433
11. Spradau T.W., and Katzenellenbogen J.A. Bioconjugate Chem. 9 (1998) 765
12. Top S., Lehn J.-S., Morel P., and Jaouen G. J. Organomet. Chem. 583 (1999) 63
13. 2:. Thiele J. Ber. Dtsch. Chem. Ges. 34 (1901) 68
14. The hydrolysis of organic esters with trimethylsilyl iodide:. Jung M.E., and Lyster M.A. J. Am. Chem. Soc. 99 (1977) 968
15. Crocco G.L., and Gladysz J.A. J. Am. Chem. Soc. 110 (1988) 6110
16. Kristjánsdóttir S.S., and Norton J.R. In: Dedieu A. (Ed). Transition Metal Hydrides: Recent Advances in Theory and Experiment (1992), VCH, New York 309
17. 2Me)Ru(dppe)X (X = Cl, H) in a manner analogous to that in Scheme 1:. Peters D. J. Chem. Soc. (1959) 1757
18. These reactions with cyclopentadiene are well known:. White C., and Cesarotti E. J. Organomet. Chem. 287 (1985) 123
19. Bruce M.I., and Windsor N.J. Aust. J. Chem. 30 (1977) 1601
20. Nantz M.H., Radisson X., and Fuchs P.L. Synth. Commun. 17 (1987) 55
21. Treichel P.M., and Vincenti P.J. Inorg. Chem. 24 (1985) 228
22. The solvolyses of related complexes in DMSO are quite slow, suggesting that the high solubilities of the halide complexes in DMSO do not result from reaction with the solvent:. Treichel P.M., Komar D.A., and Vincenti P.J. Inorg. Chim. Acta 88 (1984) 151
23. Izutsu K. Acid-Base Dissociation Constants in Dipolar Aprotic Solvents. Chemical Data Series No. 35 (1990), Blackwell Scientific Publications, Oxford
24. 1H NMR, isobutylene appears at δ 1.7 and 4.7:. Griesbaum K., and Volpp W. Chem. Ber. 121 (1988) 1795
25. Hamilton D.G., and Crabtree R.H. J. Am. Chem. Soc. 110 (1988) 4126
26. Luo X., and Crabtree R.H. Inorg. Chem. 29 (1990) 2788
27. 1H subspectrum of the expected AA′BB′ spin system to the observed triplet, but it would not reduce the cyclopentadienyl protons of the dppf ligand to only two different chemical shifts.
28. Hembre R.T., and McQueen J.S. Angew. Chem., Int. Ed. Engl. 36 (1997) 65
29. Little W.F., Reilley C.N., Johnson J.D., and Sanders A.P. J. Am. Chem. Soc. 86 (1964) 1382
30. Britton W.E., Kashyap R., El-Hashash M., El-Kady M., and Herberhold M. Organometallics 5 (1986) 1029
31. *Ru(dppf)Cl and CpRu(dppf)Cl in THF to Ru(II)/Ru(III) and Fe(II)/Fe(III), respectively:. Hembre R.T., McQueen J.S., and Day V.W. J. Am. Chem. Soc. 118 (1996) 798
32. *Fe(dppe)X has been documented, whereby the donor strength of the halogens is F > Cl > Br>I:. Tilset M., Fjeldahl I., Hamon J.-R., Hamon P., Toupet L., Saillard J.-Y., Costuas K., and Haynes A. J. Am. Chem. Soc. 123 (2001) 9984
33. Bruce M.I., Butler I.R., Cullen W.R., Koutsantonis G.A., Snow M.R., and Tiekink E.R.T. Aust. J. Chem. 41 (1988) 963
34. Leonard N.J., and Paukstelis J.V. J. Org. Chem. 28 (1963) 3021
35. Lee N.E., and Buchwald S.L. J. Am. Chem. Soc. 116 (1994) 5985
36. Hallman P.S., Stephenson T.A., and Wilkinson G. Inorg. Synth. 12 (1970) 237
37. Ortiz-Frade L.A., Ruiz-Ramírez L., González I., Marín-Becerra A., Alcarazo M., Alvarado-Rodriguez J.G., and Moreno-Esparza R. Inorg. Chem. 42 (2003) 1825
38. Shaw A.P., Ryland B.L., Norton J.R., Buccella D., and Moscatelli A. Inorg. Chem. 46 (2007) 5805
39. Hoffman R.A., Forsén S., and Gestblom B. In: Diehl P., Fluck E., and Kosfeld R. (Eds). NMR: Basic Principles and Progress vol. 2 (1971), Springer-Verlag, Berlin 61 Chapter 4
40. Newmark R.A., Boardman L.D., and Siedle A.R. Inorg. Chem. 30 (1991) 853
41. Van Geet A.L. Anal. Chem. 42 (1970) 679