Electron exchange involving a sulfur-stabilized ruthenium radical cation

Inorganic Chemistry

Volumn 46, Issue 14, 2007, Pages 5805-5812

  Shaw, Anthony P ^a   Ryland, Bradford L ^a   Norton, Jack R ^a   Buccella, Daniela ^a   Moscatelli, Alberto ^a  

^a Och Spine at New York Presbyterian Hospitals   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 34547213848     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic700580u     Document Type: Article

References (48)

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43. 31P NMR spectrum was confirmed by obtaining low-temperature spectra of a genuine sample.
44. 31P NMR spectra. We conclude that 4 (eq 11) must not disproportionate rapidly when it is present in such low concentrations.
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46. This could be due to the electron transfer equilibrium in eq 11 (most likely), slow electron exchange between 1 and 4, or proton exchange between 1 and 3.
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