Stabilization of discrete (H2O)14 water clusters in the supramolecular crystal host of [Ni(phen)3](HB)2 · 7H2O (HB-=benzilate)

Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

Volumn 38, Issue 1, 2008, Pages 49-54

  Covelo, Berta ^a   Carballo, Rosa ^a   Vázquez López, Ezequiel M ^a   Lago, Ana Belén ^a  

^a UNIVERSITY OF VIGO   (Spain)

Author keywords

Crystal structure; Metalo supramolecular chemistry; Nickel; Water clusters

Indexed keywords

EID: 40449122271     PISSN: 15533174     EISSN: 15533182     Source Type: Journal    
DOI: 10.1080/15533170701853942     Document Type: Article

References (28)

1. J.M. Ugalde, I. Alkorta, and J. Elguero, Water Clusters: Towards an Understanding Based on First Principles of their Static and Dynamic Properties, Angew. Chem. Int. Ed., 2000, 39, 717-721.
2. S.S. Xantheas, Cooperativity and Hydrogen Bonding Network in Water Clusters, Chem. Phys., 2000, 258, 225-231.
3. R. Ludwig, Water: from Clusters to the Bulk, Angew. Chem. Int. Ed., 2001, 40, 1808-1827.
4. F.N. Keutsch and R.J. Saykally, Water Clusters: Untangling the Mysteries of the Liquid, One Molecule at a Time, Proc Natl. Acad. Sci. USA, 2001, 98, 10533-10540.
5. S. Supriya and S.K. Das, Small Water Clusters in Crystalline Hydrates, J. Clust. Sci., 2003, 14, 337-366.
6. T. Miyake and M. Aida, Hydrogen Bonding Patterns in Water Clusters: Trimer, Tetramer and Pentamer. Internet Electron, J. Mol. Des., 2003, 2, 24-32.
7. 4 Cluster Characterized in the Solid State Disappears on Heating and Regenerates from Water Vapour: A Supramolecular Reversible Gas-solid Reaction, New J. Chem., 2003, 27, 1568-1574.
8. S.K. Ghosh, J. Ribas, and P.K. Bharadwaj, Metal-organic Framework Structures of Cu(II) with Pyridine-2,6-dicarboxylate and Different Spacers: Identification of a Metal Bound Acyclic Water Tetramer, Cryst. Eng. Comm., 2004, 6, 250-256.
9. 2O, Inorg. Chem., 2004, 43, 3798-3800.
10. 2O, J. Am. Chem. Soc., 2006, 128, 424-425.
11. B.-H. Ye, B.-B. Ding, Y.-Q. Weng, and X.-M. Chen, Formation of One-dimensional Metal-water Chain Containing Cyclic Water Hexamers, Inorg. Chem., 2004, 43, 6866-6868.
12. U. Mukhopadhyay and I. Bemal, Self-assembled Hexameric Water Clusters Stabilized by a Cyano-bridged Trimetallic Complex, Cryst. Growth Des., 2005, 5, 1687-1689.
13. 2O: Crystallographic, Thermal, and Theoretical Studies, Cryst. Growth Des., 2006, 6, 488-491.
14. S.K. Ghosh and P.K. Bharadwaj, Metal-organic Framework. H-bonded Like a Polycatenane: Coexistence of Acyclic Water Trimer and Nonamer, Inorg. Chem., 2005, 44, 5553-5555.
15. U. Mukhopadhyay and I. Bernal, A Self-assembled, Decameric Water Cluster Stabilized by a Cyano-bridged Copper(II) Complex, Cryst. Growth Des., 2006, 6, 363-365.
16. S.K. Ghosh and P.K. Bharadwaj, Coexistence of Water Dimer and Hexamer Clusters in 3D Metal-organic Framework Structures of Ce(III) and Pr(III) with Pyridine-2,6-dicarboxylic Acid, Inorg. Chem., 2003, 42, 8250-8254.
17. II Coordination Polymers: Studies of Topological Networks and Water Clusters, Eur. J. Inorg. Chem., 2006, 1208-1215.
18. 12 Clusters Present in the Cavity of Polymeric Interlinked Metallocycles of Nd(II) or Gd(III) and a Podand Ligand, Inorg. Chem., 2004, 43, 3771-3773.
19. S.K. Ghosh, J. Ribas, M. Salha El Fallah, and P.K. Bharadwaj, Mn(II) Staircase Structures Stitched by Water Clusters to a 3D Metal-organic Open Framework: X-ray Structural and Magnetic Studies, Inorg. Chem., 2005, 44, 3856-3862.
20. M.S. Deshpande, A.S. Kumbhar, V.G. Puranik, and K. Selvaraj, Supramolecular Self-assembled Ruthenium-polypyridyl Framework Encapsulating Discrete Water Cluster, Cryst. Growth Des., 2006, 6, 743-748.
21. S.K. Ghosh and P.K. Bharadwaj, Structure of a Discrete Hexadecameric Water Cluster in a Metal-organic Framework Structure, Inorg. Chem., 2004, 43, 6887-6889.
22. Siemens SAINT. Version 4, Software Reference Manual, 1996, Siemens Analytical X-ray Systems, Inc., Madison WI, USA.
23. G.M Sheldrick, SADABS, Program for Empirical Absorption Correction of Area Detector Data, 1996, University of Göttingen, Germany.
24. G.M Sheldrick, SHELXS-97, Program for the Solution of Crystal Structures from X-ray Data, 1997, University of Göttingen, Germany.
25. G.M Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structures from X-ray Data, 1997, University of Göttingen, Germany.
26. C. Giacovazzo, H.L. Monaco, G. Artioli, D. Viterbo, G. Ferraris, G. Gilli, G. Zanotti, and M. Catti, Fundamentals of Crystallography, 2002, IUCR Oxford University Press, New York.
27. I.J. Bruno, J.C. Cole, P.R. Edgington, M.K. Kessler, C.F. Macrae, P. McCabe, P. Pearson, and R. Taylor, MERCURY. New Software for Visualizing Crystal Structures, Acta Crystallogr., 2002, B58, 389-397.
28. n, n = 8-20: an ab initio Investigation, J. Phys. Chem. A, 2001, 105, 10525-10537.