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Volumn 27, Issue 11, 2003, Pages 1568-1574

A cyclic (H2O)4 cluster characterized in the solid state disappears on heating and regenerates from vater vapor: A supramolecular reversible gas-solid reaction

Author keywords

[No Author keywords available]

Indexed keywords

IRON COMPLEX; WATER;

EID: 0345602743     PISSN: 11440546     EISSN: None     Source Type: Journal    
DOI: 10.1039/b303539p     Document Type: Article
Times cited : (95)

References (70)
  • 49
    • 0000453239 scopus 로고
    • (b) B. R. Lentz and H. A. Scheraga, J. Chem. Phys., 1973, 58, 5296; B. R. Lentz and H. A. Scheraga, J. Chem. Phys., 1974, 61, 3493;
    • (1973) J. Chem. Phys. , vol.58 , pp. 5296
    • Lentz, B.R.1    Scheraga, H.A.2
  • 50
    • 85045804559 scopus 로고
    • (b) B. R. Lentz and H. A. Scheraga, J. Chem. Phys., 1973, 58, 5296; B. R. Lentz and H. A. Scheraga, J. Chem. Phys., 1974, 61, 3493;
    • (1974) J. Chem. Phys. , vol.61 , pp. 3493
    • Lentz, B.R.1    Scheraga, H.A.2
  • 66
    • 0345618877 scopus 로고    scopus 로고
    • note
    • 3-O group. For this reason, we decided to perform the reversible water loss experiment at 135-140°C, so that the iron-coordinated water is retained. In this temperature range complete loss of four lattice waters takes 5 hours because this process is kinetically slow at relatively lower temperature, as evidenced by the TGA plot of 1 taken after eight months from its preparation which shows gradual water loss even under ambient conditions.
  • 69
    • 0345186742 scopus 로고    scopus 로고
    • note
    • 2O vapor is not ruled out.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.