Evaluation of (+)-sparteine-like diamines for asymmetric synthesis

Journal of Organic Chemistry

Volumn 69, Issue 17, 2004, Pages 5789-5792

  Dearden, Michael J ^a   McGrath, Matthew J ^a   O'Brien, Peter ^a  

^a UNIVERSITY OF YORK   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CHEMICAL REACTIONS; KINETIC THEORY; METALS; PALLADIUM COMPOUNDS; SYNTHESIS (CHEMICAL);

ENANTIOSELECTIVE; KINETIC RESOLUTIONS; STERIC HINDERENCE;

ORGANIC COMPOUNDS;

1 INDANOL; COPPER; CYCLOOCTANE; CYCLOOCTENE OXIDE; CYTISINE; DIAMINE; LITHIUM; MAGNESIUM; PALLADIUM; SPARTEINE; SPARTEINE LIKE DIAMINE; UNCLASSIFIED DRUG;

ARTICLE; ASYMMETRIC SYNTHESIS; CATALYSIS; CHEMICAL REACTION; CRYSTAL STRUCTURE; ENANTIOSELECTIVITY; LITHIATION; OXIDATION; REACTION ANALYSIS; STEREOSPECIFICITY; X RAY CRYSTALLOGRAPHY;

ALKALOIDS; AZOCINES; CATALYSIS; DIAMINES; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; PALLADIUM; QUINOLIZINES; SPARTEINE; STEREOISOMERISM;

EID: 4043120293     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo049182w     Document Type: Article

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41. We have also found that diamine 1 is optimal for the asymmetric lithiation-trapping of N-Boc pyrrolidine. These results will be reported elsewhere, together with a detailed computational study.