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Volumn 42, Issue 15, 2004, Pages 3685-3696

Photocrosslinking system using multifunctional epoxy crosslinkers having thermally degradable properties

Author keywords

Curing of polymers; Decrosslinking; Degradation; Epoxides; In situ FT IR; Photoacid generators; Photocrosslinking; Photopolymerization; Thermal degradations

Indexed keywords

CARBOXYLIC ACIDS; CROSSLINKING; EPOXY RESINS; ESTERS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HEAT CONDUCTION; PYROLYSIS; THERMODYNAMIC STABILITY; ULTRAVIOLET RADIATION;

EID: 4043055831     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/pola.20232     Document Type: Article
Times cited : (25)

References (26)
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    • For recent publications on thermally or chemically degradable thermosets, see (a) Buchwalter, S. L.; Kosber, L. L. J Polym Sci Part A: Polym Chem 1996, 34, 249-260; (b) Yang, S.; Chen, J.-S.; Korner, H.; Breiner, T.; Ober, C. K. Chem Mater 1998, 10, 1475-1482; Ogino, K.; Chen, J.-S.; Ober, C. K. Chem Mater 1998, 10, 3833-3838; Wang, L.; Wong, C. P. J Polym Sci Part A: Polym Chem 1999, 37, 2991-3001; (e) Wang, D.; Lam, D. C. C. J Mater Sci Lett 2000, 19, 2109-2111; (f) Nakano, T.; Iwasa, H.; Miyagawa, N.; Takahara, S.; Yamaoka, T. J Photopolym Sci Technol 2000, 13, 715-717; (g) Wang, L.; Li, H.; Wong, C. P. J Polym Sci Part A: Polym Chem 2000, 38, 3771-3782; (h) Wang, L.; Wong, C. P. J Appl Polym Sci 2001, 81, 1868-1880; Malik, J.; Clarson, S. J. Polym Degrad Stab 2002, 76, 241-249; (j) Chen, J.-S.; Ober, C. K.; Poliks, M. D. Polymer 2002, 43, 131-139; (k) Gheneim, R.; Perez-Berumen, C.; Gandini, A. Macromolecules 2002, 35, 7246-7253; (1) Li, H. Y.; Wang, L. J.; Jacob, K.; Wong, C. P. J Polym Sci Part A: Polym Chem 2002, 40, 1796-1807; Wang, Z. G.; Xie, M. R.; Zhao, Y. F.; Yu, Y. Z.; Fang, S. B. Polymer 2003, 44, 923-929.
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    • For recent publications on thermally or chemically degradable thermosets, see (a) Buchwalter, S. L.; Kosber, L. L. J Polym Sci Part A: Polym Chem 1996, 34, 249-260; (b) Yang, S.; Chen, J.-S.; Korner, H.; Breiner, T.; Ober, C. K. Chem Mater 1998, 10, 1475-1482; Ogino, K.; Chen, J.-S.; Ober, C. K. Chem Mater 1998, 10, 3833-3838; Wang, L.; Wong, C. P. J Polym Sci Part A: Polym Chem 1999, 37, 2991-3001; (e) Wang, D.; Lam, D. C. C. J Mater Sci Lett 2000, 19, 2109-2111; (f) Nakano, T.; Iwasa, H.; Miyagawa, N.; Takahara, S.; Yamaoka, T. J Photopolym Sci Technol 2000, 13, 715-717; (g) Wang, L.; Li, H.; Wong, C. P. J Polym Sci Part A: Polym Chem 2000, 38, 3771-3782; (h) Wang, L.; Wong, C. P. J Appl Polym Sci 2001, 81, 1868-1880; Malik, J.; Clarson, S. J. Polym Degrad Stab 2002, 76, 241-249; (j) Chen, J.-S.; Ober, C. K.; Poliks, M. D. Polymer 2002, 43, 131-139; (k) Gheneim, R.; Perez-Berumen, C.; Gandini, A. Macromolecules 2002, 35, 7246-7253; (1) Li, H. Y.; Wang, L. J.; Jacob, K.; Wong, C. P. J Polym Sci Part A: Polym Chem 2002, 40, 1796-1807; Wang, Z. G.; Xie, M. R.; Zhao, Y. F.; Yu, Y. Z.; Fang, S. B. Polymer 2003, 44, 923-929.
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    • For recent publications on thermally or chemically degradable thermosets, see (a) Buchwalter, S. L.; Kosber, L. L. J Polym Sci Part A: Polym Chem 1996, 34, 249-260; (b) Yang, S.; Chen, J.-S.; Korner, H.; Breiner, T.; Ober, C. K. Chem Mater 1998, 10, 1475-1482; Ogino, K.; Chen, J.-S.; Ober, C. K. Chem Mater 1998, 10, 3833-3838; Wang, L.; Wong, C. P. J Polym Sci Part A: Polym Chem 1999, 37, 2991-3001; (e) Wang, D.; Lam, D. C. C. J Mater Sci Lett 2000, 19, 2109-2111; (f) Nakano, T.; Iwasa, H.; Miyagawa, N.; Takahara, S.; Yamaoka, T. J Photopolym Sci Technol 2000, 13, 715-717; (g) Wang, L.; Li, H.; Wong, C. P. J Polym Sci Part A: Polym Chem 2000, 38, 3771-3782; (h) Wang, L.; Wong, C. P. J Appl Polym Sci 2001, 81, 1868-1880; Malik, J.; Clarson, S. J. Polym Degrad Stab 2002, 76, 241-249; (j) Chen, J.-S.; Ober, C. K.; Poliks, M. D. Polymer 2002, 43, 131-139; (k) Gheneim, R.; Perez-Berumen, C.; Gandini, A. Macromolecules 2002, 35, 7246-7253; (1) Li, H. Y.; Wang, L. J.; Jacob, K.; Wong, C. P. J Polym Sci Part A: Polym Chem 2002, 40, 1796-1807; Wang, Z. G.; Xie, M. R.; Zhao, Y. F.; Yu, Y. Z.; Fang, S. B. Polymer 2003, 44, 923-929.
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    • For recent publications on thermally or chemically degradable thermosets, see (a) Buchwalter, S. L.; Kosber, L. L. J Polym Sci Part A: Polym Chem 1996, 34, 249-260; (b) Yang, S.; Chen, J.-S.; Korner, H.; Breiner, T.; Ober, C. K. Chem Mater 1998, 10, 1475-1482; Ogino, K.; Chen, J.-S.; Ober, C. K. Chem Mater 1998, 10, 3833-3838; Wang, L.; Wong, C. P. J Polym Sci Part A: Polym Chem 1999, 37, 2991-3001; (e) Wang, D.; Lam, D. C. C. J Mater Sci Lett 2000, 19, 2109-2111; (f) Nakano, T.; Iwasa, H.; Miyagawa, N.; Takahara, S.; Yamaoka, T. J Photopolym Sci Technol 2000, 13, 715-717; (g) Wang, L.; Li, H.; Wong, C. P. J Polym Sci Part A: Polym Chem 2000, 38, 3771-3782; (h) Wang, L.; Wong, C. P. J Appl Polym Sci 2001, 81, 1868-1880; Malik, J.; Clarson, S. J. Polym Degrad Stab 2002, 76, 241-249; (j) Chen, J.-S.; Ober, C. K.; Poliks, M. D. Polymer 2002, 43, 131-139; (k) Gheneim, R.; Perez-Berumen, C.; Gandini, A. Macromolecules 2002, 35, 7246-7253; (1) Li, H. Y.; Wang, L. J.; Jacob, K.; Wong, C. P. J Polym Sci Part A: Polym Chem 2002, 40, 1796-1807; Wang, Z. G.; Xie, M. R.; Zhao, Y. F.; Yu, Y. Z.; Fang, S. B. Polymer 2003, 44, 923-929.
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    • Wang, D.1    Lam, D.C.C.2
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    • For recent publications on thermally or chemically degradable thermosets, see (a) Buchwalter, S. L.; Kosber, L. L. J Polym Sci Part A: Polym Chem 1996, 34, 249-260; (b) Yang, S.; Chen, J.-S.; Korner, H.; Breiner, T.; Ober, C. K. Chem Mater 1998, 10, 1475-1482; Ogino, K.; Chen, J.-S.; Ober, C. K. Chem Mater 1998, 10, 3833-3838; Wang, L.; Wong, C. P. J Polym Sci Part A: Polym Chem 1999, 37, 2991-3001; (e) Wang, D.; Lam, D. C. C. J Mater Sci Lett 2000, 19, 2109-2111; (f) Nakano, T.; Iwasa, H.; Miyagawa, N.; Takahara, S.; Yamaoka, T. J Photopolym Sci Technol 2000, 13, 715-717; (g) Wang, L.; Li, H.; Wong, C. P. J Polym Sci Part A: Polym Chem 2000, 38, 3771-3782; (h) Wang, L.; Wong, C. P. J Appl Polym Sci 2001, 81, 1868-1880; Malik, J.; Clarson, S. J. Polym Degrad Stab 2002, 76, 241-249; (j) Chen, J.-S.; Ober, C. K.; Poliks, M. D. Polymer 2002, 43, 131-139; (k) Gheneim, R.; Perez-Berumen, C.; Gandini, A. Macromolecules 2002, 35, 7246-7253; (1) Li, H. Y.; Wang, L. J.; Jacob, K.; Wong, C. P. J Polym Sci Part A: Polym Chem 2002, 40, 1796-1807; Wang, Z. G.; Xie, M. R.; Zhao, Y. F.; Yu, Y. Z.; Fang, S. B. Polymer 2003, 44, 923-929.
    • (2000) J Photopolym Sci Technol , vol.13 , pp. 715-717
    • Nakano, T.1    Iwasa, H.2    Miyagawa, N.3    Takahara, S.4    Yamaoka, T.5
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    • 0034298914 scopus 로고    scopus 로고
    • For recent publications on thermally or chemically degradable thermosets, see (a) Buchwalter, S. L.; Kosber, L. L. J Polym Sci Part A: Polym Chem 1996, 34, 249-260; (b) Yang, S.; Chen, J.-S.; Korner, H.; Breiner, T.; Ober, C. K. Chem Mater 1998, 10, 1475-1482; Ogino, K.; Chen, J.-S.; Ober, C. K. Chem Mater 1998, 10, 3833-3838; Wang, L.; Wong, C. P. J Polym Sci Part A: Polym Chem 1999, 37, 2991-3001; (e) Wang, D.; Lam, D. C. C. J Mater Sci Lett 2000, 19, 2109-2111; (f) Nakano, T.; Iwasa, H.; Miyagawa, N.; Takahara, S.; Yamaoka, T. J Photopolym Sci Technol 2000, 13, 715-717; (g) Wang, L.; Li, H.; Wong, C. P. J Polym Sci Part A: Polym Chem 2000, 38, 3771-3782; (h) Wang, L.; Wong, C. P. J Appl Polym Sci 2001, 81, 1868-1880; Malik, J.; Clarson, S. J. Polym Degrad Stab 2002, 76, 241-249; (j) Chen, J.-S.; Ober, C. K.; Poliks, M. D. Polymer 2002, 43, 131-139; (k) Gheneim, R.; Perez-Berumen, C.; Gandini, A. Macromolecules 2002, 35, 7246-7253; (1) Li, H. Y.; Wang, L. J.; Jacob, K.; Wong, C. P. J Polym Sci Part A: Polym Chem 2002, 40, 1796-1807; Wang, Z. G.; Xie, M. R.; Zhao, Y. F.; Yu, Y. Z.; Fang, S. B. Polymer 2003, 44, 923-929.
    • (2000) J Polym Sci Part A: Polym Chem , vol.38 , pp. 3771-3782
    • Wang, L.1    Li, H.2    Wong, C.P.3
  • 8
    • 0035934420 scopus 로고    scopus 로고
    • For recent publications on thermally or chemically degradable thermosets, see (a) Buchwalter, S. L.; Kosber, L. L. J Polym Sci Part A: Polym Chem 1996, 34, 249-260; (b) Yang, S.; Chen, J.-S.; Korner, H.; Breiner, T.; Ober, C. K. Chem Mater 1998, 10, 1475-1482; Ogino, K.; Chen, J.-S.; Ober, C. K. Chem Mater 1998, 10, 3833-3838; Wang, L.; Wong, C. P. J Polym Sci Part A: Polym Chem 1999, 37, 2991-3001; (e) Wang, D.; Lam, D. C. C. J Mater Sci Lett 2000, 19, 2109-2111; (f) Nakano, T.; Iwasa, H.; Miyagawa, N.; Takahara, S.; Yamaoka, T. J Photopolym Sci Technol 2000, 13, 715-717; (g) Wang, L.; Li, H.; Wong, C. P. J Polym Sci Part A: Polym Chem 2000, 38, 3771-3782; (h) Wang, L.; Wong, C. P. J Appl Polym Sci 2001, 81, 1868-1880; Malik, J.; Clarson, S. J. Polym Degrad Stab 2002, 76, 241-249; (j) Chen, J.-S.; Ober, C. K.; Poliks, M. D. Polymer 2002, 43, 131-139; (k) Gheneim, R.; Perez-Berumen, C.; Gandini, A. Macromolecules 2002, 35, 7246-7253; (1) Li, H. Y.; Wang, L. J.; Jacob, K.; Wong, C. P. J Polym Sci Part A: Polym Chem 2002, 40, 1796-1807; Wang, Z. G.; Xie, M. R.; Zhao, Y. F.; Yu, Y. Z.; Fang, S. B. Polymer 2003, 44, 923-929.
    • (2001) J Appl Polym Sci , vol.81 , pp. 1868-1880
    • Wang, L.1    Wong, C.P.2
  • 9
    • 0036131144 scopus 로고    scopus 로고
    • For recent publications on thermally or chemically degradable thermosets, see (a) Buchwalter, S. L.; Kosber, L. L. J Polym Sci Part A: Polym Chem 1996, 34, 249-260; (b) Yang, S.; Chen, J.-S.; Korner, H.; Breiner, T.; Ober, C. K. Chem Mater 1998, 10, 1475-1482; Ogino, K.; Chen, J.-S.; Ober, C. K. Chem Mater 1998, 10, 3833-3838; Wang, L.; Wong, C. P. J Polym Sci Part A: Polym Chem 1999, 37, 2991-3001; (e) Wang, D.; Lam, D. C. C. J Mater Sci Lett 2000, 19, 2109-2111; (f) Nakano, T.; Iwasa, H.; Miyagawa, N.; Takahara, S.; Yamaoka, T. J Photopolym Sci Technol 2000, 13, 715-717; (g) Wang, L.; Li, H.; Wong, C. P. J Polym Sci Part A: Polym Chem 2000, 38, 3771-3782; (h) Wang, L.; Wong, C. P. J Appl Polym Sci 2001, 81, 1868-1880; Malik, J.; Clarson, S. J. Polym Degrad Stab 2002, 76, 241-249; (j) Chen, J.-S.; Ober, C. K.; Poliks, M. D. Polymer 2002, 43, 131-139; (k) Gheneim, R.; Perez-Berumen, C.; Gandini, A. Macromolecules 2002, 35, 7246-7253; (1) Li, H. Y.; Wang, L. J.; Jacob, K.; Wong, C. P. J Polym Sci Part A: Polym Chem 2002, 40, 1796-1807; Wang, Z. G.; Xie, M. R.; Zhao, Y. F.; Yu, Y. Z.; Fang, S. B. Polymer 2003, 44, 923-929.
    • (2002) Polym Degrad Stab , vol.76 , pp. 241-249
    • Malik, J.1    Clarson, S.J.2
  • 10
    • 0035850873 scopus 로고    scopus 로고
    • For recent publications on thermally or chemically degradable thermosets, see (a) Buchwalter, S. L.; Kosber, L. L. J Polym Sci Part A: Polym Chem 1996, 34, 249-260; (b) Yang, S.; Chen, J.-S.; Korner, H.; Breiner, T.; Ober, C. K. Chem Mater 1998, 10, 1475-1482; Ogino, K.; Chen, J.-S.; Ober, C. K. Chem Mater 1998, 10, 3833-3838; Wang, L.; Wong, C. P. J Polym Sci Part A: Polym Chem 1999, 37, 2991-3001; (e) Wang, D.; Lam, D. C. C. J Mater Sci Lett 2000, 19, 2109-2111; (f) Nakano, T.; Iwasa, H.; Miyagawa, N.; Takahara, S.; Yamaoka, T. J Photopolym Sci Technol 2000, 13, 715-717; (g) Wang, L.; Li, H.; Wong, C. P. J Polym Sci Part A: Polym Chem 2000, 38, 3771-3782; (h) Wang, L.; Wong, C. P. J Appl Polym Sci 2001, 81, 1868-1880; Malik, J.; Clarson, S. J. Polym Degrad Stab 2002, 76, 241-249; (j) Chen, J.-S.; Ober, C. K.; Poliks, M. D. Polymer 2002, 43, 131-139; (k) Gheneim, R.; Perez-Berumen, C.; Gandini, A. Macromolecules 2002, 35, 7246-7253; (1) Li, H. Y.; Wang, L. J.; Jacob, K.; Wong, C. P. J Polym Sci Part A: Polym Chem 2002, 40, 1796-1807; Wang, Z. G.; Xie, M. R.; Zhao, Y. F.; Yu, Y. Z.; Fang, S. B. Polymer 2003, 44, 923-929.
    • (2002) Polymer , vol.43 , pp. 131-139
    • Chen, J.-S.1    Ober, C.K.2    Poliks, M.D.3
  • 11
    • 0037056318 scopus 로고    scopus 로고
    • For recent publications on thermally or chemically degradable thermosets, see (a) Buchwalter, S. L.; Kosber, L. L. J Polym Sci Part A: Polym Chem 1996, 34, 249-260; (b) Yang, S.; Chen, J.-S.; Korner, H.; Breiner, T.; Ober, C. K. Chem Mater 1998, 10, 1475-1482; Ogino, K.; Chen, J.-S.; Ober, C. K. Chem Mater 1998, 10, 3833-3838; Wang, L.; Wong, C. P. J Polym Sci Part A: Polym Chem 1999, 37, 2991-3001; (e) Wang, D.; Lam, D. C. C. J Mater Sci Lett 2000, 19, 2109-2111; (f) Nakano, T.; Iwasa, H.; Miyagawa, N.; Takahara, S.; Yamaoka, T. J Photopolym Sci Technol 2000, 13, 715-717; (g) Wang, L.; Li, H.; Wong, C. P. J Polym Sci Part A: Polym Chem 2000, 38, 3771-3782; (h) Wang, L.; Wong, C. P. J Appl Polym Sci 2001, 81, 1868-1880; Malik, J.; Clarson, S. J. Polym Degrad Stab 2002, 76, 241-249; (j) Chen, J.-S.; Ober, C. K.; Poliks, M. D. Polymer 2002, 43, 131-139; (k) Gheneim, R.; Perez-Berumen, C.; Gandini, A. Macromolecules 2002, 35, 7246-7253; (1) Li, H. Y.; Wang, L. J.; Jacob, K.; Wong, C. P. J Polym Sci Part A: Polym Chem 2002, 40, 1796-1807; Wang, Z. G.; Xie, M. R.; Zhao, Y. F.; Yu, Y. Z.; Fang, S. B. Polymer 2003, 44, 923-929.
    • (2002) Macromolecules , vol.35 , pp. 7246-7253
    • Gheneim, R.1    Perez-Berumen, C.2    Gandini, A.3
  • 12
    • 0036604403 scopus 로고    scopus 로고
    • For recent publications on thermally or chemically degradable thermosets, see (a) Buchwalter, S. L.; Kosber, L. L. J Polym Sci Part A: Polym Chem 1996, 34, 249-260; (b) Yang, S.; Chen, J.-S.; Korner, H.; Breiner, T.; Ober, C. K. Chem Mater 1998, 10, 1475-1482; Ogino, K.; Chen, J.-S.; Ober, C. K. Chem Mater 1998, 10, 3833-3838; Wang, L.; Wong, C. P. J Polym Sci Part A: Polym Chem 1999, 37, 2991-3001; (e) Wang, D.; Lam, D. C. C. J Mater Sci Lett 2000, 19, 2109-2111; (f) Nakano, T.; Iwasa, H.; Miyagawa, N.; Takahara, S.; Yamaoka, T. J Photopolym Sci Technol 2000, 13, 715-717; (g) Wang, L.; Li, H.; Wong, C. P. J Polym Sci Part A: Polym Chem 2000, 38, 3771-3782; (h) Wang, L.; Wong, C. P. J Appl Polym Sci 2001, 81, 1868-1880; Malik, J.; Clarson, S. J. Polym Degrad Stab 2002, 76, 241-249; (j) Chen, J.-S.; Ober, C. K.; Poliks, M. D. Polymer 2002, 43, 131-139; (k) Gheneim, R.; Perez-Berumen, C.; Gandini, A. Macromolecules 2002, 35, 7246-7253; (1) Li, H. Y.; Wang, L. J.; Jacob, K.; Wong, C. P. J Polym Sci Part A: Polym Chem 2002, 40, 1796-1807; Wang, Z. G.; Xie, M. R.; Zhao, Y. F.; Yu, Y. Z.; Fang, S. B. Polymer 2003, 44, 923-929.
    • (2002) J Polym Sci Part A: Polym Chem , vol.40 , pp. 1796-1807
    • Li, H.Y.1    Wang, L.J.2    Jacob, K.3    Wong, C.P.4
  • 13
    • 0037449635 scopus 로고    scopus 로고
    • For recent publications on thermally or chemically degradable thermosets, see (a) Buchwalter, S. L.; Kosber, L. L. J Polym Sci Part A: Polym Chem 1996, 34, 249-260; (b) Yang, S.; Chen, J.-S.; Korner, H.; Breiner, T.; Ober, C. K. Chem Mater 1998, 10, 1475-1482; Ogino, K.; Chen, J.-S.; Ober, C. K. Chem Mater 1998, 10, 3833-3838; Wang, L.; Wong, C. P. J Polym Sci Part A: Polym Chem 1999, 37, 2991-3001; (e) Wang, D.; Lam, D. C. C. J Mater Sci Lett 2000, 19, 2109-2111; (f) Nakano, T.; Iwasa, H.; Miyagawa, N.; Takahara, S.; Yamaoka, T. J Photopolym Sci Technol 2000, 13, 715-717; (g) Wang, L.; Li, H.; Wong, C. P. J Polym Sci Part A: Polym Chem 2000, 38, 3771-3782; (h) Wang, L.; Wong, C. P. J Appl Polym Sci 2001, 81, 1868-1880; Malik, J.; Clarson, S. J. Polym Degrad Stab 2002, 76, 241-249; (j) Chen, J.-S.; Ober, C. K.; Poliks, M. D. Polymer 2002, 43, 131-139; (k) Gheneim, R.; Perez-Berumen, C.; Gandini, A. Macromolecules 2002, 35, 7246-7253; (1) Li, H. Y.; Wang, L. J.; Jacob, K.; Wong, C. P. J Polym Sci Part A: Polym Chem 2002, 40, 1796-1807; Wang, Z. G.; Xie, M. R.; Zhao, Y. F.; Yu, Y. Z.; Fang, S. B. Polymer 2003, 44, 923-929.
    • (2003) Polymer , vol.44 , pp. 923-929
    • Wang, Z.G.1    Xie, M.R.2    Zhao, Y.F.3    Yu, Y.Z.4    Fang, S.B.5
  • 19
    • 4043110783 scopus 로고    scopus 로고
    • note
    • 254 is 56,000 (L/mol cm) in acetonitrile. The quantum yield for the photochemical acid generation at 254 nm is 0.065 in a poly(methyl methacrylate) film.
  • 20
    • 4043109309 scopus 로고    scopus 로고
    • note
    • The IUPAC name is benzene-1,3,5-tricarboxylic acid tris[1-methyl-1-(6-methyl-7-oxabicyclo[4,1,0]-hept-3-yl)ethyl] ester.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.